SHIONO, Takeshi
→HIROSHIMA UNIVERSITY Profiles of Faculty and Research
Scholars
Appointment･Course: Department of Applied Chemistry, Graduate
School of Engineering
Title of Position: Professor
e-mail address: tshiono"at"hiroshima-u.ac.jp
(Please replace "at" with @.)
Telephone: +81-82-424-7730
Facsimile: +81-82-424-5494
Date of Birth: May 18, 1958
Education:
Graduated from Department of Chemical Engineering, Tokyo Institute
of Technology, Tokyo, in 1981
Obtained a M.S. of Engineering from Department of Environmental
Chemistry and Engineering, Tokyo Institute of Technology, Yokohama,
in 1983.
Received a Ph. D (Engineering) in 1988 from Tokyo Institute
of Technology for a thesis entitled: "Additive effects of
Lewis bases on olefin polymerization with Ti-based catalysts".
Occupation:
1983-1993 Research Associate, Research Laboratory of Resources
Utilization, Tokyo Institute of Technology.
1993-2004 Associate
Professor in Polymer Chemistry, Research Laboratory of Resources
Utilization, Tokyo Institute of Technology.
2004-present Professor in Polymer Chemistry Group, Department
of Applied Chemistry, Graduate School of Engineering, Hiroshima
University
University Address: Kagamiyama 1-4-1, Higashi-Hiroshima 739-8527,
JAPAN
Present Research Fields
Stereospecific Living Polymerization of Olefins
Functionalization of Polyolefins
Stereospecific Polymerization of Polar Vinyl Monomers by Metallocene
Catalysts
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Recent Publications:
- A Novel Synthetic Procedure for Stereoblock
Polypropylene with a Living Polymerization System
K. Nishii, T. Shiono and T. Ikeda
Macromol. Rapid Commun., in press
- Effect of Cross-Linking Density on Photoinduced
Bending Behavior of Oriented Liquid-Crystalline Network Films
Containing Azobenzene
Y. Yu, M. Nakano, A. Shishido, T. Shiono and T. Ikeda
Chem. Mater., in press.
- Effect of Solvents on Living Polymerization
of Propylene with [t-BuNSiMe2Flu]TiMe2-MMAO
Catalysis System
K. Nishii, T. Matsumae, E. O. Dare, T. Shiono and T. Ikeda
Macromol. Chem. Phys., 205, 363-370 (2004).
- Supporting Effects of Methylaluminoxane on
the Living Polymerization of Propylene with a Chelating (Diamide)dimethyltitanium
Complex
H. Hagimoto, T. Shiono and T. Ikeda
Macromol. Chem. Phys., 205, 19-26 (2004).
- Highly Efficient Holographic Materials Based
on Polymer Liquid Crystals
K. Okano, A. Shishido, O. Tsutsumi, T. Shiono and T. Ikeda
J. Nonlinear Opt. Phys., 12, 1-8 (2003).
- Photoresponsive Behavior of
Azobenzene Liquid-Crystalline Gels
M. Nakano, Y. Yu, A. Shishido, O. Tsutsumi, A. Kanazawa, T. Shiono
and T. Ikeda
Mol. Cryst. Liq. Cryst., 398, 1-9 (2003).
- Photo-Induced Alignment of Liquid Crystals
on Polyimide Parallel to Polarization of Linearly Polarized Light
C. Xu, T. Shiono, T. Ikeda, Y. Wang and Y. Takeuchi
J. Mater. Chem., 13, 669-671 (2003).
- Polymerization of 1,3-Butadiene
by Cobalt Dichloride Activated with Various Aluminoxanes
D. C. Nath, T. Shiono and T. Ikeda
Appl. Catal. A, 238, 193-199 (2003).
- Copolymerization of Ethylene
and Propylene Using Silicon tetrachloride-modified Silica/MAO
with Et[Ind]2ZrCl2 Metallocene Catalyst
C. Chao, W. Pratchayawutthirat, P. Praserthdam, T. Shiono and
G. L. Rempel
Macromol.Rapid Commun. 23, 672-675 (2002).
- Living Polymerization of Norbornene
via Vinyl Addition with ansa-Fluorenylamidodimethyltitanium Complex
T. Hasan, K. Nishii, T. Shiono and T. Ikeda
Macromolecules, 35, 8933-8935 (2002).
- High-Performance Material for
Holographic Gratings by Means of a Photoresponsive Polymer Liquid
Crystal Containing a Tolane Moiety with High Birefringence
S. Yoneyama, T. Yamamoto, O. Tsutsumi, A. Kanazawa, T. Shiono
and T. Ikeda
Macromolecules, 35, 8751-8758 (2002).
- Propene Polymerization with
Stereospecific Metallocene-[Ph3C][B(C6F5)4] Using w-Alkenylaluminum as an Alkylation Reagent
and as a Functional Comonomer
Y. G. Nam, T. Shiono and T. Ikeda
Macromolecules, 35, 6760-6762 (2002).
- Effect of Halogen Ligands on 1,3-Butadiene
Polymerization with Cobalt Dihalides and Methylaluminoxane
D. C. Nath, T. Shiono and T. Ikeda
Macromol. Chem. Phys., 203, 1171-1177 (2002).
- Propagation Mechanism for Living Polymerization
of Olefins Using [h1: h3-tert-butyl(dimethylfluorenylsilyl)amido]dimethyl-titanium-based
catalyst
K. Nishii, T. Shiono and T. Ikeda
Kobunshi Ronbunshu, 59, 371-376 (2002). (Japanese)
- Living Polymerization of Propene with a Chelating
(Diamide)dimethyltitanium Using Silica-Supported Methylaluminoxane
H. Hagimoto, T. Shiono and T. Ikeda
Macromolecules, 35, 5744-5745 (2002).
- Copolymerization of 1,3-Butadiene and Isoprene
with Cobalt Dichloride/Methylaluminoxane in the Presence of Triphenylphosphine
D. C. Nath, T. Shiono and T. Ikeda
J. Polym. Sci., Part A: Polym. Chem. Ed., 40, 3086-3092
(2002).
- Photoinduced Reorientation and Thermal Effects
in an Oligothiophene-doped Liquid Crystal System
H. Zhang, S. Shiino, A. Kanazawa, O. Tsutsumi, T. Shiono and
T. Ikeda
J. Appl. Phys., 91, 5558-5563 (2002).
- Living Nature of Propene Polymerization with
ansa-(Cyclopentadienylamido)dimethyltitanium Derivatives
Using MAO as Cocatalyst
T. Shiono, M. T. Hasan, A. Ioku, K. Nishii and T. Ikeda
"Future Technologies for Polyolefin and Olefin Polymerization
Catalysis", M. Terano and T. Shiono ed., Technology
and Education Publishers, Tokyo, 280-285 (2002).
- Propene Polymerization with Silica-supported
(h5-Pentamethylcyclopentadienyl)trimethyltitanium Catalyst
A. Ioku, T. Shiono and T. Ikeda
"Future Technologies for Polyolefin and Olefin Polymerization
Catalysis", M. Terano and T. Shiono ed., Technology
and Education Publishers, Tokyo, p.333-338 (2002).
- Functionalization of Isotactic Polypropene
Using 1,2,4-Trivinylcyclohexane as a Comonomer
Y. G. Nam, T. Shiono and T. Ikeda
"Future Technologies for Polyolefin and Olefin Polymerization
Catalysis", M. Terano and T. Shiono ed., Technology
and Education Publishers, Tokyo, p.339-344 (2002).
- Effect of Cocatalyst on Propene Polymerization
with [t-BuNSiMe2(C5Me4)]TiMe2
A. Ioku, T. Hasan, T. Shiono and T. Ikeda
Macromol. Chem. Phys., 203, 748-755 (2002).
- cis-Specific Living
Polymerization of 1,3-Butadiene with CoCl2 and Methylaluminoxane
D. C. Nath, T. Shiono and T. Ikeda
Macromol. Chem. Phys., 203, 756-760 (2002).
- Control of Regiospecificity in Propene Polymerization
with SiO2-Supported Cp*TiMe3 Catalysts
A. Ioku, T. Shiono and T. Ikeda
J. Macromol. Sci., Pure Appl. Chem., A39, 397-404
(2002).
- Living Polymerization of Propene with a Chelating
Diamide Complex of Titanium Using Dried Methylaluminoxane
H. Hagimoto, T. Shiono and T. Ikeda
Macromol. Rapid Commun., 23, 73-76 (2002).
- Dynamics of Photochemical Phase Transition
of Guest/Host Liquid Crystals with an Azobenzene Derivative as
a Photosensitive Chromophore
J.-H. Sung, S. Hirano, O. Tsutsumi, A. Kanazawa, T. Shiono and
T. Ikeda
Chem. Mater., 14, 385-391 (2002).
- Supporting Effect of Methylaluminoxane with
Monocylcopentadienylalkyltitanium Derivatives on Propene Polymerization
A. Ioku, T. Shiono and T. Ikeda
Appl. Catal. A: General, 226, 15-22 (2002).
- X-ray Measurements of an Oligothiophene Containing
Acetylene Linkage
H. Zhang, S. Shiino, A. Kanazawa, O. Tsutsumi, T. Shiono, T.
Ikeda and Y. Nagase
Synth. Met., 126, 11-18 (2002).
- Photochemical Phase Transition Behavior of
Polymer Liquid Crystals with ortho-Substituted Azobenzene
S. Yoneyama, O. Tsutsumi, A. Shishido, A. Kanazawa, T. Shiono
and T. Ikeda
Mol. Cryst. Liq. Cryst., in press.
- Copolymerization of ethene and 1,3-butadiene
over a SiO2-supported CpTiCl3 catalyst
T. Shiono, O. Yoshino and T. Ikeda
In "Micro-Kinetics and Dynamics of Individual Active
Sites in Catalytic Reactions", T. Sano, T. Uozumi, H.
Nakatani M. Terano and N. Otsuka ed., Technology and Education
Publishers, Tokyo, p131-137 (2001).
- Copolymerization of Propene and 1,2,4-Trivinylcyclohexane
by a MgCl2-Supported TiCl4 Catalyst
Y.-G. Nam, S. Murayama, T. Shiono and T. Ikeda
Macromolecules, 34, 6533-6535 (2001).
- Application of Photosensitive Polyimides as
Alignment Layer to Optical Switching Devices of Nematic Liquid
Crystal
G.-H. Kim, S. Enomoto, A. Kanazawa, T. Shiono, T. Ikeda and L.-S.
Park
Liq. Cryst., 28, 271-277 (2001).
- Phase-Type Gratings Formed by Photochemical
Phase Transition of Polymer Azobenzene Liquid Crystals: 2. Rapid
Switching of Diffraction Beams in Thin Films
T. Yamamoto, A. Ohashi, S. Yoneyama, M. Hasegawa, O. Tsutsumi,
A. Kanazawa, T. Shiono and T. Ikeda
J. Phys. Chem. B, 105, 2308-2331 (2001).
- Thermal Stability of Alignment of a Nematic
Liquid Crystal Induced by Polyimide Exposed to Linearly Polarized
Light
Y. Wang, C. Xu, A. Kanazawa, T. Shiono, T. Ikeda, Y. Matsuki,
and Y. Takeuchi
Liq. Cryst., 28, 473-475 (2001).
- Syndiospecific Living Polymerization of Propene
with [t-BuNSiMe2Flu]TiMe2 Using MAO as Cocatalyst
T. Hasan, A. Ioku, K. Nishii, T. Shiono and T. Ikeda
Macromolecules, 34, 3142-3145 (2001).
- Formation of Intensity Grating in a Polymer
Liquid Crystals with a Side-Chain Azobenzene Moiety by Photoinduced
Alignment Change of Mesogens
S. Yoneyama, T. Yamamoto, M. Hasegawa, O. Tsutsumi, A. Kanazawa,
T. Shiono, and T. Ikeda
J. Mater. Chem., 11, 3008-3013 (2001).
- Photoinduced Reorientation of Liquid Crystals
Doped with a Mesogenic Oligothiophene
H. Zhang, S. Shiino, O. Tsutsumi, A. Kanazawa, T. Shiono and
T. Ikeda
Mol. Cryst. Liq. Cryst., 368, 369-376 (2001).
- Electroluminescent Behavior of Oxadiazole Derivatives
in Liquid-crystalline Media
H. Mochizuki, T. Hasui, O. Tsutsumi, A. Kanazawa, T. Shiono,
T. Ikeda, C. Adachi, Y. Taniguchi and Y. Shirota
Mol. Cryst. Liq. Cryst., 365, 1085-1094 (2001).
- Formation of Grating by Means of Photoinduced
Alignment Change of Polymer Liquid Crystals with Azobenzene Moieties
S. Yoneyama, O. Tsutsumi, A. Kanazawa, T. Shiono and T. Ikeda
Mol. Cryst. Liq. Cryst., 368, 335-343 (2001).
- Synthesis and Oxidative Degradation of Poly(ethene-ran-1,3-
butadiene)
T. Shiono, O. Yoshino and T. Ikeda
Macromol. Rapid Commun., 21, 1297-1301 (2000).
- Light-Scattering-Mode Optical Switching and
Image Storage in Polymer/Liquid Crystal Composite Films by Means
of Photochemical Phase Transition
H.-K. Lee, K. Doi, A. Kanazawa, T. Shiono, T. Ikeda, T. Fujisawa,
M. Aizawa and B. Lee
Polymer, 41, 1757-1763 (2000).
- Holographic Gratings and Holographic Image
Storage by Photochemical Phase Transition of Polymer Azobenzene
Liquid-Crystal Films
T. Yamamoto, M. Hasagawa, A. Kanazawa, T. Shiono and T. Ikeda
J. Mater. Chem., 10, 337-342 (2000).
- Photoinduced Alignment of Polymer Liquid Crystals
Containing Azobenzene Moieties in the Side Chain. 7. On Irradiation
by a He-Ne Laser Beam
Y. Wu, J. Mamiya, O. Tsutsumi, A. Kanazawa, T. Shiono and T.
Ikeda
Liq. Cryst., 27, 749-753 (2000).
- Photochemical Modulation of Color and Transmittance
in Chiral Nematic Liquid Crystals Containing an Azobenzene as
a Photosensitive Chromophore
H.-K. Lee, K. Doi, H. Harada, O. Tsutsumi, A. Kanazawa, T. Shiono
and T. Ikeda
J. Phys. Chem. B, 104, 7023-7028 (2000).
- Holographic Gratings in the Optically Isotropic
State of Polymer Azobenzene Liquid-Crystal Films
T. Yamamoto, S. Yoneyama, O. Tsutsumi, A. Kanazawa, T. Shiono
and T. Ikeda
J. Appl. Phys., 88, 2215-2220 (2000).
- A Thiophene Liquid Crystal as a Novel p-Conjugated Dye for Photo-Manipulation of Molecular
Alignment
H. Zhang, S. Shiino, A. Shishido, A. Kanazawa, O. Tsutsumi,T.
Shiono and T. Ikeda
Adv. Mater., 12, 1336-1339 (2000).
- Novel Liquid-Crystalline and Amorphous Materials
Containing Oxadiazole and Amine Moieties for Electroluminescent
Devices
H. Mochizuki, T. Hasui, M. Kawamoto, T. Shiono, T. Ikeda, C.
Adachi, Y. Taniguchi and Y. Shirota
Chem. Commun., 1923-1924 (2000).
- Emission Behavior of Molecularly-Doped Electroluminescent
Device Using Liquid-Crystalline Matrix
H. Mochizuki, T. Hasui, T. Shiono, T. Ikeda, C. Adachi, Y. Taniguchi
and Y. Shirota
Appl. Phys. Lett., 77, 1587-1589 (2000).
- Copolymerization of Ethylene and Styrence with
a MgCl2-Supported CpTiCl3 Catalyst
K.K. Kang, J.K. Oh, Y.-T. Jeong, T. Shiono and T. Ikeda
Macromol. Chem. Phys., 201, 846-850 (2000).
- Additive effects of trialkylaluminum on propene
polymerization with (t-BuNSiMe2Flu)TiMe2 catalysts
T. Shiono, S. Yoshida, H. Hagihara and T. Ikeda
Appl. Catal.A, 200, 145-152 (2000).
