2026年
学術論文
6)Effect of the carbon numbers of dicarboxylic
acids and diols on marine biodegradation of aliphatic polyesters
Yuushou Nakayama, Tomoka Shuto, Ryo Tanaka,
Takeshi Shiono, Shodai Hino, Norioki
Kawasaki, Naoko Yamano, Atsuyoshi Nakayama
Polym. Degrad. Stab., ,
Accepted (2026).
BOD biodegradation (%) of PEm-n
in seawater at 27°C for 28 d
5)One-shot activating reagent of neodymium
carboxylate for highly cis-1,4 specific butadiene polymerization
Yu Jia, Kenji Komaguchi, Yuushou Nakayama,
Takeshi Shiono, Ryo Tanaka
Polym. Chem., , Accepted (2026).
4)One-shot activating reagent of neodymium
carboxylate for highly cis-1,4 specific butadiene polymerization
Yu Jia, Toru Wada, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Polym. Chem., 17, 1069-1074 (2026). doi

3)Synthesis of boronic acid-crosslinked
diene-based polymers via free-radical copolymerization
Manami Kawamoto, Shin-ichi Kihara, Subrata Dolui, Mari Nishizono, Yuushou
Nakayama, Takeshi Shiono, Ryo Tanaka
Chem. Asian J., 21, e70572 (2026). doi

2)Synthesis of Long-chain Branched Multiblock
Polyolefin Composed of Isotactic Polypropylene and Ethylene-propylene Copolymer
via Polymer Cross-Metathesis
Yuta Yanagi, Takumitsu Kida, Ryo Tanaka, Yuushou
Nakayama, Takeshi Shiono
Polym. J., , (2025). doi

1)Enhanced Marine Biodegradability of
Poly(Lactic Acid)-Based Polyurethanes via Alkylene Diglycolate
Incorporation
Yuushou Nakayama, Chigen Kinoshita, Ryo Tanaka,
Takeshi Shiono, Shodai Hino, Norioki
Kawasaki, Naoko Yamano, Atsuyoshi Nakayama
Chem. Asian J., 21, e00901 (2026). doi

2025年
学術論文
1)Multimodal polypropylene synthesis using
cyclic borane cocatalyst
Daichi Oka, Shunsuke Nishiyama, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Organometallics, 44, 2156-2162 (2025). doi

2)A Simple Cocatalyst Modification Approach
for Tuning Polyolefin Branching: Halogenated MAO in Nickel-Catalyzed Ethylene
Polymerization
Yu Jia, Nao Harada, Toru Wada, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Polym. Chem., 16, 4381-4388 (2025). doi

3)Physical properties and degradability of
branched polylactide copolymers
Chikara Tsutsumi, Susumu Nakayama, Masaki Shiomi, Yuushou Nakayama
Polymer, 337, 128971 (2025). doi

4) Enhancing Mechanical Properties and
Crystallization Kinetics of Isotactic Polypropylene by Boronic
Acid-Cross-Linked Additives
Kazuki Shimizu, Shin-ichi Kihara, Mikihiro Hayashi,
Hiroyuki Koga, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Macromolecules, 58, 8143-8150 (2025). doi

総説・解説
5) 生分解性を備えた熱可塑性エラストマーの設計と合成
中山 祐正
ポリマーTECH, 27, 19-28 (2025). URL
6) 強度が改善されたポリ乳酸/セルロースナノファイバー複合体
中山 祐正
月刊プラスチックス, 7, 5-9 (2025). URL
2024年
学術論文
1) Ring-Opening Homo- and Copolymerization of
Cyclic Esters Catalyzed by Iron(III) Triflate
Yuushou Nakayama, Toshihiko Omori, Ryo Tanaka, Takeshi Shiono
Catalysts, 14, 945 (2024). doi

3) Origin of the Two Major Types of Repeating
Units in Poly(β-pinene) Obtained by Cationic Polymerization
Oluwaseyi Aderemi Ajala, Shogo Nakaichi, Toshiyuki
Oshiki, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Macromolecules, 57, 9257-9264 (2024). doi

4) Biodegradable thermoplastic elastomers
synthesized from C7–C10 aliphatic dicarboxylic acids, 2-methyl-1,3-propanediol,
and L-lactide
Yuushou Nakayama, Takayoshi Matsu-ura, Ryo Tanaka,
Takeshi Shiono, Shodai, Hino, Norioki
Kawasaki, Naoko Yamano, Atsuyoshi Nakayama, Rie
Tezuka, Kazuya Tanaka
Polym. Degrad. Stab., 229, 110978
(2024). doi

5) Commodity Rubber Material with Reversible
Cross-linking Ability: Application of Boroxine Cross-links to
Ethylene-Propylene Rubber
Yusuke Bando, Shin-ichi Kihara, Hiroya Fujii, Yuushou Nakayama, Takeshi Shiono,
Ryo Tanaka
Macromolecules, 57, 7565-7574 (2024). doi

7) A Bio-Based Tackifier Synthesized by
Room-Temperature Cationic Copolymerization of Isobutene and β-Pinene
Oluwaseyi Aderemi Ajala, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Catalysts, 14, 402 (2024). doi

9) Copolymerization of Ethylene with
Functionalized 1,1-Disubstituted Olefins Using a Fluorenylamido-Ligated
Titanium Catalyst
Oluwaseyi Aderemi Ajala, Moeko Ono, Yuushou Nakayama, Ryo Tanaka, Takeshi
Shiono
Polymers, 16, 236 (2024). doi

2023年
学術論文
1) Selective synthesis of
α-vinyl-ω-vinylidene-oligoisoprene as a macromonomer
via ethenolysis of polyisoprene
Ryo Tanaka, Akane Shimmei, Riki Otsuka, Yuushou Nakayama, Takeshi Shiono
Polym. J., 56, 335-342 (2023). doi

2) Ring-Opening Polymerization of Lactones
Catalyzed by Silicon-Based Lewis Acid
Yuushou Nakayama, Keiya Katagi, Ryo Tanaka, Takeshi Shiono
Int. J. Polym. Sci., , 4391372 (2023). doi

4) Synthesis, Properties, and Biodegradability
of Novel Sequence-Controlled Copolyesters Composed of Glycolic Acid,
Dicarboxylic Acids, and C3 or C4 Diols
Yuushou Nakayama, Keitaro Fukumoto, Yuji Kusu, Ryo Tanaka, Takeshi Shiono, Norioki Kawasaki, Naoko Yamano, Atsuyoshi
Nakayama
Polymers, 15, 1155 (2023). doi


総説・解説
6) Control of coordination polymerization
behavior by counter-anionic effects
Ryo Tanaka, Oluwaseyi Aderemi Ajala, Yuushou Nakayama, Takeshi Shiono
Prog. Polym. Sci., 142, 101690 (2023). doi

2022年
学術論文
1) Synthesis of chain-end functional polydienes using diene comonomer bearing boronic acid
masked with diaminonaphthalene
Ryo Tanaka, Yuina Kuwabara, Yuushou Nakayama, Takeshi Shiono
Molecules, 27, 9007 (2022). doi
2) Impact of methylaluminoxane
oxidation on the ethylene polymerization using Ni catalysts
Ryo Tanaka, Kenji Sogo, Kenji Komaguchi, Kazuki Ae, Yuushou Nakayama, Takeshi
Shiono
Organometallics, 41, 3024-3031 (2022). doi

3) Synthesis of Granular Hydroxy‑Functionalized
Ultra‑high‑molecular‑weight Polyethylene and Its Fiber Properties
Haobo Yuan, Cong Long, Junrong
Yu, Fuyou Ke, Takeshi Shiono, Zhengguo
Cai
Adv. Fiber Mater. , 4, 786-794 (2022). doi
4) Star polymers with norbornene/1-octene
gradient copolymer arms synthesized by an ansa-fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)4]
catalyst system
Haobo Yuan, Takumitsu Kida,
Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama, Shin-ichi
Kihara, Takeshi Shiono
Polymer, 249, 124844 (2022). doi

5) Selective alcoholysis of lactide catalyzed
by bulky Lewis pairs of tris(pentafluorophenyl)borane
and phosphines
Yuushou Nakayama, Kentaro Yamaguchi, Ryo Tanaka, Takeshi Shiono
Mol. Catal. , 519, 112121 (2022). doi

6) Cyclic olefin copolymer bearing pendant
fluorenyl groups with high refractive index and low chromatic dispersion
Haobo Yuan, Takumitsu Kida,
Yuma Ishitobi, Ryo Tanaka, Masayuki Yamaguchi, Yuushou Nakayama, Takeshi Shiono
Macromolecules, 55, 125-132 (2022). doi

7) An environmentally adaptable stereocomplex derived from lactide copolymers with improved
UV shielding characteristics based on morphological changes
Chikara Tsutsumi, Susumu Nakayama, Yasuhiro Matsubara, Yuushou Nakayama,
Takeshi Shiono
React. Funct. Polym.,
173, 105148 (2022). doi

8) Polymerization of Styrene Derivatives Using
Anilinonaphthoquinone-ligated Nickel Complexes and
Thermal/Rheological Properties of the Produced Polymers
Samiul Islam Chowdhury, Takumitsu Kida, Ryo Tanaka,
Yuushou Nakayama, Takeshi Shiono
Macromol. Chem. Phys., 223, 2100402 (2022). doi

総説・解説
9) 配列が制御された新規生分解性コポリマーの設計とその可能性
中山 祐正
MATERIAL STAGE, 21(10), 45-49 (2022).
12)生分解性を有する新規ポリエステル系共重合体の設計と合成
中山 祐正
日本画像学会誌, 61(3), 261-270 (2022).
2021年
学術論文
2) Removal of mononuclear alkylaluminum
species in aluminoxane using crosslinked polymer bearing bulky phenoxy groups
Ryo Tanaka, Mari Nishizono, Yuushou Nakayama, Takeshi Shiono
Polym. J., 53, 1187-1193 (2021). doi
4) Incorporation of boronic acid functionality
into isotactic polypropylene and its application as crosslinking point
Ryo Tanaka, Hiroya Fujii, Takumitsu Kida, Yuushou
Nakayama, Takeshi Shiono
Macromolecules, 54, 1267-1272 (2021). doi

5) Synthesis, Properties, and Biodegradabilities of Thermoplastic Elastomers made from
2-Methyl-1,3-propanediol, Glutaric Acid and Lactide
Lamya Zahir, Takumitsu Kida, Ryo Tanaka, Yuushou
Nakayama, Takeshi Shiono, Norioki Kawasaki, Naoko
Yamano, Atsuyoshi Nakayama
Life, 11, 43 (2021). doi

6) A Neutral, Noncoordinating, and
Hydrocarbon-soluble Protic Cocatalyst for Olefin Polymerization
Tomoya Nakashima, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
ACS Catal., 11, 865-870 (2021). doi

7) Synthesis of thermoplastic elastomers with
high biodegradability in seawater
Lamya Zahir, Takumitsu Kida, Ryo Tanaka, Yuushou
Nakayama, Takeshi Shiono, Norioki Kawasaki, Naoko
Yamano, Atsuyoshi Nakayama
Polym. Degrad. Stab., 184, 109467 (2021). doi

8) Synthesis and Properties of Block
Copolymers Composed of Norbornene/Higher α-Olefin Gradient Segments Using ansa-Fluorenylamidodimethyltitanium‒[Ph3C][B(C6F5)4]
Catalyst System
Haobo Yuan, Takumitsu Kida,
Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama, Takeshi
Shiono
Polym. Chem., 12, 189-195 (2021). doi
![Graphical abstract: Synthesis and properties of block copolymers composed of norbornene/higher α-olefin gradient segments using ansa-fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)4] catalyst system](publications.files/image044.gif)
総説
9) 配列が制御された新規生分解性コポリマーの設計と合成
中山 祐正
高分子, 70(1), 23-24 (2021).
2020年
学術論文
1) Norbornadiene homopolymerization
and norbornene/norbornadiene/1-octene terpolymerization
by ansa-fluorenylamidotitanium-based
catalysts
Hongyi Suo, Haobo Yuan, Ryo Tanaka, Yuushou Nakayama,
Wen-Hua Sun, Takeshi Shiono
Polym. Chem., 11, 6803-6810 (2020). doi

2) Synthesis and Properties of Biodegradable
Thermoplastic Elastomers using 2-Methyl-1,3-propanediol, Succinic Acid and
Lactide
Lamya Zahir, Takumistu Kida, Ryo Tanaka, Yuushou
Nakayama, Takeshi Shiono, Norioki Kawasaki, Naoko
Yamano, Atsuyoshi Nakayama
Polym. Degrad. Stab., 181, 109353 (2020). doi

3) Synthesis, properties, and biodegradation
of sequential poly(ester amide)s containing gamma-aminobutyric acid
Yuushou Nakayama, Kazumasa Watanabe, Ryo Tanaka, Takeshi Shiono, Norioki Kawasaki, Naoko Yamano, Atsuyoshi
Nakayama
Int. J. Mol. Sci., 21, 3674 (2020). doi

4) Synthesis and Properties of Gradient
Copolymers Composed of Norbornene and Higher alpha-Olefins Using an ansa-Fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)4]
Catalyst System
Haobo Yuan, Takumitsu Kida,
Hyunchul Kim, Ryo Tanaka, Zhengguo
Cai, Yuushou Nakayama, Takeshi Shiono
Macromolecules, 53, 4323-4329 (2020). doi

5) Effect of Ancillary Ligands as a Part of Counteranion in Neodymium-Catalyzed Isoprene Polymerization
Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
Organometallics, 39, 1855-1860 (2020). doi

6) Synthesis of norbornene/divinylbenzene
copolymers catalyzed by anilinonaphthoquinone-ligated
nickel complexes and their applications for the synthesis of graft polymers
Samiul Islam Chowdhury, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
J. Polym. Sci., 58, 1564-1570 (2020). doi

7) Synthesis, properties and biodegradation of
periodic copolyesters composed of hydroxy acids, ethylene glycol, and
terephthalic acid
Yuushou Nakayama, Wataru Yagumo, Ryo Tanaka, Takeshi Shiono, Kei Inumaru, Chikara Tsutsumi, Norioki
Kawasaki, Naoko Yamano, Atsuyoshi Nakayama
Polym. Degrad. Stab., 174, 109095 (2020). doi

9) Coordination-insertion Copolymerization of
Norbornene and p-Substituted Styrenes using anilinonaphthoquinone-ligated Nickel Complexes
Samiul Islam Chowdhury, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
Macromol. Chem. Phys., 221, 1900494 (2020). doi

10) Copolymerization of Norbornene and
Conjugated Dienes Using Anilinonaphthoquinone-ligated
Nickel Complexes
Samiul Islam Chowdhury, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
Polymer, 187, 122094 (2020). doi

総説
2019年
学術論文
1) Impregnation of poly(L-lactide-ran-delta-valerolactone) with essential bark oil using supercritical
carbon dioxide
Chikara Tsutsumi, Souta Manabe, Susumu Nakayama, Yuushou Nakayama, Takeshi
Shiono
Sci. Rep., 9, 16326 (2019). doi

2) Effect of the number of arms on the
mechanical properties of star-shaped cyclic olefin copolymer
Takumitsu Kida, Ryo Tanaka, Koh-hei
Nitta, Takeshi Shiono
Polym. Chem., 10, 5578-5583 (2019). doi

3) Chain-walking polymerization of 3-heptene
with phenyl substituted alpha-diimine nickel
catalysts
Fuzhou Wang, Guoyong Xu, Qingshan Li, Ryo Tanaka,
Yuushou Nakayama, Takeshi Shiono
Polymer, 181, 121801 (2019). doi

4) Copolymerization of Ethylene and Fluoroalkylnorbornene Using Highly Active ansa-(Fluorenyl)(amido)titanium-Based Catalysts
Yanjie Sun, Chen Wang, Ryo Tanaka, Takeshi Shiono, Zhengguo
Cai
Macromol. Chem. Phys., 220, 1900306 (2019). doi

5) Copolymerization of Norbornene and Styrene
with Anilinonaphthoquinone-ligated Nickel Complexes
Samiul Islam Chowdhury, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
Polymers, 11, 1100 (2019). doi

6) Preparation of Methylaluminoxane
from Carbon Dioxide
Yuuya Okajima, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Eur. J. Inorg. Chem., 2392-2395 (2019). doi

7) Cis-1,4 Specific Polymerization of
1,3-butadiene using PNP-pincer Ligated Iron(II) Complexes
Ryo Tanaka, Kenshi Ikeda, Yuushou Nakayama, Takeshi Shiono
Chem. Lett., 48, 525-528 (2019). doi

8) Optically Transparent Functional Polyolefin
Elastomer with Excellent Mechanical and Thermal Properties
Xiangyang Song, Lixin Cao, Ryo Tanaka, Takeshi Shiono, Zhengguo
Cai
ACS Macro Lett., 8, 299-303 (2019). doi

9) Stereospecific polymerization of conjugated
dienes using neodymium alkylborohydride complexes
Ryo Tanaka, Yuto Shinto, Ryusei Matsuzaki, Yuushou Nakayama, Takeshi Shiono
Dalton Trans., 48 7267-7273 (2019). doi

10) ラクチドとε-カプロラクトンからなるステレオブロック共重合体の合成とその性質
中山 祐正, 宇野 智仁, 塩野 毅, 白浜 博幸
高分子論文集, 76, 61-67 (2019).doi

11) Changes in the morphology of
poly(L-lactide-ran-delta-valerolactone) following
supercritical carbon dioxide processing
Chikara Tsutsumi, Yumeko Ishikawa, Naoki Takahashi,
Souta Manabe, Susumu Nakayama, Yasuhiro Matsubara, Yuushou Nakayama, Takeshi
Shiono
Polymer Crystallization, 2, e10070 (2019). doi

総説
12) 重合技術によるポリプロピレンの高性能化・高機能化
塩野 毅
ファインケミカル, 48(6), 5-22 (2019).
13) バイオマス由来TPEの合成
中山 祐正, 塩野 毅
ファインケミカル, 48(7), 15-21 (2019).
14) メチルアルミノキサンの化学 ー 組成制御のための研究動向
田中 亮
化学と工業, 72(10), 834-835 (2019).
2018年
学術論文
1) Efficient Ethylene Copolymerization with
Polar Monomers Using Palladium Anilinonaphthoquinone
Catalysts
Lin Ding, Hailong Cheng, Yanqing Li, Ryo Tanaka, Takeshi Shiono, Zhengguo Cai
Polym. Chem., 9 5476-5482 (2018). doi

2) フルオレニルアミドチタン(テトラヒドロフラン)錯体の合成とそのオレフィン重合触媒作用
西井 圭, 早野 重孝, 角替 靖男, 中山 祐正, 塩野 毅
高分子論文集, 75, 564-569 (2018). doi

3) Efficient Control of Ethylene-Norbornene
Copolymerization Behavior of Fluorenylamido-Ligated
Titanium Complex: Substituent Effects of Amido Ligand and Copolymer Properties
Huajin Wang, Hailong Cheng, Ryo Tanaka, Takeshi
Shiono, Zhengguo Cai
Polym. Chem., 9, 4492-4497 (2018). doi

4) Reversible Star Assembly of Polyolefins
Using Interconversion between Boroxine and Boronic Acid
Ryo Tanaka, Naoki Tonoko, Shin-ichi Kihara, Yuushou Nakayama, Takeshi Shiono
Polym. Chem., 9, 3774-3779 (2018). doi

5) メチルアルミノキサンの助触媒能に対するフェノール・シラノール類の添加効果
田中 亮, 山下 高幸, 渡子 直紀, 中山 祐正, 塩野 毅
高分子論文集, 75, 551-556 (2018). doi

6) Chain-Walking Polymerization of Linear
Internal Octenes Catalyzed by alpha-Diimine Nickel
Catalysts
Fuzhou Wang, Ryo Tanaka, Qingshan Li, Yuushou Nakayama, Takeshi Shiono
Organometallics, 37, 1358-1367 (2018). doi

7) Selective synthesis of highly soluble
cyclic olefin copolymers with pendant vinyl groups using 1,5-hexadiene as a
comonomer Polymer
Ryo Tanaka, Akane Sasaki, Takuma Takenaka, Yuushou Nakayama, Takeshi Shiono
Polymer, 136, 109-113 (2018). doi

総説
8) 原料の構造を保持したバイオベースポリマーの開発
中山祐正
ケミカルエンジニヤリング, 63(12), 896-900 (2018).
2017年
学術論文
1) Substituent Effects of Adamantyl
Group on Amido Ligand in Syndiospecific
Polymerization of Propylene with Ansa-Dimethylsilylene(Fluorenyl)(Amido)
Zirconium Complex
Yanjie Sun, Shuhui Li, Takeshi Shiono, Zhengguo Cai
Polymers, 9, 632 (2017). doi

2) Highly Robust Nickel Catalysts Containing Anilinonaphthoquinone Ligand for Copolymerization of
Ethylene and Polar Monomers
Xia Fu, Lingjun Zhang, Ryo Tanaka, Takeshi Shiono, Zhengguo Cai
Macromolecules, 50, 9216-9221 (2017). doi

3) Synthesis of Stereodiblock
Polybutadiene Using Cp*Nd(BH4)2(thf)2 as A Catalyst
Ryo Tanaka, Yuto Shinto, Yuushou Nakayama, Takeshi Shiono
Catalysts, 7, 284 (2017). doi

4) Living polymerization of higher 2-alkene
with α-diimine nickel catalysts: Synthesis and
characterization of high molecular weight poly(2-alkene)s
Fuzhou Wang, Ryo Tanaka, Zhengguo Cai, Yuushou
Nakayama, Takeshi Shiono
Polymer, 127, 88-100 (2017). doi

5) Highly Active ansa-(Fluorenyl)(amido)titanium-Based
Catalysts with Low Load of Methylaluminoxane for
Syndiotactic-Specific Living Polymerization of Propylene
Yanjie Sun, Bo Xu, Takeshi Shiono, Zhengguo Cai
Organometallics, 36, 3009-3012 (2017). doi

6) An alternative method for the preparation
of trialkylaluminum-depleted modified-methylaluminoxane (dMMAO)
Ryo Tanaka, Tomoyasu Kawahara, Yuto Shinto, Yuushou Nakayama, Takeshi Shiono
Macromolecules, 50, 5989–5993 (2017). doi

7) Synthesis and Biodegradation of
Poly(L-lactide-co-beta-propiolactone)
Yuushou Nakayama, Kazuki Aihara, Zhengguo Cai,
Takeshi Shiono, Chikara Tsutsumi
Int. J. Mol. Sci., 18, 1312 (2017). doi

8) Effect of end-group modification of
poly(lactide)s by cinnamoyl chloride on their thermal stability
Yuushou Nakayama, Naoki Matsubara, Zhennguo Cai,
Takeshi Shiono, Kei Inumaru, Hiroyuki Shirahama
Polym. Degrad. Stab., 141, 97-103 (2017). doi

9) Quasi-Living Polymerization of Propene with
an Isotactic-Specific Zirconocene Catalyst
Kei Nishii, Miyuki Murase, Takeshi Shiono
Molecules, 22, 725 (2017). doi

10) Living Polymerization of Propylene with ansa-Dimethylsilylene(fluorenyl)(cumylamido)
Titanium Complexes
Huajin Wang, Xinwei Wang,
Yanjie Sun, Hailong Cheng, Takeshi Shiono, Zhengguo
Cai
Polymers, 9, 131 (2017). doi

11) Synthesis of Hydroxy-Functionalized Cyclic
Olefin Copolymer and Its Block Copolymers with Semicrystalline Polyolefin
Segments
Xiangyang Song, Lijun Yu, Takeshi Shiono, Tariqul Hasan, Zhengguo
Cai
Macromol. Rapid Commun., 38, 1600815 (2017). doi

12) Synthesis of highly thermostable
norbornene-isoprene-1-octene terpolymer with titanium catalyst
Ryo Tanaka, Ryusei Matsuzaki, Yuushou Nakayama, Takeshi Shiono
J. Polym. Sci. Part A: Polym.
Chem., 55, 2136-2140 (2017).doi

13) Controlled Ring-Opening Polymerization of
L-Lactide and ε-Caprolactone Catalyzed by Aluminum-Based Lewis Pairs or Lewiss
Acid Alone
Yuushou Nakayama, Shunsuke Kosaka, Kentaro Yamaguchi, Gentaro
Yamazaki, Ryo Tanaka, Takeshi Shiono
J. Polym. Sci. Part A: Polym.
Chem., 55, 297-303 (2017).doi

2016年
学術論文
1) Enzymatic degradation of poly(l-lactide)
treated with supercritical carbon dioxide
Chikara Tsutsumi, Ryousuke Ikeda, Ryouji Watanabe,
Susumu Nakayama, Masaki Shiomi, Yuushou Nakayama, Takeshi Shiono
Polym. Degrad.
Stab., 134, 366-375 (2016).doi
2) Theoretical investigation of the mechanism
of syndiospecific propylene polymerization using ansa-dimethylsilylene(fluorenyl)(amido)titanium complexes
Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
J. Organomet. Chem., 823, 112-115 (2016).doi

3) Effects of supercritical carbon dioxide
treatment on the morphology of poly(l-lactide)
Chikara Tsutsumi, Ryouji Watanabe, Ayaka Tokumaru,
Nao Kuwaoka, Yuushou Nakayama, Takeshi Shiono
J. Appl. Polym. Sci., 133, 44006 (2016).doi

4) Precision Chain-Walking Polymerization of
trans-4-Octene Catalyzed by α-Diimine Nickel(II)
Catalysts Bearing ortho-sec-Phenethyl Groups
Wang Fuzhou, Ryo Tanaka, Zhengguo Cai, Yuushou
Nakayama, Takeshi Shiono
Macromol. Rapid Commun., 37, 1375-1381 (2016).doi

5) Synthesis of Highly Branched Polyolefins
Using Phenyl Substituted α-Diimine Ni(II) Catalysts
Wang Fuzhou, Ryo Tanaka, Zhengguo Cai, Yuushou
Nakayama, Takeshi Shiono
Polymers, 8, 160 (2016).doi

6) Synthesis of stereodiblock
polyisoprene consisting of cis-1,4 and trans-1,4 sequences by neodymium
catalyst: change of the stereospecificity triggered by aluminum compound
Ryo Tanaka, Kaede Yuuya, Hiroki Sato, Peter Eberhardt, Yuushou Nakayama,
Takeshi Shiono
Polym. Chem., 7, 1239-1243 (2016).doi

7) Structure-stereospecificity relationships
of propylene polymerization using substituted ansa-silylene(fluorenyl)(amido)
titanium complexes
Ryo Tanaka, Chie Yanase, Zhengguo Cai, Yuushou
Nakayama, Takeshi Shiono
J. Organomet. Chem., 804, 95-100 (2016).doi

8) Facile Synthesis of Novel
Polyethylene-Based A-B-C Block Copolymers Containing Poly(methyl methacrylate)
Using a Living Polymerization System
Xiangyang Song, Qiong Ma, Zhengguo Cai, Ryo Tanaka,
Takeshi Shiono, Robert B. Grubbs
Macromol. Rapid Commun., 37, 227-231 (2016).doi

9) The Preparation of Boron-containing
Aluminoxanes and their Application as Cocatalysts in the Polymerization of
Olefins
Ryo Tanaka, Takaaki Hirose, Yuushou Nakayama, Takeshi Shiono
Polym. J., 48, 67-71 (2016).doi

総説
10) オレフィンと13族アルケニル化合物の共重合による官能基化ポリオレフィンの合成
田中亮、塩野毅
触媒, 58(1), 27-31 (2016).
2015年
学術論文
1) Room-temperature Suzuki-Miyaura
cross-coupling reaction with alpha-diimine Pd(II)
catalysts
Fuzhou Wang, Ryo Tanaka, Zhengguo Cai, Yuushou
Nakayama, Takeshi Shiono
Appl. Organomet. Chem., 29, 771-776 (2015). doi

2) Highly Soluble Polynorbornene Prepared by
an Anilinonaphthoquinone-Ligated Nickel Complex via
Coordination-Insertion Polymerization
Mitsuhiro Okada, Yuushou Nakayama, Takeshi Shiono
J. Organomet. Chem., 798, 384-387 (2015). doi

3) Synthesis of Polystyrene-Grafted
Cycloolefin Copolymer
Ryo Tanaka, Manami Goda, Zhengguo Cai, Yuushou
Nakayama, Takeshi Shiono
Polymer, 70, 252-256 (2015). doi

4) キレートへテロドナー配位子を有する8族遷移金属触媒による開環メタセシス重合の立体制御
中山 祐正, 奥野 晋吾, 田中 亮, 蔡 正国, 塩野 毅
高分子論文集, 72, 460-467 (2015). doi
5) Ethylene-propylene copolymerization
behavior of ansa-dimethylsilylene(fluorenyl)(amido)dimethyltitanium complex: application to
ethylene-propylene-diene or ethylene-propylene-norbornene terpolymers
Ryo Tanaka, Issei Kamei, Zhengguo Cai, Yuushou
Nakayama, Takeshi Shiono
J. Polym. Sci. Part A, 53, 685-691 (2015). doi

6) Pseudo-living copolymerization of
norbornene and omega-alkenylborane - synthesis of
monodisperse functionalized cycloolefin copolymer
Ryo Tanaka, Tomomi Ikeda, Yuushou Nakayama, Takeshi Shiono
Polymer, 56, 218-222 (2015). (doi)

7) Synthesis and application of α-diimine Ni(II) and Pd(II) complexes with bulky steric
groups to polymerization of ethylene and methyl methacrylate
Fuzhou Wang, Ryo Tanaka, Qingshan Li, Yuushou Nakayama, Jianchao
Yuan, Takeshi Shiono
J. Mol. Catal. A: Chem., 398, 231-240 (2015).
(doi)

8) Synthesis of Biodegradable Thermoplastic
Elastomers from ε-Caprolactone and Lactide
Yuushou Nakayama, Kazuki Aihara, Hitomi Yamanishi, Hiroshi Fukuoka, Ryo Tanaka,
Zhengguo Cai, Takeshi Shiono
J. Polym. Sci. Part A: Polym.
Chem., 53, 489-495 (2015).(doi)

9) Synthesis of Aliphatic Polyesters via
Ring-Opening Polymerization of Macrocyclic Oligoesters
Yuushou Nakayama, Keisuke Sakaguchi, Ryo Tanaka, Zhengguo
Cai, Takeshi Shiono
Macromol. Symp., 350, 7-13 (2015). doi

2014年
学術論文
1) Synthesis of C1 symmetrical ansa-cyclopentadienylamidotitanium complexes and their
application for living polymerization of propylene
Zhengguo Cai, Haihui Su,
Yuushou Nakayama, Takeshi Shiono, Munetaka Akita
J. Organomet Chem., 770, 136-141 (2014). doi

2) Heterogenization of an Anilinonaphthoquinone-Chelated
Nickel Complex for Ethylene Polymerization Using Silica-Supported Modifi ed Methylaluminoxane
Mitsuhiro Okada, Yuushou Nakayama, Takeshi Shiono
Macromol. Chem. Phys., 215, 1792-1796 (2014). doi

3) New Nickel(II) Diimine
Complexes Bearing Phenyl and sec-Phenethyl Groups: Synthesis, Characterization,
and Ethylene Polymerization Behaviour
Fuzhou Wang, Jianchao Yuan, Qingshan Li, Ryo Tanaka,
Yuushou Nakayama, Takeshi Shiono
Appl. Organomet. Chem., 28, 477-483 (2014). doi

4) Synthesis of multiblock copolymer of
poly(cis-1,4-butadiene) and poly(3-buten-1-ol)
Ryo Tanaka, Yuki Kasai, Masahito Shinzawa, Zhengguo
Cai, Yuushou Nakayama, Takeshi Shiono
Macromol. Chem. Phys., 215, 888-892 (2014). doi

5) 天然由来揮発性化合物の有効活用を目的とした超臨界二酸化炭素による新規徐放剤に関する研究
堤 主計, 津々木 亜美, 原 光志, 中山 祐正, 塩野 毅
高分子論文集, 71, 1-10 (2014). doi
6) Synthesis and their thermal, mechanical,
and optical properties of A-B-A or A-B block copolymers containing
poly(norbornene-co-1-octene)
Ryo Tanaka, Takuya Suenaga, Zhengguo Cai, Yuushou
Nakayama, Takeshi Shiono
J. Polym. Sci. Part A: Polym.
Chem., 52, 267-271 (2014). doi

学術論文(非SCI)
7) Synthesis and Properties of
Polylactide-based Poly(ester-urethane)s with Ionic Groups
Yuushou Nakayama, Toshitaka Ohmori, Ryo Tanaka,
Takeshi Shiono, Hiroyuki Shirahama
J. Jpn. Inst. Energy, 93, 921-925 (2014). doi

8) Synthesis and Properties of Poly(epsilon-carprolactone)-based Poly(ester-urethane)s Having
Quaternary Ammonium Groups
Yuushou Nakayama, Naoki Matsubara, Ryo Tanaka, Zhengguo
Cai, Takeshi Shiono, Hiroyuki Shirahama, Chikara Tsutsumi
J. Jpn. Inst. Energy, 93, 916-920 (2014). doi

総説
9) ジメチルシリレン架橋(フルオレニル)(アミド)ジメチルチタン錯体触媒によるシクロオレフィン共重合体の精密合成
田中亮、塩野毅
有機合成化学協会誌, 72(2), 118-125 (2014). doi
Books, Reports (2014-2023)
1) 中山 祐正, 塩野 毅、"生分解性を有する新規機能性コポリエステルの設計と合成"
in「海洋汚染問題を解決する生分解性プラスチック開発」, 監修 岩田 忠久,
p.187-201, エヌ・ティー・エス (2023).
2) 中山 祐正,
"ハフニウム"-"イリジウム" in「元素118の新知識 第2版」, 桜井 弘 編著, 講談社 (2023).
3) 中山 祐正,
"配列が制御された生分解性コポリマーの設計と合成" in「容器包装材料の環境対応とリサイクル技術」,
p.300-310, 技術情報協会 (2022).
4) 田中亮, 藤井裕也, 木田拓充, 中山祐正, 塩野毅, "含ホウ素モノマーの共重合によるポリオレフィンの機能化"
in「次世代ポリオレフィン総合研究」, 15, p.10-14, 三恵社
(2022).
5) 田中亮, 中島智哉, 中山祐正, 塩野毅,
"新規Brønsted酸助触媒DHBAの開発"
in「次世代ポリオレフィン総合研究」, 14, p.7-10, 三恵社
(2021).
6) Haobo Yuan, Ryo
Tanaka, Yuushou Nakayama, Takeshi Shiono, "Synthesis and Properties of
Star Polymers with Norbornene/alpha-olefin Gradient Copolymer Arms Using ansa-Fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)4]
Catalyst System" in「次世代ポリオレフィン総合研究」, 14, p.11-14, 三恵社
(2021).
7) 塩野毅, 田中亮, "[82]エチレンの重合, [83]オレフィンの配位連鎖移動重合,
[84]オレフィン, ジエンのチェーンウォーキング重合, [90]共役ジエンの高立体特異性重合" in「有機合成のための新触媒反応101」, 檜山為次郎, 野崎京子, 中尾佳亮, 中野幸司 編, 東京化学同人 (2021).
8) 中山祐正,
"生分解性コポリエステルの設計,合成とその特性" in「生分解,バイオマスプラスチックの開発と応用」, p.153-159 技術情報協会 (2020).
9) 岡島裕矢, 中山祐正, 塩野毅, 田中亮,
"二酸化炭素を用いたメチルアルミノキサンの調製" in 「次世代ポリオレフィン総合研究」, 次世代ポリオレフィン総合研究会編, Vol. 13, p. 47-50, 三恵社
(2019).
10) 中山祐正, 塩野毅, "高性能なコポリエステルの合成と生分解性" in「生分解性プラスチックの環境配慮設計指針」岩田忠久, 阿部英喜編, p.149-157, シーエムシー出版 (2019).
11) 中山祐正, 塩野毅 "バイオマス由来TPEの合成"
in「プラスチックの資源循環に向けたグリーンケミストリーの要素技術」澤口孝志編, p. 291-298, シーエムシー出版
(2019).
12) 中山祐正, 塩野毅 "生分解性を備えた熱可塑性エラストマーの設計と合成"
in「熱可塑性エラストマーの開発と市場 2019」, p.99-107, シーエムシー出版 (2019).
13) 田中亮, 塩野毅, "第8章 第3節: 配位重合によるステレオブロックポリマーの合成とその性質"
in 「次世代のポリマー・高分子開発,新しい用途展開と将来展望」, 技術情報協会 (2019).
14) 塩野毅, 田中亮, "第10章 配位重合によるオレフィンブロック共重合体の合成", in「ブロック共重合体の構造制御と応用展開」,p.
141-156, シーエムシー出版 (2018).
15) 田中亮, 渡子直紀, 中山祐正, 塩野毅,
"末端ボロン酸修飾を用いた星型ポリオレフィンの合成", in 「次世代ポリオレフィン総合研究」, 次世代ポリオレフィン総合研究会編, Vol. 12, p. 55-58, 三恵社
(2018).
16) 塩野毅, 田中亮, "第5章 第4節:錯体触媒によるポリオレフィンの精密合成と耐熱性向上" in 「高耐熱樹脂の開発事例集」,技術情報協会
(2018).
17) 田中亮, 川原友泰,神藤佑斗,中山祐正, 塩野毅, "修飾メチルアルミノキサン中のトリアルキルアルミニウムを簡便に除去する手法の開発" in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.11,
p.63-67, 三恵社 (2017).
18) 塩野毅, 田中亮(撮影協力), "プロピレンの配位重合"
in 「新・高分子合成実験法 第3巻:高分子合成実験 II」,冨田育義, 佐藤絵理子 監修,丸善 (2017).
19) 田中亮, 祐谷楓,佐藤弘樹,Peter Eberhardt,中山祐正, 塩野毅, "ネオジム触媒系を用いたステレオブロックポリイソプレンの合成"
in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.10, p.66-70, 三恵社
(2016).
20) 田中亮, 塩野毅, "第1章 1節:ポリプロピレンの精密合成" in 「ポリプロピレンの構造制御と複合化、成形加工技術」,技術情報協会
(2016).
21) 塩野毅,
"第7章:配位重合(1):プロピレンの立体特異的リビング重合" in 「CSJカレントレビュー20 精密重合が拓く高分子合成」,日本化学会編,p.90-95, 化学同人 (2016).
22) 田中亮, 柳瀬千絵,蔡正国,中山祐正, 塩野毅, "計算化学的手法によるフルオレニルアミドチタン錯体を用いたプロピレン重合の機構解析" in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.9,
p.27-30, 三恵社 (2015).
23) Yuushou Nakayama, Takeshi Shiono,
"Coordination Polymerization (Olefin and Diene)" in Encyclopedia
of Polymeric Nanomaterials, Kobayashi, S.; Mullen, K. Eds., Springer,
469-474 (2015). doi
24) Ryo Tanaka, Takeshi Shiono,
"Coordination Polymerization (Styrene and Polar Vinyl Monomers)" in Encyclopedia
of Polymeric Nanomaterials, Kobayashi, S.; Mullen, K. Eds., Springer,
474-480 (2015). doi
25) 田中亮, 廣瀬貴彰,中山祐正, 塩野毅, "新規含ホウ素アルミニウム錯体の合成とオレフィン重合触媒としての応用" in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.8,
p.59-62, 三恵社 (2014).
26) Takeshi Shiono, "1. Olefin
Polymerization with Metallocene Catalysts" in Organometallic Reactions
and Polymerization, Osakada, K. Ed., Springer,
2014.
2013年
学術論文
1) イタコン酸とイソソルビドの縮合重合によるポリエステルの合成とその性質
中山 祐正, 坂口 圭祐, 田中 亮, 蔡 正国, 塩野 毅
高分子論文集, 70, 559-564 (2013). doi

2) Modification effect of spherical zirconia
with SiCl4 as a support of methylaluminoxane for
heterogeneous single-site catalyst
Sasiradee Jantasee, Bunjerd Jongsomjit, Haruki Yano, Takeshi Shiono
Eur. Polym. J., 49, 4195-4200 (2013). doi

3) Copolymerization of Norbornene with ω-Alkenylaluminum as a Precursor Comonomer for Introduction
of Carbonyl Moieties
Jang-Woo Lee, Sasiradee Jantasee,
Bunjerd Jongsomsit, Ryo Tanaka, Yuushou Nakayama,
Takeshi Shiono
J. Polym. Sci. Part A: Polym.
Chem., 51, 5085-5090 (2013). doi

4) Copolymerization of Ethylene and 1-Hexene
with Ansa-Dimethylsilylene(fluorenyl) (t-butylamido)Dimethyltitanium
Complexes Activated by Modified Methylaluminoxane
Mingkwan Wannaborworn, Piyasan
Praserthdam, Bunjerd
Jongsomjit, Zhengguo Cai, Haruki Yano, Takeshi Shiono
Macromol. Chem. Phys., 214, 2584-2590 (2013). doi

5) Synthesis and properties of cationic
ionomers from poly(ester-urethane)s based on polylactide
Yuushou Nakayama, Takamichi Inaba, Yosuke Toda, Ryo
Tanaka, Zhengguo Cai, Takeshi Shiono, Hiroyuki
Shirahama, Chikara Tsutsumi
J. Polym. Sci. Part A: Polym.
Chem., 51, 4423-4428 (2013). doi

6) Facile Synthesis of Hydroxy-Functionalized
Cycloolefin Copolymer Using omega-Alkenylaluminium as
a Comonomer
Takeshi Shiono, Mitsunori Sugimoto, Tariqul Hasan, Zhengguo Cai
Macromol. Chem. Phys., 214, 2239-2244 (2013). doi

7) Synthesis of high-molecular weight block
copolymers of norbornene and propylene with methyl methacrylate initiated by fluorenylamido titanium complex
Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
Polym. Chem., 4, 3974-3980
(2013). doi

8) Copolymerization of ethylene/1-hexene with zirconocene/MAO catalyst supported on spherical zirconia
modified with BCl3, SiCl4, and glycerol
Sasiradee Jantasee, Takeshi
Shiono, Bunjerd Jongsomjit
Polym. Bull., 70, 1753-1768 (2013). doi
9) Copolymerization of ethylene with
1,1-disubstituted olefins catalyzed by ansa-(fluorenyl)(cyclododecylamido)dimethyltitanium
complexes
Yuushou Nakayama, Yuuichi Sogo, Zhengguo
Cai, Takeshi Shiono
J. Polym. Sci. Part A: Polym.
Chem., 51, 1223-1229 (2013). doi

学術論文(非SCI)
10) Copolymerization of Ethylene with
Isobutylene and Limonene Catalyzed by Titanium Complexes with Various ansa-(Fluorenyl)(alkylamido)
Ligand
Yuushou Nakayama, Yuuichi Sogo, Ryo Tanaka, Zhengguo Cai, Takeshi Shiono
Eng. J. 17, 7-12 (2013). doi
総説
11) Trialkylaluminum-Free
Modified Methylaluminoxane as a Cocatalyst for Living
Polymerization of Olefins
Takeshi Shiono
Adv. Polym. Sci., 258, 143-161 (2013). doi
12) 生分解性を備えた熱可塑性エラストマー
中山祐正、田中亮、塩野毅
Polyfile, 50(592), 28-32 (2013).
13) Precise synthesis of olefin block
copolymers using a syndiospecific living
polymerization system
Zheng-guo Cai, Hai-hui Su, Takeshi Shiono
Chinese J. Polym. Sci., 31, 541-549
(2013). doi
2012年
1) 2-(1-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinolylcobalt
dichloride: Synthesis and polyethylene wax formation
Wen-Hua Sun, Shaoliang Kong, Wenbin Chai, Takeshi
Shiono, Carl Redshaw, Xinquan Hu, Cunyue
Guo, Xiang Hao
Appl. Catal. A General, 447-448, 67-73
(2012). doi

2) Synthesis and Emission Behavior of
Liquid-Crystalline Main-Chain Polyesters Containing Carbazole and Oxadiazole
Moieties
Motoi Kinoshita, Kenji Takamura, Masuki Kawamoto,
Atsushi Shishido, Takeshi Shiono, Tomiki Ikeda
Mol. Cryst. and Liq. Cryst.,
563, 92-100 (2012). doi
3) Effect of Ga- and BCl3-modified
silica-supported [t-BuNSiMe2(2,7-t-Bu2Flu)]TiMe2/MAO catalyst on
ethylene/1-hexene copolymerization
Patcharaporn Kaivalchatchawal,
Sutheerawat Samingprai,
Takeshi Shiono, Piyasan Praserthdam,
Bunjerd Jongsomjit
Eur. Polym. J., 48, 1304-1312 (2012). doi

4)
2-[1-(2,6-Dibenzhydryl-4-chlorophenylimino)ethyl]-6-[1-(arylimino)ethyl]pyridyliron(II)
dichlorides: Synthesis, characterization and ethylene
polymerization behavior
Xiaoping Cao, Fan He, Weizhen Zhao, Zhengguo Cai, Xiang Hao, Takeshi Shiono, Carl Redshaw,
Wen-Hua Sun
Polymer, 53, 1870-1880 (2012). doi

5) Incorporation of L-lactide random
copolymers with Japanese cypress oil (alpha-pinene) using supercritical carbon
dioxide
Chikara Tsutsumi, Teruyuki Hara, Naohisa
Fukukawa, Kazuyuki Oro, Kazuaki Hata, Yuushou Nakayama, Takeshi Shiono
Green Chem., 14, 1211-1219 (2012). doi

総説
6) 生分解性を有する熱可塑性エラストマーの合成
中山祐正、塩野 毅
日本ゴム協会誌, 85, 229-233 (2012).
2011年
1) Highly thermostable and low birefringent
norbornene-styrene copolymers with advanced optical properties: A potential
plastic substrate for flexible displays
Hoang The Ban, Hideaki Hagihara, Yasuo Tsunogae, Zhengguo
Cai, Takeshi Shiono
J. Polym. Sci., Part A: Polym.
Chem., 49, 65-71 (2011). doi
2) Highly trans-1,4-specific
polymerization of 1,3-butadiene catalyzed by
[2,6-bis{(4S)-(-)-isopropyl-2-oxazolin-2-yl}pyridine] chromium complex
activated with modified methylaluminoxane
Yuushou Nakayama, Kenji Sogo, Zhengguo Cai, Hajime
Yasuda, Takeshi Shiono
Polym. Int., 60, 692-697 (2011).
doi
3) The influence of t-butyl and
cyclododecyl substitution on ethylene/1-hexene copolymerization using ansa-fluorenylamidodimethyltitanium derivatives
Patcharaporn Kaivalchatchawal,
Piyasan Praserthdam, Yuuichi Sogo, Zhengguo Cai,
Takeshi Shiono, Bunjerd Jongsomjit
Molecules, 16, 4122-4130 (2011). doi
4) Impregnation of poly(L-lactide-ran-cyclic
carbonate) copolymers with useful compounds with supercritical carbon dioxide
Chikara Tsutsumi, Naohisa Fukukawa, Jun Sakafuji,
Kazuyuki Oro, Kazuaki Hata, Yuushou Nakayama, Takeshi Shiono
J. Appl. Polym. Sci., 121, 1431-1441
(2011). doi
5) High activity of rare earth tetrahydroborates for ring-opening polymerization of omega-pentadecalactone
Yuushou Nakayama, Naoki Watanabe, Keisuke Kusaba, Kenta Sasaki, Zhengguo Cai, Takeshi Shiono, Chikara Tsutsumi
J. Appl. Polym. Sci., 121, 2098-2103
(2011). doi
6) 架橋型モノシクロペンタジエニルアミドジメチルチタン錯体を用いたプロピレン重合におけるシクロペンタジエニル配位子の効果
西井圭, 塩野毅
高分子論文集, 68, 341-344 (2011). doi
7) ピリジンチオラート配位子を有するハーフチタノセン錯体を用いたエチレンおよびスチレンの重合
中山祐正, 谷本匡哉, 蔡正国, 塩野毅
高分子論文集, 68, 457-463 (2011). doi
学術論文(非SCI)
8) Activated carbons containing dispersed
metal oxide particles for removal of methyl mercaptan in air
Hisashi Tamai, Miki Nakamori, Masayoshi Nishikawa, Takeshi Shiono
Mater. Sci. Appl., 2, 49-52 (2011). doi
9) Production of functional carbon by
iron-catalyzed carbonization of biomass - effect of washing with acid followed
by atmospheric oxidation on the electroconductivity of crystallized mesoporous
wood carbon
Tsutomu Suzuki, Tatsuya Shinomoto, Hiroshi Matsuzaki, Kyoko Suzuki, Noriyasu
Okazaki, Yukie Saito, Hidetoshi Kita, Hisashi Tamai
Trans. Mater. Res. Soc. Jpn., 36,
417-420 (2011).
総説
10) Living polymerization of olefins with ansa-dimethylsilylene(fluorenyl)(amido)dimethyltitanium-based catalysts
Takeshi Shiono
Polym. J., 43, 331-351 (2011). doi
11) オレフィン重合の最近の展開
中山祐正, 蔡正国, 塩野毅
成形加工, 23, 518-523 (2011).
2010年
学術論文
1) Efficient molecular weight control with trialkylaluminum in ethylene/norbornene copolymerization by
[Ph2C(Flu)(3-MeCp)]ZrCl2/methylaluminoxane catalyst
Tomoyuki Tada, Zhengguo Cai, Yuushou Nakayama,
Takeshi Shiono
Macromol. Chem. Phys., 211, 2132-2137 (2010). doi
2) Synthesis of stereoblock
polypropylene by change of temperature in living polymerization
Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
Macromol. Res., 18, 737-741 (2010). doi
3) Additive effects of alkylaluminium
compounds on propylene-1,3-butadiene copolymerization using isospecific
zirconocene catalysts
Takeshi Ishihara, Hoang The Ban, Hideaki Hagihara, Takeshi Shiono
J. Organomet. Chem., 695, 1694-1699
(2010). doi
4) Highly active living random
copolymerization of norbornene and 1-alkene with ansa-fluorenylamidodimethyltitanium
derivative: substituent effects on fluorenyl ligand
Zhengguo Cai, Ryotaro Harada, Yuushou Nakayama,
Takeshi Shiono
Macromolecules, 43, 4527-4531 (2010). doi
学術論文(非SCI)
5) Preparation of activated carbons from
polymer/carbon black composites as an EDLC electrode
Hisashi Tamai, Mitsunori Nishita, Takeshi Shiono
J. Mater. Sci. Eng. Adv. Technol., 1, 121-134 (2010).
総説
6) 架橋型フルオレニルアミドジメチルチタン錯体によるオレフィンのリビング配位重合
塩野毅
触媒, 52, 540-546 (2010).
2009年
1) Highly active syndiospecic
living polymerization of higher 1-alkene with ansa-fluorenylamidodimethyltitanium
complex
Zhengguo Cai, Masayoshi Ohmagari, Yuushou Nakayama,
Takeshi Shiono
Macromol. Rapid Commun., 30, 1812-1816 (2009). doi
2) Synthesis of Regioblock
Polybutadiene with CoCl2-Based Catalyst via Reversible Coordination of Lewis
Base
Zhengguo Cai, Masahito Shinzawa, Yuushou Nakayama,
Takeshi Shiono
Macromolecules, 42, 7642-7643 (2009). doi
3) A highly active catalyst composed of ansa-fluorenylamidodimethyltitanium derivative for
propene polymerization
Takeshi Shiono, Ryotaro Harada, Zhengguo Cai, Yuushou
Nakayama
Top. Catal., 52, 675-680 (2009). doi
4) Preparation of Pd supported mesoporous
activated carbons and their catalytic activity
Hisashi Tamai, Nobuaki Uragawa, Hajime Yasuda
Mater. Chem. Phys., 114, 10-13 (2009). doi
5) Ring-opening polymerization of six-membered
cyclic esters catalyzed by tetrahydroborate complexes
of rare earth metals
Yuushou Nakayama, Kenta Sasaki, Naoki Watanabe, Zhengguo
Cai, Takeshi Shiono
Polymer, 50, 4788-4793 (2009). doi
2008年
1) Random copolymerization of norbornene with
higher 1-alkene with ansa-fluorenylamidodimethyltitanium
catalyst
Takeshi Shiono, Mitsunori Sugimoto, Tariqul Hasan, Zhengguo Cai, and Tomiki Ikeda
Macromolecules, 41, 8292-8294 (2008). doi
2) Substituent effects of tert-butyl
groups on fluorenyl ligand of [t-BuNSiMe2Flu]ZrMe2
Zheng-guo Cai, Yuushou Nakayama, and Takeshi Shiono
Chin. J. Polym. Sci., 26, 575-578
(2008). doi
3) Facile synthesis of tailor-made stereoblock polypropylenes via successive variation of
monomer pressure
Zhengguo Cai, Yuushou Nakayama, and Takeshi Shiono
Macromolecules, 41, 6596-6598 (2008). doi
4) Catalytic synthesis of a monodisperse
olefin block copolymer using a living polymerization system
Zhengguo Cai, Yuushou Nakayama, and Takeshi Shiono
Macromol. Rapid Commun., 29, 525-529 (2008). doi
5) A new approach for controlling birefringent
property of cyclic olefin copolymers
Hoang The Ban, Hideaki Hagihara, Kei Nishii, Yasuo Tsunogae, Shuichi Nojima,
and Takeshi Shiono
J. Polym. Sci., Part A: Polym.
Chem., 46, 7395-7400 (2008). doi
6) Highly active copolymerization of ethylene
and dicyclopentadiene with [(1-t-BuN)SiMe2(1-C29H36)]TiMe2(THF) complex
Kei Nishii, Shigetaka Hayano, Yasuo Tsunogae, Zhengguo Cai, Yuushou Nakayama, and Takeshi Shiono
Chem. Lett., 37, 590-591 (2008). doi
7) Precise control of microstructure of
functionalized polypropylene synthesized by the ansa-zirconocene/MAO
catalysts
Hideaki Hagihara, Takeshi Ishihara, Hoang The Ban, and Takeshi Shiono
J. Polym. Sci., Part A: Polym.
Chem., 46, 1738-1748 (2008). doi
8) Ring-opening metathesis polymerization of
norbornene catalyzed by tantalum and niobium complexes with chelating O-donor
ligands
Yuushou Nakayama, Naoaki Maeda, Hajime Yasuda, and
Takeshi Shiono
Polym. Int., 57, 950-956 (2008).
doi
9) Synthesis of poly(ester-urethane)s from hydroxytelechelic polylactide: Effect of initiators on
their physical and degradation properties
Yuushou Nakayama, Ryo Yamaguchi, Chikara Tsutsumi, and Takeshi Shiono
Polym. Degrad.
Stab., 93, 117-124 (2008). doi
10) Synthesis, characterization, and thermal
properties of ring-opening metathesis polynorbornenes and their hydrogenated
derivatives bearing various ester and cyano groups
Yasushi Nishihara, Seisuke Izawa, Yoshiaki Inoue,
Yuushou Nakayama, Takeshi Shiono, and Kentaro Takagi
J. Polym. Sci., Part A: Polym.
Chem., 46, 3314-3325 (2008). doi
11) チタン錯体触媒による炭化水素系モノマーのリビング重合
蔡正国, 塩野毅
有機合成化学協会誌, 66, 664-672 (2008). doi
2007年
1) Preparation of polyaniline coated activated
carbon and their electrode performance for supercapacitor
H. Tamai, M. Hakoda, T. Shiono, and H. Yasuda
J. Mater. Sci., 42, 1293-1298 (2007). doi
2) Synthesis of anilinonaphthoquinone
based nickel complexes and their application for olen
polymerization
M. Okada, Y. Nakayama, and T. Shiono
J. Organomet. Chem., 692, 5183-5189
(2007). doi
3) Synthesis and characterization of
norbornene-ethylene-styrene terpolymers with a substituted ansa-fuorenylamidodimethyltitanium-based catalyst
H. T. Ban, K. Nishii, Y. Tsunogae and T. Shiono
J. Polym. Sci., Part A: Polym.
Chem., 45, 2765-2773 (2007). doi
4) Homo- and copolymerization of norbornene
derivatives with ethene by ansa-fuorenylamidodimethyltitanium
activated with methylaluminoxane
T. Hasan, T. Ikeda, and T. Shiono
J. Polym. Sci., Part A: Polym.
Chem., 45, 4581-4587 (2007). doi
5) Copolymerization of propylene with
1,3-butadiene using isospecific zirconocene
catalysts
T. Ishihara, H. T. Ban, H. Hagihara, and T. Shiono
J. Polym. Sci., Part A: Polym.
Chem., 45, 5731-5740 (2007). doi
6) Effect of cocatalysts on the catalytic
activities of tantalum- and niobium-based catalysts for ring-opening metathesis
polymerization of norbornene
Y. Nakayama, M. Tanimoto, and T. Shiono
Macromol. Rapid Commun., 28, 646-650 (2007). doi
7) Living ring-opening metathesis
polymerization of exo-norbornenes bearing both cyano and ester functionalities by a well dened ruthenium catalyst
Y. Nishihara, Y. Inoue, A. T. Saito, Y. Nakayama, T. Shiono, and K. Takagi
Polym. J., 39, 318-329 (2007). doi
8) Synthesis of multiblock poly(L-lactide)-co-poly(epsiron-caprolactone) from hydroxy-telechelic
prepolymers prepared by using neodymium tetrahydroborate
Y. Nakayama, S. Okuda, H. Yasuda, and T. Shiono
React. Funct. Polym.,
67, 798-806 (2007). doi
9) チーグラー・ナッタ触媒
塩野毅
高分子, 56, 16-17 (2007).
10) 炭化水素系モノマーの立体特異的リビング重合
蔡正国, 塩野毅
高分子論文集, 64, 77-89 (2007).
11) 金属化合物添加による多孔質炭素の細孔制御
玉井久司
炭素, 227, 122-128 (2007).
2006年
1) A new approach to styrenic
thermoplastic elastomers: synthesis and characterization of crystalline
styrene-butadiene-styrene triblock copolymers
H. T. Ban, T. Kase, M. Kawabe, A. Miyazawa, T. Ishihara, H. Hagishara,
Y. Tsunogae, M. Murata, and T. Shiono
Macromolecules, 39, 171-176 (2006). doi
2) Stereospecific polymerization of propylene
with group 4 ansa-fluorenylamidodimethyl
complexes
K. Nishii, H. Hagihara, T. Ikeda, M. Akita, and T. Shiono
J. Organomet. Chem., 691, 193-201
(2006). doi
3) Preparation of
poly(3,3'-dialkynyl-2,2'-bithiophene-5,5'-diyl) with high coplanarity and
effective-conjugation system
T. Sato Z. Cai, T. Shiono, and T. Yamamoto
Polymer, 47, 37-41 (2006). doi
4) Living random copolymerization of propylene
and norbornene with ansa-fluorenylamidodimethyltitanium
complex: synthesis of novel syndiotactic polypropylene-b-poly(propylene-ran-norbornene)
Z. Cai, Y. Nakayama, and T. Shiono
Macromolecules, 39, 2031-2033 (2006). doi
5) Synthesis of crystallizable sydiotactic-atactic stereoblock
polypropylene using a living polymerization system
Z. Cai, Y. Nakayama, and T. Shiono
Kinet. Catal., 47, 274-277 (2006). doi
6) Characteristics of LLDPE/ZrO2 nanocomposite
synthesized by in-situ polymerization using a zirconocene/MAO
catalyst
P. Praserthdam, B. Jongsomjit, J. Panpranot,
M. Okada, and T. Shiono
Iran. Polym. J., 15, 433-439 (2006). link
7) Synthesis of uniquely branched polyethylene
by anilinonaphthoquinoneligated nickel complex
activated with tris(penta uorophenyl)borane
M. Okada, Y. Nakayama, T. Ikeda, and T. Shiono
Macromol. Rapid Commun., 27, 1418-1423 (2006). doi
8) Catalytic synthesis of monodisperse
polypropylene using a living polymerization system with ansa-fluorenylamidodimethyltitanium-based catalyst
Z. Cai, M. Shigemasa, Y. Nakayama, and T. Shiono
Macromolecules, 39, 6321-6323 (2006). doi
9) Alternating copolymer of bithiophene and dialkylbithiazole and its tendency to align on the surfaces
T. Yamamoto, S. Otsuka, K. Namekawa, H. Fukumoto, I.
Yamaguchi, T. Fukuda, N. Asakawa, T. Yamanobe, T.
Shiono, and Z. Cai
Polymer, 47, 6038-6041 (2006). doi
10) Comparative reactivity of exo- and endo-isomers in the Ru-initiated ring-opening
metathesis polymerization of doubly functionalized
norbornenes with both cyano and ester groups
Y. Nishihara, Y. Inoue, Y. Nakayama, T. Shiono, and K. Takagi
Macromolecules, 39, 7458-7460 (2006). doi
11) Effects of solvents in living
polymerization of propene with [t-BuNSiMe2(3,6-t-Bu2Flu)]TiMe2-MMAO
catalyst
T. Shiono, Z. Cai, and Y. Nakayama
Stud. Surf. Sci. Catal., 161, 47-52
(2006). doi
12) Synthesis of bis(imino)pyridine
complexes of group 5 metals and their catalysis for polymerization of ethylene
and norbornene
Y. Nakayama, N. Maeda, and T. Shiono
Stud. Surf. Sci. Catal., 161, 165-170
(2006). doi
13)Ethylene polymerization with an anilinonaphthoquinone-ligated nickel complex
M. Okada, Y. Nakayama, and T. Shiono
Stud. Surf. Sci. Catal., 161, 171-174
(2006). doi
14) Effects of temperature in syndiospecific living polymerization of propylene with [t-BuNSiMe2(3,6-t-Bu2Flu)]TiMe2-MMAO
catalyst
Z. Cai, Y. Nakayama, and T. Shiono
Stud. Surf. Sci. Catal., 161, 189-192
(2006). doi
15) Additive effects of dialkylaluminum
hydrides on propylene-1,3-butadiene copolymerization using an isospecific zirconocene catalyst
T. Ishihara, H. T. Ban, H. Hagihara, and T. Shiono
Stud. Surf. Sci. Catal., 161,197-200
(2006). doi
16) Propene polymerization by ansa-fluorenylamidodimethyltitanium activated with
SiO2-supported modi ed methylalminoxane
T. Shiono, T. Matsumae, K. Nishii, and T. Ikeda
Stud. Surf. Sci. Catal., 161, 241-244
(2006). doi
17) Effect of alpha-olefins on
copolymerization of ethylene and alpha-olefin with [t-BuNSiMe2Flu]TiMe2
catalyst
N. Intaragamjon, T. Shiono, B. Jongsomjit, and P. Praserthdam
Stud. Surf. Sci. Catal., 161, 271-274
(2006). doi
18) Elucidation of solvent effects on the
catalytic behaviors for [t-BuNSiMe2Flu]TiMe2 complex during
ethylene/1-hexene copolymerization
N. Intaragamjon, T. Shiono, B. Jongsomjit, and P. Praserthdam
Catal. Commun., 7, 721-727
(2006). doi
19) A comparative study ethylene/1-hexene
copolymerization with [t-BuNSiMe2Flu]TiMe2 catalyst via various
activators
N. Intaragamjon, T. Shiono, and P. Praserthdam
Stud. Surf. Sci. Catal., 159, 841-844
(2006). doi
20) Kinetic features of the cobalt dihalide/methylaluminoxane catalytic system in 1,3-butadiene
polymerization
D. C. D. Nath, C. M. Fellows, and T. Shiono
Macromol. Res., 14, 338-342 (2006). doi
21) Surface functionalization of mesoporous
and microporous activated carbons by immobilization of diamine
H. Tamai, K. Shiraki, T. Shiono, and H. Yasuda
J. Colloid Interface Sci., 295, 299-302 (2006). doi
22) Adsorption of methyl mercaptan on surface modi ed activated carbon
H. Tamai, H. Nagoya, and T. Shiono
J. Colloid Interface Sci., 300, 814-817 (2006). doi
23) Syntheses of group 4 transition metal
complexes bearing 2-pyridinethiolate ligands and their catalytic activities for
ethylene polymerization
Y. Takashima, Y. Nakayama, M. Hashiguchi, T. Hosoda, H. Yasuda, T. Hirao, and
A. Harada
Polymer, 47, 5762-5774 (2006). doi
24) 金属触媒による環状エステルの開環重合
中山祐正, 塩野毅
高分子加工, 55, 17-26 (2006).
25) 希土類触媒によるアクリル酸エステル類のリビング重合
中山祐正, 塩野毅
触媒, 48, 182-188 (2006).
2005年
1) Random copolymerization of propene and
norbornene with ansa-fluorenylamidodimethyltitanium-based
catalysts
T. Hasan, T. Ikeda, and T. Shiono
Macromolecules, 38, 1071-1074 (2005).doi
2) Polymerization of propylene with [t-BuNSiMe2Ind]TiMe2-MAO
catalyst systems
K. Nishii, T. Ikeda, M. Akita, and T. Shiono
J. Mol. Catal. A, 231, 241-246 (2005). doi
3) Hydrogenated 1,4-insertion of butadiene in
the copolymerization with propylene using an isospecific
zirconocene catalyst
T. Ishihara, and T. Shiono
J. Am. Chem. Soc., 127, 5774-5775 (2005). doi
4) Substituent efects
of tert-butyl groups on fluorenyl ligand in syndiospecific
living polymerization of propylene with ansa-fluorenylamidodimethyltitanium
complex
Z. Cai, T. Ikeda, M. Akita, and T. Shiono
Macromolecules, 38, 8135-8139 (2005). doi
5) Stereospecific sequential block copolymerizations of styrene and 1,3-butadiene with a
C5Me5TiMe3/B(C6F5)3/Al(oct)3 catalyst
H. T. Ban, Y. Tsunogae, and T. Shiono
J. Polym. Sci., Part A, Polym.
Chem., 43, 1188-1195 (2005). doi
6) Impact of diene addition on properties for
ethylene-propylene copolymerization with rac-Et[Ind]2ZrCl2/MAO
catalyst
B. Jongsomjit, S. Phoowakeereewiwat, S. Thongyai, T. Shiono, and P. Praserthdam
Mater. Lett., 59, 3771-3774 (2005). doi
7) Highly birefringent liquid-crystalline
polymers for photonic applications: synthesis of liquid-crystalline polymers
with sidechain azo-tolane mesogens
and their holographic properties
K. Okano, A. Shishido, O. Tsutsumi, T. Shiono, and T. Ikeda
J. Mater. Chem., 15, 3395-3401 (2005). doi
8) Effect of ester moieties in dye structures
on photoinduced reorientation of dyedoped liquid
crystals
M. Yaegashi, A. Shishido, T. Shiono, and T. Ikeda
Chem. Mater., 17, 4304-4309 (2005). doi
9) Photoinduced change in birefringence and
optical switching at near-infrared region based on photochemical phase
transition of azobenzene liquid crystals
H. Kurihara, A. Shishido, O. Tsutsumi, T. Shiono, and T. Ikeda
Mol. Cryst. Liq. Cryst.,
441, 173-184 (2005). doi
10) Novel liquid-crystalline phenylene-thienylene co-oligomers for photoinduced reorientation of
liquid crystals
M. Yaegashi, A. Shishido, T. Shiono, and T. Ikeda
Mol. Cryst. Liq. Cryst.,
441, 201-210 (2005). doi
11) Synthesis and properties of highly
birefringent azo-tolane liquid-crystalline polymers:
effect of the position of the tolane moiety in the
side chain
K. Okano, A. Shishido, T. Ikeda, and T. Shiono
Mol. Cryst. Liq. Cryst.,
441, 275-285 (2005). doi
12) Preparation and characterization of
azobenzene liquid-crystalline elastomer films with homeotropic alignment
M. Kondo, T. Maeda, A. Shishido, T. Ikeda, Y. Yu, M. Nakano, T. Shiono
Mol. Cryst. Liq. Cryst.,
441, 297-305 (2005). doi
13) Synthesis and electroluminescent
properties of liquid-crystalline polymers containing oxazole and carbazole
moieties in the same side chain
Y. M. Nam, M. Kawamoto, M. Kinoshita, T. Shiono, and T. Ikeda
Mol. Cryst. Liq. Cryst.,
443, 95-104 (2005). doi
14) Photoinduced alignment behavior of
poly(alkyl methacrylates) containing azobenzene moiety in the side chain
H.-B. Cha, A. Shishido, T. Shiono, and T. Ikeda
Mol. Cryst. Liq. Cryst.,
443, 201-209 (2005). doi
15) Effect of intensity of actinic light and
temperature on photochemical phase transition of azobenzene liquid crystals
probed by a nearinfrared laser beam
H. Kurihara, A. Shishido, O. Tsutsumi, T. Shiono, and T. Ikeda
Mol. Cryst. Liq. Cryst.,
443, 229-238 (2005). doi
16) Unique catalytic behavior of chromium
complexes having halogenated bis(imino)pyridine
ligands for ethylene polymerization
Y. Nakayama, K. Sogo, H. Yasuda, and T. Shiono
J. Polym. Sci.: Part A: Polym.
Chem., 43, 3368-3375 (2005). doi
17) Mesoporous activated carbon as electrode
for electric double layer capacitor
H. Tamai, M. Kunihiro, M. Morita, H. Yasuda
J. Mater. Sci., 40, 3703-3707 (2005). doi
18) Synthesis of pentavalent imidovanadium complexes and their catalyses
for the polymerization of ethylene and propylene
Y. Sato, Y. Nakayama, H. Yasuda
J. Appl. Polym. Sci., 97, 1008-1015
(2005). doi
19) Characteristics of the biodegradability
and physical properties of stereocomplexes between
poly(L-lactide) and poly(D-lactide) copolymers
H. Shirahama, A. Ichimaru,
C. Tsutsumi, Y. Nakayama, and H. Yasuda
J. Polym. Sci.: Part A: Polym.
Chem., 43, 438-454 (2005). doi
20) Comparison of Sm
complexes with Sn compounds for syntheses of copolymers composed of lactide and
cyclic carbonates and their biodegradabilities
Y. Nakayama, H. Yasuda, K. Yamamoto, C. Tsutsumi, R. Jerome, and P. Lecomte
React. Funct. Polym.,
63, 95-105 (2005). doi
21) Developments of chiral metallocenes
as polymerization catalysts
Y. Nakayama, and T. Shiono
Molecules, 10, 620-633 (2005). doi
22) シンプルプロセスによるポリオレフィンの高性能化・高機能化は可能か?
塩野毅, 石原毅
化学工業, 56, 801-805 (2005).
23) シングルサイト触媒によるオレフィンのリビング重合
蔡正国, 塩野毅
化学, 60, 74-75 (2005).
24) 遷移金属錯体触媒によるシクロオレフィンのビニル重合
中山祐正, 塩野毅
日本ゴム協会誌, 78, 453-460 (2005).
25) 金属触媒作用による炭素細孔体のナノ構造制御
玉井久司
炭素, 216, 47-52 (2005).
Books, Reports (2005-2013)
1) 田中亮, 中山祐正, 塩野毅, "プロピレン, ノルボルネン, メタクリル酸メチルからなるブロック共重合体の合成とその性質"
in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.7, p.49-52, 三恵社
(2013).
2) 塩野毅,
"触媒調製ハンドブック", 岩本正和監修, エヌ・ティー・エス
(2011).
3) 塩野毅,
"チーグラー触媒とともに30 年" in 「成型加工」, 23, 517 (2011).
4) 塩野毅, 中山祐正, 蔡正国, "配位重合"
in 「高分子の合成(下)―開環重合・重縮合・配位重合」,遠藤剛編,講談社
(2010).
5) Takeshi Shiono, Tomiki
Ikeda, Lee-Soon Park, "Foreword" in Mol. Cryst.
Liq. Cryst., 529, vii (2010).
6) 中山祐正,
"アルバータ大学への留学とその後" in 「財団ニュース(財団法人山田科学振興財団)」 12 (2010).
7) Takeshi Shiono, Tomiki
Ikeda, Lee-Soon Park, "Advanced Display Materials and Devices, (ADMD2009),
Part I. (Proceedings of the 13th International Symposium held at Hiroshima
University, Japan 23-24 July 2009). [In: Mol. Cryst.
Liq. Cryst., 2010; 529]", Taylor and Francis,
Inc. (2010).
8) Takeshi Shiono, Tomiki
Ikeda, Lee-Soon Park, "Advanced Display Materials and Devices, (ADMD2009),
Part II. (Proceedings of the 13th International Symposium held at Hiroshima
University, Japan 23-24 July 2009). [In: Mol. Cryst.
Liq. Cryst., 2010; 530]", Taylor and Francis,
Inc. (2010).
9) Takeshi Shiono, Tomiki
Ikeda, Lee-Soon Park, "Advanced Display Materials and Devices, (ADMD2009),
Part III. (Proceedings of the 13th International Symposium held at Hiroshima
University, Japan 23-24 July 2009). [In: Mol. Cryst.
Liq. Cryst., 2010; 531]", Taylor and Francis,
Inc. (2010).
10) Takeshi Shiono, Tomiki
Ikeda, Lee-Soon Park, "Advanced Display Materials and Devices, (ADMD2009),
Part IV. (Proceedings of the 13th International Symposium held at Hiroshima
University, Japan 23-24 July 2009). [In: Mol. Cryst.
Liq. Cryst., 2010; 532]", Taylor and Francis,
Inc. (2010).
11) 中山祐正,
"ハフニウム〜イリジウム" in 「元素111 の新知識 第2 版」,桜井弘編,p.299-315, 講談社 (2009).
12) 蔡正国, 塩野毅, "ジメチルシリレン架橋フルオレニルアミドジメチルチタン錯体によるプロピレンのシンジオ特異的リビング重合" in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.1,
p.106-113, 三恵社 (2008).
13) 萩原英昭, 飯塚豊, 石原毅, 尾崎裕之, 塩野毅, "プロピレンと極性基含有モノマーの共重合による機能化PP の合成とその性質" in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.2,
p.80-85, 三恵社 (2008).
14) H. T. Ban, 萩原英昭, 角替康男, 野島伸司, 塩野毅, "高耐熱低複屈折環状オレフィン共重合体の開発"
in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.2, p.86-94, 三恵社
(2008).
15) 塩野毅,
"配位重合による配列制御" in「精密高分子の基礎と実用化技術」,中濱清一監修,p.16-24
シーエムシー出版 (2008).
16) 塩野毅, "触媒便覧" 触媒学会編, 講談社 (2008).
17) Yuushou Nakayama, Yosuke Ikemoto, Ryo
Yamaguchi, Hajime Yasuda, and Takeshi Shiono, "Comparison of
polymerization catalysts for syntheses of hydroxytelechelic
polylactides", in Reactive and Functional Polymers Research Advances, M.
I. Barroso eds., p. 113-129, NOVA Science Publisher, New York, (2008).
18) 塩野毅,
"炭素材料の新展開", 日本学術振興会炭素材料第117 委員会
(2007).
19) 塩野毅,
"第5 版実験化学講座25 触媒化学・電気化学",
丸善, (2006).
20) 塩野毅,
"基礎高分子科学", 東京化学同人, (2006).
21) 塩野毅,
"エコマテリアルハンドブック", 丸善, (2006).
22) T. Shiono, K. Nomura, and M. Terano, "Process in ole n polymerization catalysts and
polyole n materials, studies in surface science and
catalysis 161", Elsevier, (2006).
23) 塩野毅, "高分子辞典第3版", 朝倉書店, (2005).
24) 塩野毅, 中山祐正, "第5 版実験化学講座26 高分子化学", 丸善, (2005).
25) H. Yasuda, Y. Nakayama, and H. Shirahama, "Handbook of biodegradable polymeric
materials and their applications", American Scientific Publishers, (2005).
26) 玉井久司,
"多孔質吸着材ハンドブック", フジテクノシステム, (2005).
2004年
1) "Supporting effects of methylaluminoxane on living polymerization of propylene
with a chelating (diamide)dimethyltitanium
complex"
H. Hagimoto, T. Shiono, and T. Ikeda, Macromol. Chem. Phys. vol. 205, no. 1, 19-16
(2004).
2) "Copolymerization of ethylene or
propylene with a-olefins containing hydroxy groups with zirconocene/methylaluminoxane catalyst"
H. Hagihara, K. Tsuchihara,
K. Takeuchi, M. Murata, H. Ozaki, and T. Shiono, J. Polym.
Sci., PART A, Polym. Chem. vol. 42, no. 1, 52-58
(2004).
3) "Effect of solvents of living
polymerization of propylene with [t-BuNSiMe2Flu]TiMe2-MMAO"
K. Nishii, T. Matsumae, E. O. Dare, T. Shiono,
and T. Ikeda, Macromol. Chem. Phys.
vol. 205, no. 3, 363-369 (2004).
4) "Copolymerization of propylene and
polar allyl monomer with zirconocene/methylaluminoxane catalyst: Catalytic synthesis of
amino-terminated isotactic polyproppylene"
H. Hagihara, K. Tsuchihara,
J. Sugiyama, K. Takeuchi, and T. Shiono, Macromolecules, vol. 37, no.
14, 5145-5148 (2004).
5) "Synthesis and characterization of
cis-polybutadiene-block-syn-polystyrenecopolymers
with a cyclopentadienyltitanium trichloride/modified methylaluminoxane catalyst"
H. T. Ban, Y. Tsunogae,
and T. Shiono, J. Polym. Sci., PART A, Polym. Chem. vol. 42, no. 11, 2698-2704 (2004).
6) "Highly efficient Ti-based Cctalyst systems for vinyl addition polymerization of
norbornene"
T. Hasan, T. Ikeda, and T. Shiono, Macromolecules,
vol. 37, no. 20, 7432-7436 (2004).
7) "Ethene-norbornene copolymer with high
norbornene content produced by ansa-fluorenylamidodimethyltitanium
complex using a suitable activator"
T. Hasan, T. Ikeda, and T. Shiono, Macromolecules,
vol. 37, no. 23, 8503-8509 (2004).
8) "A novel synthetic procedure for steteoblock poly(propylene) with a living polymerization
system"
K. Nishii, T. Shiono, and T. Ikeda, Macromol. Rapid Commun. vol. 25, no. 10, 1029-1032
(2004).
9) "Copolymerization of 3-butene-1-ol and
propylene with an isospecific zirconocene/methylaluminoxane catallyst"
H. Hagihara, K. Tsuchihara,
J. Sugiyama, K. Takeuchi, and T. Shiono, J. Polym.
Sci., PART A, Polym. Chem. vol. 42, no. 22,
5600-5607 (2004).
10) "Effect of cross-linking density on phoroinduced bending behavior of oriented
liquid-crystalline network films containing azobenzene"
Y. Yu, M. Nakano, A. Shishido, T. Shiono, T.
Ikeda, Chem. Mater. vol. 16, no. 9, 1637-1643 (2004).
11) "Photoinduced reorientation of liquid
crystals doped with thiophene having ester moieties"
M. Yaegashi, A. Shishido, T. Shiono, and T.
Ikeda, Trans. Mater. Res. Soc. Jpn. vol. 29,
955-958 (2004).
12) "Supporting effects of
silica-supported MAO with zirconocene catalyst on
ethylene//1-olefin copolymerization behaviors for LLDPE production"
B. Jongsomijit, P. Kaewkrajang,
T. Shiono, and P. Praserthdam, Ind. & Eng.
Chem. Res. vol. 43, no. 24, 7959-7963 (2004).
13) "Effect of aluminoxanes on kinetic
feature of 1-hexene polymerization with ansa-(fluorenylamido)dimethyltitanium"
T. Shiono, T. Matsumae, K. Nishii, and T.
Ikeda, Proceedings of the 3rd International Workshop on "Heterogeneous
Ziegler-Natta Polymerization", 65-70 (2004).
14) "Living random copolymerization of
ethene and norbornene using ansa-fluorenylamidodimethyltitanium
complex"
T. Hasan, T. Shiono, and T.Ikeda,
Macromol. Symp. vol. 213, no. 1,
123-130 (2004).
15) "極性基含有機能化ポリオレフィンの開発"
塩野毅, 萩原英昭, 月刊コンバーテック, vol. 377, 65-70 (2004).
16) "アルキルチタン錯体と担持型活性化剤によるプロピレンのリビング重合"
塩野毅, 触媒,
vol. 46, no. 8, 644-649 (2004).
17) "重合技術によるポリオレフィンへの極性付与の試み"
石原毅, 塩野毅, 日本接着学会誌, vol. 40, no. 12, 615-622 (2004).
18) "Random and block copolymerizations
of norbornene with other monomers catalyzed by novel Ni compounds involving N-
or O-donated ligands"
H. Suzuki, S. Matsumura, Y. Satoh, K. Sogoh, and H. Yasuda, React. Funct.
Polym. vol. 58, no. 2, 77-91 (2004).
19) "Random and block copolymerizations
of norbornene with conjugated 1,3-dienes catalyzed by novel Ni compounds
involving N- or O-donated ligands"
H. Suzuki, S. Matsumura, Y. Satoh, K. Sogoh, and H. Yasuda, React. Funct.
Polym. vol. 59, no. 3, 253-266 (2004).
20) "Synthesis of random and block
copolymers of lactides with 1,5-dioxepan-2-one and their biodegradability"
Y. Watanabe, H. Shirahama,
and H. Yasuda, React. Funct. Polym.
vol. 59, no. 3, 211-224 (2004).
21) "Comparison of Sm
complexes with Sn compounds for syntheses of copolymers composed of lactides
and e-caprolactone and their biodegradabilities"
H. Yasuda, K. Yamamoto, Y. Nakayama, C.
Tsutsumi, P. Lecomte, R. Jerome, S. McCarthy, and D. Kaplan, React. Funct. Polym. vol. 61, no. 2,
277-292 (2004).
22) "Developments of rare earth metal
catalysts for olefin polymerization"
Y. Nakayama and H. Yasuda, J. Organomet. Chem. vol. 689, no. 24, 4489-4498 (2004).
23) "Adsorption of tetraalkylammonium
ions on microporous and mesoporous activated carbons prepared from vinylidene
chloride copolymer"
H. Tamai, M. Kunihiro and H. Yasuda, J.
Colloid, Interface Sci. vol. 275, no. 1, 44-47 (2004).
24) "Bis(amido)titanium complexes having
chelating diaryloxo ligands bridged by sulfur or
methylene and their catalytic behaviors for ring-opening polymerization of
cyclic esters"
Y. Takashima, Y. Nakayama, T. Hirao, H. Yasuda
and A. Harada, J. Organomet. Chem. vol. 689,
no. 3, 612-619 (2004).
25) "Activity of samarocene
catalysts adsorbed on mesoporous silicates for the polymerization of methyl
methacrylate"
H. Yasuda, Y. Nakayama, Y. Satoh, Z. Shen, X.
Ni, M. Inoue and S. Namba, Polym. Int.
vol. 53, no. 11, 1682-1685 (2004).
26) "Block copolymerizations
of higher 1-olefins with traditional polar monomers using metallocene-type
single component lanthanide initiators"
H. Yasuda and Guillaume Desurmont,
Polym. Int. vol. 53, no. 8, 1017-1024
(2004).
27) "Controlled vinyl-sddition-type
polymerization of norbornene initiated by several cobalt complexes having
substituted terpyridine ligands"
Y. Sato, Y. Nakayama and H. Yasuda, J. Organomet. Chem. vol. 689, no. 4, 744-750 (2004).
28) "有機金属化合物を用いた新しい高分子材料の開発"
安田 源, Organometallic News, no. 3, 88-91
(2004).
2003年
1) "Preparation of Pt Dispersed Carbon
Particles from Polyimide Particles"
H. Tamai, S. Nakatsuchi,
and H. Yasuda, J. Mater. Sci. vol. 38, no. 9, 1859-1868 (2003).
2) "New Pt and Pt/Ru Supported Cabon
Particles for Polymer Electrolyte Fuel Cell"
H. Tamai, S. Nakatsuchi,
Y. Kera, and H. Yasuda, J. Mater. Sci. Lett. vol. 22, no. 2, 145-148
(2003).
3) "Simple Preparation and Catalytic
Activity of Pd Particles Dispersed Mesoporous Carbons from Poly(VDC/MA)
Containing Pt and Y Complexes"
H. Tamai, J. Ogawa, and H. Yasuda, J.
Colloid Interface Sci. vol. 260, no. 2, 312-316 (2003).
4) "Preparation of Highly Mesoporous and
High Surface Area Activated Carbons from Vinylidene Chloride Copolymer"
H. Tamai, M. Kouzu,
and H. Yasuda, Carbon, vol. 41, no. 8, 1678-1681 (2003).
5) "Highly Mesoporous Carbon Electrodes
for Electric Double-Layer Capacitor"
H. Tamai, M. Kouzu,
M. Morita, and H. Yasuda, Electrochem.
Solid State Lett. vol. 6, no. 10, A214-A217 (2003).
6) "Syntheses of Bis- and
Tetra(trimethylsilyl) Substituted Lanthanocene Methyl
Complexes and Their Catalyses for Polymerization of
MMA, CL, and lactide"
Y. Satoh, N. Ikitake,
Y. Nakayama, S. Okuno, and H. Yasuda, J. Organomet.
Chem. vol. 667, no. 1-2, 42-52 (2003).
7) "Synthesis, Structure, and Olefin
Polymerization Calysis of a Novel Vanadum
(III) 1,1-Bi-2-naphthoolate Complex"
Y. Sato, Y. Nakayama and H. Yasuda, J.
Appl. Polym. Sci. vol. 89, no. 6, 1659-1662
(2003).
8) "Ring-opening Metathesis
Polymerization of Norbornene with Catecholato
Complexes of Tungsten (VI) as Effective Catalyst Precursors"
Y. Nakayama, K. Katsuda, and H. Yasuda, Polym. J. vol. 35, no. 11, 896-900 (2003).
9) "Stereospecific Ring-Opening
Metathesis Polymerization of Cycloolefins Using Novel Molybdenum and Tungsten
Complexes Having Biphenolate Ligands. Development of
Crystalline Hydrogenated Poly(endo-dicyclopentadiene) and
Poly(norbornene)"
S. Hayano, H. Kurakata,
Y. Tsunogae, Y. Nakayama, Y. Sato, and H. Yasuda, Macromolecules,
vol. 36, no. 20, 7422-7431 (2003).
10) "Facile Syntheses of Bis[1-(arylimino)ethyl]pyridine-MoCl3/MMAO Catalytic System and
Their Dual Functions for ROMP of Norbornene and Linear Polymerization of
Ethylene"
K. Hiya, Y. Nakayama, and H. Yasuda, Macromolecules,
vol. 36, no. 21, 7916-7922 (2003).
11) "Stereospecific Polymerizations of
Conjugated Dienes by Single Site Iron Complexes Having Chelating N,N,N-Donor
Ligands"
Y. Nakayama, Y. Baba, H. Yasuda, K. Kawakita,
and N. Ueyama, Macromolecules, vol. 36, no. 21, 7953-7958 (2003).
12) "Biodegradations of Block Copolymers
Composed of L- or D,L-Lactide and Six- membered Cyclic Carbonates Prepred with Organolanthanoide
Initiators"
C. Tsursumi, K. Yamamoto, A. Ichimaru, M. Nodono, K. Nakagawa, and H. Yasuda, J. Polym. Sci. Polym. Chem. 41,
3572 (2003).
13) "Isospecific
polymerization of alkyl methacrylates with a bis(alkyl) complex and formation
of stereocomplexes with syndiotactic poly(alkyl
methacrylate)s"
G. Qi, Y. Nitto, A. Saiki, T. Tomohiro, Y.
Nakayama, H. Yasuda, Tetrahedrom, 59,
10409-10418 (2003).
14) "生分解樹脂の性能評価と分解速度の制御技術"
安田源, Material Stage, no. 3, 82 (2003).
15) "極性モノマ−と非極性モノマ−の共重合"
安田源, 化学,
vol. 58, no. 1, 62-63 (2003).
16) "有機金属化合物を用いた新規材料の開発"
安田源, 玉井久司, 炭素, no. 8, 145-146 (2003).
17) "夢の錯体合成−−新しい挑戦"
安田源, 未来科学,
no. 11, 71-73 (2003).
2002年
1) "Preparation and High Bacteriostatic
Action of the Activated Carbons Possessing Ultrafine Silver Particles"
S. Miyanaga, A. Hiwara, and H. Yasuda, Sci.
Tec. Adv. Mater. vol. 3, no. 2, pp. 103-109 (2002).
2) "Preparation of Noble Metal Particles
Dispersed Mesoporous Carbons and Their Functions"
H. Tamai, J. Ogawa, and H. Yasuda, Mol. Cryst. Liq. Cryst. vol. 388,
pp. 465-469 (2002).
3) "Preparation of Mesoporous Carbons
from Polymer Materials Using Organometallics"
H. Tamai, M. Kouzu,
and H. Yasuda, Mol. Cryst. Liq. Cryst. vol. 388, pp. 447-451 (2002).
4) "Simple Praparation
of TiO$_{2}$ Particles Dispersed Activated Carbons
and Their Photo-sterilization"
H. Tamai , N. Katsu, K. Ono, and H. Yasuda, J.
Mater. Sci. vol. 37, pp. 3175-3180 (2002).
5) "炭化フェノール樹脂のナノ細孔生成とその吸着特性"
玉井 久司, 長永 昭宏, 村上 一幸, 野中 俊晴, 佐々木 雅彦, 安田 源, 炭素 no. 205, pp. 226-230 (2002).
6) "Organo-rare-earth Initiated Living
Polymerization of Polar and Nonpolar Monomers"
H. Yasuda, J. Organomet.
Chem. vol. 647, no. 1-2, pp. 128-138 (2002).
7) "Maximizationof
the Molecular Weight of Poly[alkyl(meth)acrylate] Using SmMe(C5Me5)2(THF)
as an Initiator"
M. Tanabe, T. Sugimura, and H. Yasuda, React.
Func. Polym. vol. 52, no. 3, pp. 135-141 (2002).
8) "Synthesis and Structure of a
Chromium(III) Complex Coordinated by 1,1'-Bi-2-naphtholate Ligands and Its
Catalytic Acyivity for Ethylene Polymerization"
H. Ikeda, T. Monoi, Y. Nakayama, and H.
Yasuda, J. Organomet. Chem. vol. 648, no. 1-2,
pp. 226-230 (2002).
9) "Chromium Complexes Coordinated with
Chelating Disiloxane-1,3-diamido Ligands as Catalyst Precursors for Ethylene
Polymerization"
H. Ikeda, T. Monoi, Y. Nakayama, and H.
Yasuda, J. Organomet. Chem. vol. 642, no. 1-2,
pp. 156-162 (2002).
10) "キレート配位子を有する5,6および8族遷移金属錯体を用いたオレフィン重合"
中山 祐正, 緒方 敬治, 佐藤 嘉記, 馬場 勇志, 肥谷 幸司, 安田 源, 高分子論文集 vol. 59, no. 4, pp.
235-242 (2002).
11) "Homopolymerization
and Randam Copolymerization of Olefins with
Amino-substituted Cyclopentadienylchromium
Complexes"
K. Ogata, Y. Nakayama, and H. Yasuda, J. Polym. Sci. Polym.Chem. vol.
40, pp. 2759-2771 (2002).
12) "Synthesis of cis-Dichloride
Complexes of Group 6 Transition Metals Bearing Alkyne and Chalcogen-bridged
Chelating Bis(aryloxo) Ligands as Catalyst Precursors
for Ring-opening Metathesis Polymerization"
Y. Takashima, Y. Nakayama, H. Yasuda, A.
Nakamura, and A. Harada, J. Organomet. Chem.
vol. 654, no. 1-2, pp. 74-82 (2002).
13) "Synthesis of Novel Oxo Complexes of
Tungsten and Molybdenum with Various Charcogen-bridged
Chelating Bis(aryloxo) Ligands and Their Catalytic
Behavior for Ring-opening Metathesis Polymerization"
Y. Takashima, Y. Nakayama, H. Yasuda, and A.
Harada, J. Organomet. Chem. vol. 651, no. 1-2,
pp. 114-123 (2002).
14) "O,S,O−およびO,N,O−キレート三座配位子を有するタングステン錯体の開環メタセシス重合触媒挙動"
高島 義徳, 中山 祐正, 安田 源, 中村 晃, 原田 明, 高分子論文集 vol. 59, no. 6, pp. 298-308 (2002).
15) "Polymerization of Cyclic Esters
Catalyzed by Titanium Complexes Having Chalcogen-bridged Chelating Daryloxo Ligands"
Y. Takashima, Y. Nakayama, K. Watanabe, T. Itono, N. Ueyama, A. Nakamura, H. Yasuda, A. Harada, and J.
Okuda, Macromolecules, vol. 35, no. 20, pp. 7538-7544 (2002).
16) "Steric Isomerization of Alkyne-dialkyltungsten Complexes with a Chelating Diarloxo Ligand: Crystal Structures of Cs- and
C1-W(h2-RCCR)[2,2'-S(4-Me-6-R'C6H2O)2](CH2SiMe3)2"
Y. Takashima, Y. Nakayama, H. Yasuda, A.
Nakamura, and A. Harada, J. Organomet. Chem. vol.
664, no. 1-2, pp. 234-244 (2002).
17) "Highly Biodegradable Copolymers
Composed of Chiral Depsipeptide and L-Lactide Units
with Favorable Physical Properties"
H. Shirahama, A.
Tanaka, and H. Yasuda, J. Polym. Sci. Polym. Chem. vol. 40, no. 3, pp. 302-316 (2002).
18) "Enzymatic Degradations of Copolymers
of L-Lactide with Cyclic Carbonates"
C. Tsutsumi, K. Nakagawa, H. Shirahama, and H.Yasuda, Macromol. Biosci. vol.
2, no. 5, pp. 223-232 (2002).
19) "希土類錯体を用いたアクリルポリマーの重合と粘着剤への応用"
筧 鷹麿, 川口 佳秀, 安田 源, 接着 vol. 46, no. 12, pp. 548-553 (2002).
2001年
1) "Utilization of Activated Carbon Fiber
with Mesopore Structure for Electric Double Layer Capacitors"
M. Morita, S. Watanabe, M. Ishikawa, H, Tani,
H. Yasuda, Electrochemistry, 69, 462-466 (2001).
2) "New Carbon Materials from Pitch
Containing Organotin Compounds for Anode of Lithium Ion Batteries"
H. Tamai, S. Matsuoka, M. Ishihara, H. Yasuda,
Carbon, 39, 1515-1523 (2001).
3) "Antibacterial Activated Carbon
Prepared from Pitch Containing Organometallics"
H. Tamai, N. Katsu, K. Ono, H. Yasuda, Carbon,
39, 1963-1969 (2001).
4) "トリアルキルゲルミルメタクリレート共重合ポリマーの合成およびその船底防汚機能"
玉井久司, 河合弘幸, 松田隆臣, 中村直哉, 坪井 誠, 安田 源, 高分子論文集, 58, 611-616 (2001).
5) "Synthesis of Monodisperse Poly(butyl
acrylate) Initiated by SmMe(C5Me5)2(THF) and Its
Adhesive Properties After Crosslinking by the Electron Beam Irradiation"
Y. Kawaguchi, H. Yasuda, J. Appl. Polym. Sci., 80, 432-437 (2001).
6) "Unique Dual Functions of
La(C5Me5)[CH(SiMe3)2]2(THF) for Non-polar and Polar Monomers"
K. Tanaka, M. Furo, E. Ihara, H. Yasuda, J.
Polym. Sci., Polym. Chem.
Ed., 39, 1382-1390 (2001).
7) "Synthesis of End Functionalized Low
Molecular Weight Poly(butyl acylate) and Its Elongation Using a
Diisocyanate"
Y. Kawaguchi, H. Yasuda, React. Fucnt. Polym., 46, 185
(2001).
8) "Synthesis and Olefin Polymerization
Catalysis of New Trivalent Samarium and Yttrium Complexes with Bridging
Bis(cyclopentadienyl) Ligands"
E. Ihara, S. Yoshioka, M. Furo, K. Katsura, H.
Yasuda, S. Mohri, N. Kanehisa,
Y. Kai, Organometallics, 20, 1752-1761 (2001).
9) "Rare Earth Metal Initiated
Polymerizations of (Meth)acrylates and Block Copolymerizations
of Olefins with Polar Monomers"
H. Yasuda, J. Polym.
Sci. Polym. Chem., 39, 1955-1959 (2001).
10) "Supercritical CO2-Induced Stereocomplex Formation of High Stereoregular Isotactic
Poly(methyl methacrylate) and Syndiotactic Poly(methyl methacrylate) Blends:
Effect of Molecular Weight on Crystalline Structure"
T. Mizumoto, N. Sugimura, M. Moritani, H.
Yasuda, Y. Sato, H. Masuoka, Macromolecules, 34, 5200-5204
(2001).
11) "Polymerization of styrene with a
simple rare earth metal initiator"
T. Hayakawa, Y. Nakayama, H. Yasuda, Polym. Int., 50, 1260-1264 (2001).
12) "Polymerization of methyl methacylate initiated by silica supported
(C5Me5)2SmMe(THF)"
Y. F. Zhang, X. F. Ni, Z. Q. Shen, H. Yasuda, Chem.
J. Chinese Univ., 22, 1778 (2001).
13) "Polymerization of methyl
methacrylate with samarocene complex supported on
mesoporous silica"
X. F. Ni, Z. Q. Shen, H. Yasuda, Chinese
Chem. Lett., 12, 821 (2001).
14) "Polymerization of Methyl
Methacrylate with Homogeneous Organopalladium/MMAO Systems"
E. Ihara, Y. Maeno, H. Yasuda, Macromol. Chem. Phys, 202, 1518-1523
(2001).
15) "Ethylene Polymerizations with
Alkyl-, Disilylamino- and Cyclopentadinenyl
Chromium/MAO Initiators"
H. Ikeda, T. Monoi, K. Ogata, H, Yasuda, Macromol. Chem. Phys, 202, 1806-1811
(2001).
16) "Synthesis of Poly(lactide-ran-MOHEL)
and Its Biodegradation with Proteinase K"
H. Shirahama, K. Mizuma, K. Umemoto, H. Yasuda, J. Polym.
Sci., Polym. Chem. Ed., 39, 1374-1381
(2001).
17) "Synthesis and Enzymatic Degradation
of High Molecular Weight Aliphatic Polyesters"
H. Shirahama, Y.
Kawaguchi, M. S. Aldin, H. Yasuda, J. Appl. Polym.
Sci., 80, 340-347 (2001).
18) "Synthesis and Biodegradability of
Monoalkylated Caprolactone Copolymers"
H. Shirahama, N.
Kanamori, H. Yasuda, J. Oleo. Sci., 50, 49 (2001).
19) "Biodegradation of Copolymers
Composed of Optically Active L-Lactide and (R)- or (S)-1-Methyltrimethylene
Carbonate"
C. Tsutsumi, H. Yasuda, J. Polym. Sci., Polym. Chem., 39,
3916-3927 (2001).
20) "光学活性L-ラクチド/1-トリメチレンカーボネート共重合体の合成と酵素分解性"
堤主計, 中川克彦, 白浜博幸, 安田 源, 高分子論文集, 58,
245 (2001).
21) "Synthesis of supine-prone
bis(diene)tungsten complexes bearing catecholate and diphenylacetylene
ligands"
Y, Nakayama, H. Saito, N. Ueyama, A. Nakamura J.
Organomet. Chem., 627, 221-225 (2001).
22) "Synthesis of a Novel Oxotungsten(VI) Complex Having a Chelating Bis(aryloxo) Ligand and Its Catalytic Behavior for Ring-Opening
Metathesis Polymerization"
Y. Takashima, Y. Nakayama, A. Harada, Chem.
Lett., 6, 488-489 (2001).
2000年
1) "Characteristics and Catalytic
Activity of Carbons Obtained from Pitch Containing Noble Metal Complexes"
H. Tamai, Y. Kataoka, F. Nishiyama, H. Yasuda,
Carbon, 38, 899-906 (2000).
2) "NO Decomposition by Ultrafine Noble
Metals Dispersed on the Rare Earth Phosphate Hollow Particles"
H. Tamai, T. Ikeya, F. Nishiyama, H. Yasuda,
K. Iida, S. Nojima, J. Mater. Sci., 35, 4945-4953 (2000).
3) "Preparation of Carbons from Pitch
Containing Polysilane and their Anode Properties for
Lithium-ion Batteries"
H. Tamai, H. Sugahara, H. Yasuda, J. Mater.
Sci. Lett., 19, 53-56 (2000).
4) "Coordination of Allenyl/propargyl
Group to Samarium(III): the First Crystal Structures of h3-Allenyl and
h1-Propargyl Lanthanide Complexes"
M. Tanaka, H. Yasuda, N. Kanehisa,
T. Maruo, Y. Kai, J. Organomet. Chem., 613,
26-32 (2000).
5) "New Approach to Block
Copolymerization of Ethylene with Polar Monomers by the Unique Catalytic
Function of Organolanthanide Complexes"
G. Desurmont, M.
Tanaka, Y. Li, H. Yasuda, T. Tokimitsu, S. Tone, A. Yanagase, J. Polym. Sci., Part
A: Polym. Chem., 38, 4095-4109 (2000).
6) "High Polymerization of Methyl
Methacrylate with Organonickel/MMAO Systems"
E. Ihara, T. Fujimura, H. Yasuda, T. Maruo, N.
Kanehisa, Y. Kai, J. Polym.
Sci., Part A: Polym. Chem., 38, 4764-4775
(2000).
7) "First Controlled Block Copolymerizations of Higher 1-Olefins with Polar Monomers
Using Metallocene Type Single Component Lanthanide Initiators"
G. Desurmont, T. Tokimitsu, H. Yasuda, Macromolecules, 33,
7679-7681 (2000).
8) "Reaction Pathway for the Formation of
Binuclear Samarocene Hydride from Monomeric Alkyl Samarocene Derivative and the Effective Catalysis of Samarocene Hydride for the Block Copolymerization of
Ethylene with Polar Monomers"
G. Desurmont, Y. Li,
H. Yasuda, T. Maruo, N. Kanehisa, Y. Kai, Organometallics,
19, 1811-1813 (2000).
9) "Alternative h5- and h6-Bonding Modes
for Bis(fluorenyl)lanthanide Complexes by Reactions with AlR3 and Succesive Addition of THF"
H. Nakamura, Y. Nakayama, H. Yasuda, T. Maruo,
N. Kanehisa, Y. Kai, Organometallics, 19,
5392-5399 (2000).
10) "Synthesis and Biodegradability of
Copolymers of Ethylene Carbonate with Lactones"
H. Shirahama, A. Kanetani, H. Yasuda, Polym.
J., 32, 280-286 (2000).
11) "Organo Transition Metal Initiated
Living Polymerizations"
H. Yasuda, Prog. Polym.
Sci., 25, 573-626 (2000).
12) "Synthesis and Adhesion Properties of
Novel Syndiotactic Block Copolymers of Alkyl (Meth)acrylate with Methacrylic
Acid and its Analogues"
T. Kakehi, M.
Yamashita, H. Yasuda, React. Funct. Polym., 46, 81-94 (2000).
13) "Synthesis of end-functionalized low
molecular weight poly(butyl acrylate) and its elongation using a
diisocyanate"
Y. Kawaguchi, H. Yasuda, React. Funct. Polym., 46,
185-192 (2000).
14) "New Approaches in Polymerizations
Using Transition Metal Complexes"
H. Yasuda, E. Ihara, T. Fujimura, Y. Maeno, K.
Ogata, Y. Sato, G. Desurmont, 有機合成化学協会誌, 58, 1084-1094 (2000).
15) "Activation of a trans-Dialkyl(oxo)tungsten Complex Bearing a
2,6-Pyridinediethanolate Ligand with Aluminum Cocatalysts to Catalyze the ROMP
of Norbornene"
Y. Nakayama, N. Ikushima,
N. Ueyama, A. Nakamura, A. Harada, Chem. Lett., 434-435 (2000).
16) "Titanium Complexes Having Chelating Diaryloxo Ligands Bridged by Tellurium and Their Catalytic
Behaviors for Polymerization of Ethylene"
Y. Nakayama, K. Watanabe, N. Ueyama, A.
Nakamura, A. Harada, J. Okuda, Organometallics, 19, 2498-2503
(2000).
Books, Reports (2000-2004)
1) 塩野 毅
"触媒活用大辞典", 工業調査会 (2004).
2) 安田源,
"脱石油素材化に向けた生分解性プラスチックの高機能化とその応用", エヌ・ティー・エス (2003).
3) 安田 源,
"化学ってそういうこと!夢広がる分子の世界", 日本化学会 (2003).
4) H. Yasuda, "Novel h5-h6 Rearrangement
of Bis(fluorenyl)lanthanide Complexes by the Addition of AlR3", in Perspectives
in Organometallic Chemistry, C. G. Screttas and
B. R. Steele eds., Royal Society of Chemistry pp.152 (2003).
5) H. Tamai, and H. Yasuda, "Encyclopedia
of Surface and Colloid Science "
Marcel Dekker, Inc. (2002).
6) H. Yasuda, G. Desurmont,
"Future Technology of Polyolefin and Olefin Polymerization Catalysis
"
Technogy
and Education Publisher (2002).
7) 安田 源,
"高分子辞典"
朝倉出版 (2002).
8) 安田 源,
"OM News "
近畿化学協会有機金属部会 (2002).
9) 安田 源,
"有機合成における触媒反応"
東京化学同人 (2002).
10) 安田 源,
"希土類金属錯体を用いたアクリルポリマーの重合と粘着剤への応用"
高分子刊行会 (2002).
11) 白浜 博幸, 安田 源, "グリーンプラスチック最新技術”新規ラクチド共重合体の合成”"
シーエムシー (2002).