2026

学術論文

6)Effect of the carbon numbers of dicarboxylic acids and diols on marine biodegradation of aliphatic polyesters

Yuushou Nakayama, Tomoka Shuto, Ryo Tanaka, Takeshi Shiono, Shodai Hino, Norioki Kawasaki, Naoko Yamano, Atsuyoshi Nakayama

Polym. Degrad. Stab., , Accepted (2026).

BOD biodegradation (%) of PEm-n in seawater at 27°C for 28 d

  

 

5)One-shot activating reagent of neodymium carboxylate for highly cis-1,4 specific butadiene polymerization

Yu Jia, Kenji Komaguchi, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka

Polym. Chem., , Accepted (2026).

 

4)One-shot activating reagent of neodymium carboxylate for highly cis-1,4 specific butadiene polymerization
Yu Jia, Toru Wada, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Polym. Chem., 17, 1069-1074 (2026). doi

Graphical abstract: A one-shot activating reagent of neodymium carboxylate for highly cis-1,4 specific butadiene polymerization

 

3)Synthesis of boronic acid-crosslinked diene-based polymers via free-radical copolymerization
Manami Kawamoto, Shin-ichi Kihara, Subrata Dolui, Mari Nishizono, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Chem. Asian J., 21, e70572 (2026). doi

 

2)Synthesis of Long-chain Branched Multiblock Polyolefin Composed of Isotactic Polypropylene and Ethylene-propylene Copolymer via Polymer Cross-Metathesis
Yuta Yanagi, Takumitsu Kida, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
Polym. J., , (2025). doi

 

1)Enhanced Marine Biodegradability of Poly(Lactic Acid)-Based Polyurethanes via Alkylene Diglycolate Incorporation
Yuushou Nakayama, Chigen Kinoshita, Ryo Tanaka, Takeshi Shiono, Shodai Hino, Norioki Kawasaki, Naoko Yamano, Atsuyoshi Nakayama
Chem. Asian J., 21, e00901 (2026). doi

 

 

 

 

2025

学術論文

1)Multimodal polypropylene synthesis using cyclic borane cocatalyst
Daichi Oka, Shunsuke Nishiyama, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Organometallics, 44, 2156-2162 (2025). doi

Figure 1

 

2)A Simple Cocatalyst Modification Approach for Tuning Polyolefin Branching: Halogenated MAO in Nickel-Catalyzed Ethylene Polymerization
Yu Jia, Nao Harada, Toru Wada, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Polym. Chem., 16, 4381-4388 (2025). doi

Graphical abstract: A simple cocatalyst modification approach for tuning polyolefin branching: halogenated MAO in nickel-catalyzed ethylene polymerization

 

3)Physical properties and degradability of branched polylactide copolymers
Chikara Tsutsumi, Susumu Nakayama, Masaki Shiomi, Yuushou Nakayama
Polymer, 337, 128971 (2025). doi

Image 1

 

4) Enhancing Mechanical Properties and Crystallization Kinetics of Isotactic Polypropylene by Boronic Acid-Cross-Linked Additives
Kazuki Shimizu, Shin-ichi Kihara, Mikihiro Hayashi, Hiroyuki Koga, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Macromolecules, 58, 8143-8150 (2025). doi

 

総説・解説

5) 生分解性を備えた熱可塑性エラストマーの設計と合成
中山 祐正
ポリマーTECH, 27, 19-28 (2025). URL

6) 強度が改善されたポリ乳酸/セルロースナノファイバー複合体
中山 祐正
月刊プラスチックス, 7, 5-9 (2025). URL

 

 

 

2024

学術論文

1) Ring-Opening Homo- and Copolymerization of Cyclic Esters Catalyzed by Iron(III) Triflate
Yuushou Nakayama, Toshihiko Omori, Ryo Tanaka, Takeshi Shiono
Catalysts, 14, 945 (2024). doi

Graphical Abstract

 

3) Origin of the Two Major Types of Repeating Units in Poly(β-pinene) Obtained by Cationic Polymerization
Oluwaseyi Aderemi Ajala, Shogo Nakaichi, Toshiyuki Oshiki, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Macromolecules, 57, 9257-9264 (2024). doi

 

4) Biodegradable thermoplastic elastomers synthesized from C7–C10 aliphatic dicarboxylic acids, 2-methyl-1,3-propanediol, and L-lactide
Yuushou Nakayama, Takayoshi Matsu-ura, Ryo Tanaka, Takeshi Shiono, Shodai, Hino, Norioki Kawasaki, Naoko Yamano, Atsuyoshi Nakayama, Rie Tezuka, Kazuya Tanaka
Polym. Degrad. Stab., 229, 110978 (2024). doi

Scheme 1

 

5) Commodity Rubber Material with Reversible Cross-linking Ability: Application of Boroxine Cross-links to Ethylene-Propylene Rubber
Yusuke Bando, Shin-ichi Kihara, Hiroya Fujii, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Macromolecules, 57, 7565-7574 (2024). doi

 

7) A Bio-Based Tackifier Synthesized by Room-Temperature Cationic Copolymerization of Isobutene and β-Pinene
Oluwaseyi Aderemi Ajala, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Catalysts, 14, 402 (2024). doi

Graphical Abstract

 

9) Copolymerization of Ethylene with Functionalized 1,1-Disubstituted Olefins Using a Fluorenylamido-Ligated Titanium Catalyst
Oluwaseyi Aderemi Ajala, Moeko Ono, Yuushou Nakayama, Ryo Tanaka, Takeshi Shiono
Polymers, 16, 236 (2024). doi

Graphical Abstract

 

 

2023

学術論文

1) Selective synthesis of α-vinyl-ω-vinylidene-oligoisoprene as a macromonomer via ethenolysis of polyisoprene
Ryo Tanaka, Akane Shimmei, Riki Otsuka, Yuushou Nakayama, Takeshi Shiono
Polym. J., 56, 335-342 (2023). doi

 

2) Ring-Opening Polymerization of Lactones Catalyzed by Silicon-Based Lewis Acid
Yuushou Nakayama, Keiya Katagi, Ryo Tanaka, Takeshi Shiono
Int. J. Polym. Sci., , 4391372 (2023). doi

Details are in the caption following the image

 

4) Synthesis, Properties, and Biodegradability of Novel Sequence-Controlled Copolyesters Composed of Glycolic Acid, Dicarboxylic Acids, and C3 or C4 Diols
Yuushou Nakayama, Keitaro Fukumoto, Yuji Kusu, Ryo Tanaka, Takeshi Shiono, Norioki Kawasaki, Naoko Yamano, Atsuyoshi Nakayama
Polymers, 15, 1155 (2023). doi

 

総説・解説

6) Control of coordination polymerization behavior by counter-anionic effects
Ryo Tanaka, Oluwaseyi Aderemi Ajala, Yuushou Nakayama, Takeshi Shiono
Prog. Polym. Sci., 142, 101690 (2023). doi

 

2022

学術論文

1) Synthesis of chain-end functional polydienes using diene comonomer bearing boronic acid masked with diaminonaphthalene
Ryo Tanaka, Yuina Kuwabara, Yuushou Nakayama, Takeshi Shiono
Molecules, 27, 9007 (2022). doi

 

2) Impact of methylaluminoxane oxidation on the ethylene polymerization using Ni catalysts
Ryo Tanaka, Kenji Sogo, Kenji Komaguchi, Kazuki Ae, Yuushou Nakayama, Takeshi Shiono
Organometallics, 41, 3024-3031 (2022). doi

 

3) Synthesis of Granular Hydroxy‑Functionalized Ultra‑high‑molecular‑weight Polyethylene and Its Fiber Properties
Haobo Yuan, Cong Long, Junrong Yu, Fuyou Ke, Takeshi Shiono, Zhengguo Cai
Adv. Fiber Mater. , 4, 786-794 (2022). doi

4) Star polymers with norbornene/1-octene gradient copolymer arms synthesized by an ansa-fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)4] catalyst system
Haobo Yuan, Takumitsu Kida, Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama, Shin-ichi Kihara, Takeshi Shiono
Polymer, 249, 124844 (2022). doi

Image 1

 

5) Selective alcoholysis of lactide catalyzed by bulky Lewis pairs of tris(pentafluorophenyl)borane and phosphines
Yuushou Nakayama, Kentaro Yamaguchi, Ryo Tanaka, Takeshi Shiono
Mol. Catal. , 519, 112121 (2022). doi

Image, graphical abstract

 

6) Cyclic olefin copolymer bearing pendant fluorenyl groups with high refractive index and low chromatic dispersion
Haobo Yuan, Takumitsu Kida, Yuma Ishitobi, Ryo Tanaka, Masayuki Yamaguchi, Yuushou Nakayama, Takeshi Shiono
Macromolecules, 55, 125-132 (2022). doi

 

7) An environmentally adaptable stereocomplex derived from lactide copolymers with improved UV shielding characteristics based on morphological changes
Chikara Tsutsumi, Susumu Nakayama, Yasuhiro Matsubara, Yuushou Nakayama, Takeshi Shiono
React. Funct. Polym., 173, 105148 (2022). doi

 

8) Polymerization of Styrene Derivatives Using Anilinonaphthoquinone-ligated Nickel Complexes and Thermal/Rheological Properties of the Produced Polymers
Samiul Islam Chowdhury, Takumitsu Kida, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
Macromol. Chem. Phys., 223, 2100402 (2022). doi

Details are in the caption following the image


総説・解説

9) 配列が制御された新規生分解性コポリマーの設計とその可能性
中山 祐正
MATERIAL STAGE, 21(10), 45-49 (2022).

12)生分解性を有する新規ポリエステル系共重合体の設計と合成
中山 祐正
日本画像学会誌, 61(3), 261-270 (2022).

 

 

2021

学術論文

2) Removal of mononuclear alkylaluminum species in aluminoxane using crosslinked polymer bearing bulky phenoxy groups
Ryo Tanaka, Mari Nishizono, Yuushou Nakayama, Takeshi Shiono
Polym. J., 53, 1187-1193 (2021). doi

 

4) Incorporation of boronic acid functionality into isotactic polypropylene and its application as crosslinking point
Ryo Tanaka, Hiroya Fujii, Takumitsu Kida, Yuushou Nakayama, Takeshi Shiono
Macromolecules, 54, 1267-1272 (2021). doi

 

5) Synthesis, Properties, and Biodegradabilities of Thermoplastic Elastomers made from 2-Methyl-1,3-propanediol, Glutaric Acid and Lactide
Lamya Zahir, Takumitsu Kida, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono, Norioki Kawasaki, Naoko Yamano, Atsuyoshi Nakayama
Life, 11, 43 (2021). doi

 

6) A Neutral, Noncoordinating, and Hydrocarbon-soluble Protic Cocatalyst for Olefin Polymerization
Tomoya Nakashima, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
ACS Catal., 11, 865-870 (2021). doi

 

7) Synthesis of thermoplastic elastomers with high biodegradability in seawater
Lamya Zahir, Takumitsu Kida, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono, Norioki Kawasaki, Naoko Yamano, Atsuyoshi Nakayama
Polym. Degrad. Stab., 184, 109467 (2021). doi

 

8) Synthesis and Properties of Block Copolymers Composed of Norbornene/Higher α-Olefin Gradient Segments Using ansa-Fluorenylamidodimethyltitanium‒[Ph3C][B(C6F5)4] Catalyst System
Haobo Yuan, Takumitsu Kida, Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
Polym. Chem., 12, 189-195 (2021). doi

Graphical abstract: Synthesis and properties of block copolymers composed of norbornene/higher α-olefin gradient segments using ansa-fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)4] catalyst system

 

総説

9) 配列が制御された新規生分解性コポリマーの設計と合成
中山 祐正
高分子, 70(1), 23-24 (2021).

 

 

2020

学術論文

1) Norbornadiene homopolymerization and norbornene/norbornadiene/1-octene terpolymerization by ansa-fluorenylamidotitanium-based catalysts
Hongyi Suo, Haobo Yuan, Ryo Tanaka, Yuushou Nakayama, Wen-Hua Sun, Takeshi Shiono
Polym. Chem., 11, 6803-6810 (2020). doi

Graphical abstract: Norbornadiene homopolymerization and norbornene/norbornadiene/1-octene terpolymerization by ansa-fluorenylamidotitanium-based catalysts

 

2) Synthesis and Properties of Biodegradable Thermoplastic Elastomers using 2-Methyl-1,3-propanediol, Succinic Acid and Lactide
Lamya Zahir, Takumistu Kida, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono, Norioki Kawasaki, Naoko Yamano, Atsuyoshi Nakayama
Polym. Degrad. Stab., 181, 109353 (2020). doi

 

3) Synthesis, properties, and biodegradation of sequential poly(ester amide)s containing gamma-aminobutyric acid
Yuushou Nakayama, Kazumasa Watanabe, Ryo Tanaka, Takeshi Shiono, Norioki Kawasaki, Naoko Yamano, Atsuyoshi Nakayama
Int. J. Mol. Sci., 21, 3674 (2020). doi

 

4) Synthesis and Properties of Gradient Copolymers Composed of Norbornene and Higher alpha-Olefins Using an ansa-Fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)4] Catalyst System
Haobo Yuan, Takumitsu Kida, Hyunchul Kim, Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
Macromolecules, 53, 4323-4329 (2020). doi

 

5) Effect of Ancillary Ligands as a Part of Counteranion in Neodymium-Catalyzed Isoprene Polymerization
Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
Organometallics, 39, 1855-1860 (2020). doi

6) Synthesis of norbornene/divinylbenzene copolymers catalyzed by anilinonaphthoquinone-ligated nickel complexes and their applications for the synthesis of graft polymers
Samiul Islam Chowdhury, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
J. Polym. Sci., 58, 1564-1570 (2020). doi

 

7) Synthesis, properties and biodegradation of periodic copolyesters composed of hydroxy acids, ethylene glycol, and terephthalic acid
Yuushou Nakayama, Wataru Yagumo, Ryo Tanaka, Takeshi Shiono, Kei Inumaru, Chikara Tsutsumi, Norioki Kawasaki, Naoko Yamano, Atsuyoshi Nakayama
Polym. Degrad. Stab., 174, 109095 (2020). doi

 

9) Coordination-insertion Copolymerization of Norbornene and p-Substituted Styrenes using anilinonaphthoquinone-ligated Nickel Complexes
Samiul Islam Chowdhury, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
Macromol. Chem. Phys., 221, 1900494 (2020). doi

10) Copolymerization of Norbornene and Conjugated Dienes Using Anilinonaphthoquinone-ligated Nickel Complexes
Samiul Islam Chowdhury, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
Polymer, 187, 122094 (2020). doi

総説

 

2019

学術論文

1) Impregnation of poly(L-lactide-ran-delta-valerolactone) with essential bark oil using supercritical carbon dioxide
Chikara Tsutsumi, Souta Manabe, Susumu Nakayama, Yuushou Nakayama, Takeshi Shiono
Sci. Rep., 9, 16326 (2019). doi

2) Effect of the number of arms on the mechanical properties of star-shaped cyclic olefin copolymer
Takumitsu Kida, Ryo Tanaka, Koh-hei Nitta, Takeshi Shiono
Polym. Chem., 10, 5578-5583 (2019). doi

3) Chain-walking polymerization of 3-heptene with phenyl substituted alpha-diimine nickel catalysts
Fuzhou Wang, Guoyong Xu, Qingshan Li, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
Polymer, 181, 121801 (2019). doi

4) Copolymerization of Ethylene and Fluoroalkylnorbornene Using Highly Active ansa-(Fluorenyl)(amido)titanium-Based Catalysts
Yanjie Sun, Chen Wang, Ryo Tanaka, Takeshi Shiono, Zhengguo Cai
Macromol. Chem. Phys., 220, 1900306 (2019). doi

5) Copolymerization of Norbornene and Styrene with Anilinonaphthoquinone-ligated Nickel Complexes
Samiul Islam Chowdhury, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
Polymers, 11, 1100 (2019). doi

6) Preparation of Methylaluminoxane from Carbon Dioxide
Yuuya Okajima, Yuushou Nakayama, Takeshi Shiono, Ryo Tanaka
Eur. J. Inorg. Chem., 2392-2395 (2019). doi

7) Cis-1,4 Specific Polymerization of 1,3-butadiene using PNP-pincer Ligated Iron(II) Complexes
Ryo Tanaka, Kenshi Ikeda, Yuushou Nakayama, Takeshi Shiono
Chem. Lett., 48, 525-528 (2019). doi

8) Optically Transparent Functional Polyolefin Elastomer with Excellent Mechanical and Thermal Properties
Xiangyang Song, Lixin Cao, Ryo Tanaka, Takeshi Shiono, Zhengguo Cai
ACS Macro Lett., 8, 299-303 (2019). doi

9) Stereospecific polymerization of conjugated dienes using neodymium alkylborohydride complexes
Ryo Tanaka, Yuto Shinto, Ryusei Matsuzaki, Yuushou Nakayama, Takeshi Shiono
Dalton Trans., 48 7267-7273 (2019). doi

10) ラクチドとε-カプロラクトンからなるステレオブロック共重合体の合成とその性質
中山 祐正, 宇野 智仁, 塩野 , 白浜 博幸
高分子論文集, 76, 61-67 (2019).doi

11) Changes in the morphology of poly(L-lactide-ran-delta-valerolactone) following supercritical carbon dioxide processing
Chikara Tsutsumi, Yumeko Ishikawa, Naoki Takahashi, Souta Manabe, Susumu Nakayama, Yasuhiro Matsubara, Yuushou Nakayama, Takeshi Shiono
Polymer Crystallization, 2, e10070 (2019). doi

総説

12) 重合技術によるポリプロピレンの高性能化・高機能化
塩野 毅
ファインケミカル, 48(6), 5-22 (2019).

13) バイオマス由来TPEの合成
中山 祐正, 塩野
ファインケミカル, 48(7), 15-21 (2019).

14) メチルアルミノキサンの化学 組成制御のための研究動向
田中 亮
化学と工業, 72(10), 834-835 (2019).

 

 

2018

学術論文

1) Efficient Ethylene Copolymerization with Polar Monomers Using Palladium Anilinonaphthoquinone Catalysts
Lin Ding, Hailong Cheng, Yanqing Li, Ryo Tanaka, Takeshi Shiono, Zhengguo Cai
Polym. Chem., 9 5476-5482 (2018). doi

2) フルオレニルアミドチタン(テトラヒドロフラン)錯体の合成とそのオレフィン重合触媒作用
西井 圭, 早野 重孝, 角替 靖男, 中山 祐正, 塩野 毅
高分子論文集, 75, 564-569 (2018). doi

3) Efficient Control of Ethylene-Norbornene Copolymerization Behavior of Fluorenylamido-Ligated Titanium Complex: Substituent Effects of Amido Ligand and Copolymer Properties
Huajin Wang, Hailong Cheng, Ryo Tanaka, Takeshi Shiono, Zhengguo Cai
Polym. Chem., 9, 4492-4497 (2018). doi

4) Reversible Star Assembly of Polyolefins Using Interconversion between Boroxine and Boronic Acid
Ryo Tanaka, Naoki Tonoko, Shin-ichi Kihara, Yuushou Nakayama, Takeshi Shiono
Polym. Chem., 9, 3774-3779 (2018). doi

5) メチルアルミノキサンの助触媒能に対するフェノール・シラノール類の添加効果
田中 亮, 山下 高幸, 渡子 直紀, 中山 祐正, 塩野 毅
高分子論文集, 75, 551-556 (2018). doi

6) Chain-Walking Polymerization of Linear Internal Octenes Catalyzed by alpha-Diimine Nickel Catalysts
Fuzhou Wang, Ryo Tanaka, Qingshan Li, Yuushou Nakayama, Takeshi Shiono
Organometallics, 37, 1358-1367 (2018). doi

7) Selective synthesis of highly soluble cyclic olefin copolymers with pendant vinyl groups using 1,5-hexadiene as a comonomer Polymer
Ryo Tanaka, Akane Sasaki, Takuma Takenaka, Yuushou Nakayama, Takeshi Shiono
Polymer, 136, 109-113 (2018). doi

総説

8) 原料の構造を保持したバイオベースポリマーの開発
中山祐正
ケミカルエンジニヤリング, 63(12), 896-900 (2018).

 

 

2017

学術論文

1) Substituent Effects of Adamantyl Group on Amido Ligand in Syndiospecific Polymerization of Propylene with Ansa-Dimethylsilylene(Fluorenyl)(Amido) Zirconium Complex
Yanjie Sun, Shuhui Li, Takeshi Shiono, Zhengguo Cai
Polymers, 9, 632 (2017). doi

2) Highly Robust Nickel Catalysts Containing Anilinonaphthoquinone Ligand for Copolymerization of Ethylene and Polar Monomers
Xia Fu, Lingjun Zhang, Ryo Tanaka, Takeshi Shiono, Zhengguo Cai
Macromolecules, 50, 9216-9221 (2017). doi

3) Synthesis of Stereodiblock Polybutadiene Using Cp*Nd(BH4)2(thf)2 as A Catalyst
Ryo Tanaka, Yuto Shinto, Yuushou Nakayama, Takeshi Shiono
Catalysts, 7, 284 (2017). doi

4) Living polymerization of higher 2-alkene with α-diimine nickel catalysts: Synthesis and characterization of high molecular weight poly(2-alkene)s
Fuzhou Wang, Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
Polymer, 127, 88-100 (2017). doi

5) Highly Active ansa-(Fluorenyl)(amido)titanium-Based Catalysts with Low Load of Methylaluminoxane for Syndiotactic-Specific Living Polymerization of Propylene
Yanjie Sun, Bo Xu, Takeshi Shiono, Zhengguo Cai
Organometallics, 36, 3009-3012 (2017). doi

6) An alternative method for the preparation of trialkylaluminum-depleted modified-methylaluminoxane (dMMAO)
Ryo Tanaka, Tomoyasu Kawahara, Yuto Shinto, Yuushou Nakayama, Takeshi Shiono
Macromolecules, 50, 5989–5993 (2017). doi

7) Synthesis and Biodegradation of Poly(L-lactide-co-beta-propiolactone)
Yuushou Nakayama, Kazuki Aihara, Zhengguo Cai, Takeshi Shiono, Chikara Tsutsumi
Int. J. Mol. Sci., 18, 1312 (2017). doi

8) Effect of end-group modification of poly(lactide)s by cinnamoyl chloride on their thermal stability
Yuushou Nakayama, Naoki Matsubara, Zhennguo Cai, Takeshi Shiono, Kei Inumaru, Hiroyuki Shirahama
Polym. Degrad. Stab., 141, 97-103 (2017). doi

9) Quasi-Living Polymerization of Propene with an Isotactic-Specific Zirconocene Catalyst
Kei Nishii, Miyuki Murase, Takeshi Shiono
Molecules, 22, 725 (2017). doi

10) Living Polymerization of Propylene with ansa-Dimethylsilylene(fluorenyl)(cumylamido) Titanium Complexes
Huajin Wang, Xinwei Wang, Yanjie Sun, Hailong Cheng, Takeshi Shiono, Zhengguo Cai
Polymers, 9, 131 (2017). doi

11) Synthesis of Hydroxy-Functionalized Cyclic Olefin Copolymer and Its Block Copolymers with Semicrystalline Polyolefin Segments
Xiangyang Song, Lijun Yu, Takeshi Shiono, Tariqul Hasan, Zhengguo Cai
Macromol. Rapid Commun., 38, 1600815 (2017). doi

12) Synthesis of highly thermostable norbornene-isoprene-1-octene terpolymer with titanium catalyst
Ryo Tanaka, Ryusei Matsuzaki, Yuushou Nakayama, Takeshi Shiono
J. Polym. Sci. Part A: Polym. Chem., 55, 2136-2140 (2017).doi

13) Controlled Ring-Opening Polymerization of L-Lactide and ε-Caprolactone Catalyzed by Aluminum-Based Lewis Pairs or Lewiss Acid Alone
Yuushou Nakayama, Shunsuke Kosaka, Kentaro Yamaguchi, Gentaro Yamazaki, Ryo Tanaka, Takeshi Shiono
J. Polym. Sci. Part A: Polym. Chem., 55, 297-303 (2017).doi

 

 

2016

学術論文

1) Enzymatic degradation of poly(l-lactide) treated with supercritical carbon dioxide
Chikara Tsutsumi, Ryousuke Ikeda, Ryouji Watanabe, Susumu Nakayama, Masaki Shiomi, Yuushou Nakayama, Takeshi Shiono
Polym. Degrad. Stab., 134, 366-375 (2016).doi

2) Theoretical investigation of the mechanism of syndiospecific propylene polymerization using ansa-dimethylsilylene(fluorenyl)(amido)titanium complexes
Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
J. Organomet. Chem., 823, 112-115 (2016).doi

3) Effects of supercritical carbon dioxide treatment on the morphology of poly(l-lactide)
Chikara Tsutsumi, Ryouji Watanabe, Ayaka Tokumaru, Nao Kuwaoka, Yuushou Nakayama, Takeshi Shiono
J. Appl. Polym. Sci., 133, 44006 (2016).doi

4) Precision Chain-Walking Polymerization of trans-4-Octene Catalyzed by α-Diimine Nickel(II) Catalysts Bearing ortho-sec-Phenethyl Groups
Wang Fuzhou, Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
Macromol. Rapid Commun., 37, 1375-1381 (2016).doi

5) Synthesis of Highly Branched Polyolefins Using Phenyl Substituted α-Diimine Ni(II) Catalysts
Wang Fuzhou, Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
Polymers, 8, 160 (2016).doi

6) Synthesis of stereodiblock polyisoprene consisting of cis-1,4 and trans-1,4 sequences by neodymium catalyst: change of the stereospecificity triggered by aluminum compound
Ryo Tanaka, Kaede Yuuya, Hiroki Sato, Peter Eberhardt, Yuushou Nakayama, Takeshi Shiono
Polym. Chem., 7, 1239-1243 (2016).doi

7) Structure-stereospecificity relationships of propylene polymerization using substituted ansa-silylene(fluorenyl)(amido) titanium complexes
Ryo Tanaka, Chie Yanase, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
J. Organomet. Chem., 804, 95-100 (2016).doi

8) Facile Synthesis of Novel Polyethylene-Based A-B-C Block Copolymers Containing Poly(methyl methacrylate) Using a Living Polymerization System
Xiangyang Song, Qiong Ma, Zhengguo Cai, Ryo Tanaka, Takeshi Shiono, Robert B. Grubbs
Macromol. Rapid Commun., 37, 227-231 (2016).doi

9) The Preparation of Boron-containing Aluminoxanes and their Application as Cocatalysts in the Polymerization of Olefins
Ryo Tanaka, Takaaki Hirose, Yuushou Nakayama, Takeshi Shiono
Polym. J., 48, 67-71 (2016).doi

総説

10) オレフィンと13族アルケニル化合物の共重合による官能基化ポリオレフィンの合成
田中亮、塩野毅
触媒, 58(1), 27-31 (2016).

 

 

2015

学術論文

1) Room-temperature Suzuki-Miyaura cross-coupling reaction with alpha-diimine Pd(II) catalysts
Fuzhou Wang, Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
Appl. Organomet. Chem., 29, 771-776 (2015). doi

2) Highly Soluble Polynorbornene Prepared by an Anilinonaphthoquinone-Ligated Nickel Complex via Coordination-Insertion Polymerization
Mitsuhiro Okada, Yuushou Nakayama, Takeshi Shiono
J. Organomet. Chem., 798, 384-387 (2015). doi

3) Synthesis of Polystyrene-Grafted Cycloolefin Copolymer
Ryo Tanaka, Manami Goda, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
Polymer, 70, 252-256 (2015). doi

4) キレートへテロドナー配位子を有する8族遷移金属触媒による開環メタセシス重合の立体制御
中山 祐正, 奥野 晋吾, 田中 亮, 蔡 正国, 塩野 毅
高分子論文集, 72, 460-467 (2015). doi

5) Ethylene-propylene copolymerization behavior of ansa-dimethylsilylene(fluorenyl)(amido)dimethyltitanium complex: application to ethylene-propylene-diene or ethylene-propylene-norbornene terpolymers
Ryo Tanaka, Issei Kamei, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
J. Polym. Sci. Part A, 53, 685-691 (2015). doi

6) Pseudo-living copolymerization of norbornene and omega-alkenylborane - synthesis of monodisperse functionalized cycloolefin copolymer
Ryo Tanaka, Tomomi Ikeda, Yuushou Nakayama, Takeshi Shiono
Polymer, 56, 218-222 (2015). (doi)

7) Synthesis and application of α-diimine Ni(II) and Pd(II) complexes with bulky steric groups to polymerization of ethylene and methyl methacrylate
Fuzhou Wang, Ryo Tanaka, Qingshan Li, Yuushou Nakayama, Jianchao Yuan, Takeshi Shiono
J. Mol. Catal. A: Chem., 398, 231-240 (2015). (doi)

8) Synthesis of Biodegradable Thermoplastic Elastomers from ε-Caprolactone and Lactide
Yuushou Nakayama, Kazuki Aihara, Hitomi Yamanishi, Hiroshi Fukuoka, Ryo Tanaka, Zhengguo Cai, Takeshi Shiono
J. Polym. Sci. Part A: Polym. Chem., 53, 489-495 (2015).(doi)

9) Synthesis of Aliphatic Polyesters via Ring-Opening Polymerization of Macrocyclic Oligoesters
Yuushou Nakayama, Keisuke Sakaguchi, Ryo Tanaka, Zhengguo Cai, Takeshi Shiono
Macromol. Symp., 350, 7-13 (2015). doi

 

 

2014

学術論文

1) Synthesis of C1 symmetrical ansa-cyclopentadienylamidotitanium complexes and their application for living polymerization of propylene
Zhengguo Cai, Haihui Su, Yuushou Nakayama, Takeshi Shiono, Munetaka Akita
J. Organomet Chem., 770, 136-141 (2014). doi

2) Heterogenization of an Anilinonaphthoquinone-Chelated Nickel Complex for Ethylene Polymerization Using Silica-Supported Modifi ed Methylaluminoxane
Mitsuhiro Okada, Yuushou Nakayama, Takeshi Shiono
Macromol. Chem. Phys., 215, 1792-1796 (2014). doi

3) New Nickel(II) Diimine Complexes Bearing Phenyl and sec-Phenethyl Groups: Synthesis, Characterization, and Ethylene Polymerization Behaviour
Fuzhou Wang, Jianchao Yuan, Qingshan Li, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
Appl. Organomet. Chem., 28, 477-483 (2014). doi

4) Synthesis of multiblock copolymer of poly(cis-1,4-butadiene) and poly(3-buten-1-ol)
Ryo Tanaka, Yuki Kasai, Masahito Shinzawa, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
Macromol. Chem. Phys., 215, 888-892 (2014). doi

5) 天然由来揮発性化合物の有効活用を目的とした超臨界二酸化炭素による新規徐放剤に関する研究
主計, 津々木 亜美, 光志, 中山 祐正, 塩野
高分子論文集, 71, 1-10 (2014). doi

6) Synthesis and their thermal, mechanical, and optical properties of A-B-A or A-B block copolymers containing poly(norbornene-co-1-octene)
Ryo Tanaka, Takuya Suenaga, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
J. Polym. Sci. Part A: Polym. Chem., 52, 267-271 (2014). doi

学術論文(非SCI

7) Synthesis and Properties of Polylactide-based Poly(ester-urethane)s with Ionic Groups
Yuushou Nakayama, Toshitaka Ohmori, Ryo Tanaka, Takeshi Shiono, Hiroyuki Shirahama
J. Jpn. Inst. Energy, 93, 921-925 (2014). doi

8) Synthesis and Properties of Poly(epsilon-carprolactone)-based Poly(ester-urethane)s Having Quaternary Ammonium Groups
Yuushou Nakayama, Naoki Matsubara, Ryo Tanaka, Zhengguo Cai, Takeshi Shiono, Hiroyuki Shirahama, Chikara Tsutsumi
J. Jpn. Inst. Energy, 93, 916-920 (2014). doi

 

 

総説

9) ジメチルシリレン架橋(フルオレニル)(アミド)ジメチルチタン錯体触媒によるシクロオレフィン共重合体の精密合成
田中亮、塩野毅
有機合成化学協会誌, 72(2), 118-125 (2014). doi

 

 

Books, Reports (2014-2023)

1) 中山 祐正, 塩野 毅、"生分解性を有する新規機能性コポリエステルの設計と合成" in「海洋汚染問題を解決する生分解性プラスチック開発」, 監修 岩田 忠久, p.187-201, エヌ・ティー・エス (2023).

2) 中山 祐正, "ハフニウム"-"イリジウム" in「元素118の新知識 2版」, 桜井 編著, 講談社 (2023).

3) 中山 祐正, "配列が制御された生分解性コポリマーの設計と合成" in「容器包装材料の環境対応とリサイクル技術」, p.300-310, 技術情報協会 (2022).

4) 田中亮, 藤井裕也, 木田拓充, 中山祐正, 塩野毅, "含ホウ素モノマーの共重合によるポリオレフィンの機能化" in「次世代ポリオレフィン総合研究」, 15, p.10-14, 三恵社 (2022).

5) 田中亮, 中島智哉, 中山祐正, 塩野毅, "新規Brønsted酸助触媒DHBAの開発" in「次世代ポリオレフィン総合研究」, 14, p.7-10, 三恵社 (2021).

6) Haobo Yuan, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono, "Synthesis and Properties of Star Polymers with Norbornene/alpha-olefin Gradient Copolymer Arms Using ansa-Fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)4] Catalyst System" in「次世代ポリオレフィン総合研究」, 14, p.11-14, 三恵社 (2021).

7) 塩野毅, 田中亮, "[82]エチレンの重合, [83]オレフィンの配位連鎖移動重合, [84]オレフィン, ジエンのチェーンウォーキング重合, [90]共役ジエンの高立体特異性重合" in「有機合成のための新触媒反応101, 檜山為次郎, 野崎京子, 中尾佳亮, 中野幸司 , 東京化学同人 (2021).

8) 中山祐正, "生分解性コポリエステルの設計,合成とその特性" in「生分解,バイオマスプラスチックの開発と応用」, p.153-159 技術情報協会 (2020).

9) 岡島裕矢, 中山祐正, 塩野毅, 田中亮, "二酸化炭素を用いたメチルアルミノキサンの調製" in 「次世代ポリオレフィン総合研究」, 次世代ポリオレフィン総合研究会編, Vol. 13, p. 47-50, 三恵社 (2019).

10) 中山祐正, 塩野毅, "高性能なコポリエステルの合成と生分解性" in「生分解性プラスチックの環境配慮設計指針」岩田忠久, 阿部英喜編, p.149-157, シーエムシー出版 (2019).

11) 中山祐正, 塩野毅 "バイオマス由来TPEの合成" in「プラスチックの資源循環に向けたグリーンケミストリーの要素技術」澤口孝志編, p. 291-298, シーエムシー出版 (2019).

12) 中山祐正, 塩野毅 "生分解性を備えた熱可塑性エラストマーの設計と合成" in「熱可塑性エラストマーの開発と市場 2019, p.99-107, シーエムシー出版 (2019).

13) 田中亮, 塩野毅, "8 3: 配位重合によるステレオブロックポリマーの合成とその性質" in 「次世代のポリマー・高分子開発,新しい用途展開と将来展望」, 技術情報協会 (2019).

14) 塩野毅, 田中亮, "10章 配位重合によるオレフィンブロック共重合体の合成", in「ブロック共重合体の構造制御と応用展開」,p. 141-156, シーエムシー出版 (2018).

15) 田中亮, 渡子直紀, 中山祐正, 塩野毅, "末端ボロン酸修飾を用いた星型ポリオレフィンの合成", in 「次世代ポリオレフィン総合研究」, 次世代ポリオレフィン総合研究会編, Vol. 12, p. 55-58, 三恵社 (2018).

16) 塩野毅, 田中亮, "第5章 第4節:錯体触媒によるポリオレフィンの精密合成と耐熱性向上" in 「高耐熱樹脂の開発事例集」,技術情報協会 (2018).

17) 田中亮, 川原友泰,神藤佑斗,中山祐正, 塩野毅, "修飾メチルアルミノキサン中のトリアルキルアルミニウムを簡便に除去する手法の開発" in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.11, p.63-67, 三恵社 (2017).

18) 塩野毅, 田中亮(撮影協力), "プロピレンの配位重合" in 「新・高分子合成実験法 第3巻:高分子合成実験 II」,冨田育義, 佐藤絵理子 監修,丸善 (2017).

19) 田中亮, 祐谷楓,佐藤弘樹,Peter Eberhardt,中山祐正, 塩野毅, "ネオジム触媒系を用いたステレオブロックポリイソプレンの合成" in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.10, p.66-70, 三恵社 (2016).

20) 田中亮, 塩野毅, "第1章 1節:ポリプロピレンの精密合成" in 「ポリプロピレンの構造制御と複合化、成形加工技術」,技術情報協会 (2016).

21) 塩野毅, "第7章:配位重合(1):プロピレンの立体特異的リビング重合" in CSJカレントレビュー20 精密重合が拓く高分子合成」,日本化学会編,p.90-95, 化学同人 (2016).

22) 田中亮, 柳瀬千絵,蔡正国,中山祐正, 塩野毅, "計算化学的手法によるフルオレニルアミドチタン錯体を用いたプロピレン重合の機構解析" in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.9, p.27-30, 三恵社 (2015).

23) Yuushou Nakayama, Takeshi Shiono, "Coordination Polymerization (Olefin and Diene)" in Encyclopedia of Polymeric Nanomaterials, Kobayashi, S.; Mullen, K. Eds., Springer, 469-474 (2015). doi

24) Ryo Tanaka, Takeshi Shiono, "Coordination Polymerization (Styrene and Polar Vinyl Monomers)" in Encyclopedia of Polymeric Nanomaterials, Kobayashi, S.; Mullen, K. Eds., Springer, 474-480 (2015). doi

25) 田中亮, 廣瀬貴彰,中山祐正, 塩野毅, "新規含ホウ素アルミニウム錯体の合成とオレフィン重合触媒としての応用" in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.8, p.59-62, 三恵社 (2014).

26) Takeshi Shiono, "1. Olefin Polymerization with Metallocene Catalysts" in Organometallic Reactions and Polymerization, Osakada, K. Ed., Springer, 2014.

 

 

 

2013

学術論文

1) イタコン酸とイソソルビドの縮合重合によるポリエステルの合成とその性質
中山 祐正, 坂口 圭祐, 田中 , 正国, 塩野
高分子論文集, 70, 559-564 (2013). doi

2) Modification effect of spherical zirconia with SiCl4 as a support of methylaluminoxane for heterogeneous single-site catalyst
Sasiradee Jantasee, Bunjerd Jongsomjit, Haruki Yano, Takeshi Shiono
Eur. Polym. J., 49, 4195-4200 (2013). doi

3) Copolymerization of Norbornene with ω-Alkenylaluminum as a Precursor Comonomer for Introduction of Carbonyl Moieties
Jang-Woo Lee, Sasiradee Jantasee, Bunjerd Jongsomsit, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
J. Polym. Sci. Part A: Polym. Chem., 51, 5085-5090 (2013). doi

4) Copolymerization of Ethylene and 1-Hexene with Ansa-Dimethylsilylene(fluorenyl) (t-butylamido)Dimethyltitanium Complexes Activated by Modified Methylaluminoxane
Mingkwan Wannaborworn, Piyasan Praserthdam, Bunjerd Jongsomjit, Zhengguo Cai, Haruki Yano, Takeshi Shiono
Macromol. Chem. Phys., 214, 2584-2590 (2013). doi

5) Synthesis and properties of cationic ionomers from poly(ester-urethane)s based on polylactide
Yuushou Nakayama, Takamichi Inaba, Yosuke Toda, Ryo Tanaka, Zhengguo Cai, Takeshi Shiono, Hiroyuki Shirahama, Chikara Tsutsumi
J. Polym. Sci. Part A: Polym. Chem., 51, 4423-4428 (2013). doi

6) Facile Synthesis of Hydroxy-Functionalized Cycloolefin Copolymer Using omega-Alkenylaluminium as a Comonomer
Takeshi Shiono, Mitsunori Sugimoto, Tariqul Hasan, Zhengguo Cai
Macromol. Chem. Phys., 214, 2239-2244 (2013). doi

7) Synthesis of high-molecular weight block copolymers of norbornene and propylene with methyl methacrylate initiated by fluorenylamido titanium complex
Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono
Polym. Chem., 4, 3974-3980 (2013). doi

8) Copolymerization of ethylene/1-hexene with zirconocene/MAO catalyst supported on spherical zirconia modified with BCl3, SiCl4, and glycerol
Sasiradee Jantasee, Takeshi Shiono, Bunjerd Jongsomjit
Polym. Bull., 70, 1753-1768 (2013). doi

9) Copolymerization of ethylene with 1,1-disubstituted olefins catalyzed by ansa-(fluorenyl)(cyclododecylamido)dimethyltitanium complexes
Yuushou Nakayama, Yuuichi Sogo, Zhengguo Cai, Takeshi Shiono
J. Polym. Sci. Part A: Polym. Chem., 51, 1223-1229 (2013). doi

学術論文(非SCI

10) Copolymerization of Ethylene with Isobutylene and Limonene Catalyzed by Titanium Complexes with Various ansa-(Fluorenyl)(alkylamido) Ligand
Yuushou Nakayama, Yuuichi Sogo, Ryo Tanaka, Zhengguo Cai, Takeshi Shiono
Eng. J. 17, 7-12 (2013). doi

総説

11) Trialkylaluminum-Free Modified Methylaluminoxane as a Cocatalyst for Living Polymerization of Olefins
Takeshi Shiono
Adv. Polym. Sci., 258, 143-161 (2013). doi

12) 生分解性を備えた熱可塑性エラストマー
中山祐正、田中亮、塩野毅
Polyfile, 50(592), 28-32 (2013).

13) Precise synthesis of olefin block copolymers using a syndiospecific living polymerization system
Zheng-guo Cai, Hai-hui Su, Takeshi Shiono
Chinese J. Polym. Sci., 31, 541-549 (2013). doi

2012

1) 2-(1-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinolylcobalt dichloride: Synthesis and polyethylene wax formation
Wen-Hua Sun, Shaoliang Kong, Wenbin Chai, Takeshi Shiono, Carl Redshaw, Xinquan Hu, Cunyue Guo, Xiang Hao
Appl. Catal. A General, 447-448, 67-73 (2012). doi

2) Synthesis and Emission Behavior of Liquid-Crystalline Main-Chain Polyesters Containing Carbazole and Oxadiazole Moieties
Motoi Kinoshita, Kenji Takamura, Masuki Kawamoto, Atsushi Shishido, Takeshi Shiono, Tomiki Ikeda
Mol. Cryst. and Liq. Cryst., 563, 92-100 (2012). doi

3) Effect of Ga- and BCl3-modified silica-supported [t-BuNSiMe2(2,7-t-Bu2Flu)]TiMe2/MAO catalyst on ethylene/1-hexene copolymerization
Patcharaporn Kaivalchatchawal, Sutheerawat Samingprai, Takeshi Shiono, Piyasan Praserthdam, Bunjerd Jongsomjit
Eur. Polym. J., 48, 1304-1312 (2012). doi

4) 2-[1-(2,6-Dibenzhydryl-4-chlorophenylimino)ethyl]-6-[1-(arylimino)ethyl]pyridyliron(II) dichlorides: Synthesis, characterization and ethylene polymerization behavior
Xiaoping Cao, Fan He, Weizhen Zhao, Zhengguo Cai, Xiang Hao, Takeshi Shiono, Carl Redshaw, Wen-Hua Sun
Polymer, 53, 1870-1880 (2012). doi

5) Incorporation of L-lactide random copolymers with Japanese cypress oil (alpha-pinene) using supercritical carbon dioxide
Chikara Tsutsumi, Teruyuki Hara, Naohisa Fukukawa, Kazuyuki Oro, Kazuaki Hata, Yuushou Nakayama, Takeshi Shiono
Green Chem., 14, 1211-1219 (2012). doi

総説

6) 生分解性を有する熱可塑性エラストマーの合成
中山祐正、塩野 毅
日本ゴム協会誌, 85, 229-233 (2012).

2011

1) Highly thermostable and low birefringent norbornene-styrene copolymers with advanced optical properties: A potential plastic substrate for flexible displays
Hoang The Ban, Hideaki Hagihara, Yasuo Tsunogae, Zhengguo Cai, Takeshi Shiono
J. Polym. Sci., Part A: Polym. Chem., 49, 65-71 (2011). doi

2) Highly trans-1,4-specific polymerization of 1,3-butadiene catalyzed by [2,6-bis{(4S)-(-)-isopropyl-2-oxazolin-2-yl}pyridine] chromium complex activated with modified methylaluminoxane
Yuushou Nakayama, Kenji Sogo, Zhengguo Cai, Hajime Yasuda, Takeshi Shiono
Polym. Int., 60, 692-697 (2011). doi

3) The influence of t-butyl and cyclododecyl substitution on ethylene/1-hexene copolymerization using ansa-fluorenylamidodimethyltitanium derivatives
Patcharaporn Kaivalchatchawal, Piyasan Praserthdam, Yuuichi Sogo, Zhengguo Cai, Takeshi Shiono, Bunjerd Jongsomjit
Molecules, 16, 4122-4130 (2011). doi

4) Impregnation of poly(L-lactide-ran-cyclic carbonate) copolymers with useful compounds with supercritical carbon dioxide
Chikara Tsutsumi, Naohisa Fukukawa, Jun Sakafuji, Kazuyuki Oro, Kazuaki Hata, Yuushou Nakayama, Takeshi Shiono
J. Appl. Polym. Sci., 121, 1431-1441 (2011). doi

5) High activity of rare earth tetrahydroborates for ring-opening polymerization of omega-pentadecalactone
Yuushou Nakayama, Naoki Watanabe, Keisuke Kusaba, Kenta Sasaki, Zhengguo Cai, Takeshi Shiono, Chikara Tsutsumi
J. Appl. Polym. Sci., 121, 2098-2103 (2011). doi

6) 架橋型モノシクロペンタジエニルアミドジメチルチタン錯体を用いたプロピレン重合におけるシクロペンタジエニル配位子の効果
西井圭, 塩野毅
高分子論文集, 68, 341-344 (2011). doi

7) ピリジンチオラート配位子を有するハーフチタノセン錯体を用いたエチレンおよびスチレンの重合
中山祐正, 谷本匡哉, 蔡正国, 塩野毅
高分子論文集, 68, 457-463 (2011). doi

学術論文(非SCI

8) Activated carbons containing dispersed metal oxide particles for removal of methyl mercaptan in air
Hisashi Tamai, Miki Nakamori, Masayoshi Nishikawa, Takeshi Shiono
Mater. Sci. Appl., 2, 49-52 (2011). doi

9) Production of functional carbon by iron-catalyzed carbonization of biomass - effect of washing with acid followed by atmospheric oxidation on the electroconductivity of crystallized mesoporous wood carbon
Tsutomu Suzuki, Tatsuya Shinomoto, Hiroshi Matsuzaki, Kyoko Suzuki, Noriyasu Okazaki, Yukie Saito, Hidetoshi Kita, Hisashi Tamai
Trans. Mater. Res. Soc. Jpn., 36, 417-420 (2011).

総説

10) Living polymerization of olefins with ansa-dimethylsilylene(fluorenyl)(amido)dimethyltitanium-based catalysts
Takeshi Shiono
Polym. J., 43, 331-351 (2011). doi

11) オレフィン重合の最近の展開
中山祐正, 蔡正国, 塩野毅
成形加工, 23, 518-523 (2011).

2010

学術論文

1) Efficient molecular weight control with trialkylaluminum in ethylene/norbornene copolymerization by [Ph2C(Flu)(3-MeCp)]ZrCl2/methylaluminoxane catalyst
Tomoyuki Tada, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
Macromol. Chem. Phys., 211, 2132-2137 (2010). doi

2) Synthesis of stereoblock polypropylene by change of temperature in living polymerization
Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono
Macromol. Res., 18, 737-741 (2010). doi

3) Additive effects of alkylaluminium compounds on propylene-1,3-butadiene copolymerization using isospecific zirconocene catalysts
Takeshi Ishihara, Hoang The Ban, Hideaki Hagihara, Takeshi Shiono
J. Organomet. Chem., 695, 1694-1699 (2010). doi

4) Highly active living random copolymerization of norbornene and 1-alkene with ansa-fluorenylamidodimethyltitanium derivative: substituent effects on fluorenyl ligand
Zhengguo Cai, Ryotaro Harada, Yuushou Nakayama, Takeshi Shiono
Macromolecules, 43, 4527-4531 (2010). doi

学術論文(SCI)

5) Preparation of activated carbons from polymer/carbon black composites as an EDLC electrode
Hisashi Tamai, Mitsunori Nishita, Takeshi Shiono
J. Mater. Sci. Eng. Adv. Technol., 1, 121-134 (2010).

総説

6) 架橋型フルオレニルアミドジメチルチタン錯体によるオレフィンのリビング配位重合
塩野毅
触媒, 52, 540-546 (2010).

2009

1) Highly active syndiospecic living polymerization of higher 1-alkene with ansa-fluorenylamidodimethyltitanium complex
Zhengguo Cai, Masayoshi Ohmagari, Yuushou Nakayama, Takeshi Shiono
Macromol. Rapid Commun., 30, 1812-1816 (2009). doi

2) Synthesis of Regioblock Polybutadiene with CoCl2-Based Catalyst via Reversible Coordination of Lewis Base
Zhengguo Cai, Masahito Shinzawa, Yuushou Nakayama, Takeshi Shiono
Macromolecules, 42, 7642-7643 (2009). doi

3) A highly active catalyst composed of ansa-fluorenylamidodimethyltitanium derivative for propene polymerization
Takeshi Shiono, Ryotaro Harada, Zhengguo Cai, Yuushou Nakayama
Top. Catal., 52, 675-680 (2009). doi

4) Preparation of Pd supported mesoporous activated carbons and their catalytic activity
Hisashi Tamai, Nobuaki Uragawa, Hajime Yasuda
Mater. Chem. Phys., 114, 10-13 (2009). doi

5) Ring-opening polymerization of six-membered cyclic esters catalyzed by tetrahydroborate complexes of rare earth metals
Yuushou Nakayama, Kenta Sasaki, Naoki Watanabe, Zhengguo Cai, Takeshi Shiono
Polymer, 50, 4788-4793 (2009). doi

2008

1) Random copolymerization of norbornene with higher 1-alkene with ansa-fluorenylamidodimethyltitanium catalyst
Takeshi Shiono, Mitsunori Sugimoto, Tariqul Hasan, Zhengguo Cai, and Tomiki Ikeda
Macromolecules, 41, 8292-8294 (2008). doi

2) Substituent effects of tert-butyl groups on fluorenyl ligand of [t-BuNSiMe2Flu]ZrMe2
Zheng-guo Cai, Yuushou Nakayama, and Takeshi Shiono
Chin. J. Polym. Sci., 26, 575-578 (2008). doi

3) Facile synthesis of tailor-made stereoblock polypropylenes via successive variation of monomer pressure
Zhengguo Cai, Yuushou Nakayama, and Takeshi Shiono
Macromolecules, 41, 6596-6598 (2008). doi

4) Catalytic synthesis of a monodisperse olefin block copolymer using a living polymerization system
Zhengguo Cai, Yuushou Nakayama, and Takeshi Shiono
Macromol. Rapid Commun., 29, 525-529 (2008). doi

5) A new approach for controlling birefringent property of cyclic olefin copolymers
Hoang The Ban, Hideaki Hagihara, Kei Nishii, Yasuo Tsunogae, Shuichi Nojima, and Takeshi Shiono
J. Polym. Sci., Part A: Polym. Chem., 46, 7395-7400 (2008). doi

6) Highly active copolymerization of ethylene and dicyclopentadiene with [(1-t-BuN)SiMe2(1-C29H36)]TiMe2(THF) complex
Kei Nishii, Shigetaka Hayano, Yasuo Tsunogae, Zhengguo Cai, Yuushou Nakayama, and Takeshi Shiono
Chem. Lett., 37, 590-591 (2008). doi

7) Precise control of microstructure of functionalized polypropylene synthesized by the ansa-zirconocene/MAO catalysts
Hideaki Hagihara, Takeshi Ishihara, Hoang The Ban, and Takeshi Shiono
J. Polym. Sci., Part A: Polym. Chem., 46, 1738-1748 (2008). doi

8) Ring-opening metathesis polymerization of norbornene catalyzed by tantalum and niobium complexes with chelating O-donor ligands
Yuushou Nakayama, Naoaki Maeda, Hajime Yasuda, and Takeshi Shiono
Polym. Int., 57, 950-956 (2008). doi

9) Synthesis of poly(ester-urethane)s from hydroxytelechelic polylactide: Effect of initiators on their physical and degradation properties
Yuushou Nakayama, Ryo Yamaguchi, Chikara Tsutsumi, and Takeshi Shiono
Polym. Degrad. Stab., 93, 117-124 (2008). doi

10) Synthesis, characterization, and thermal properties of ring-opening metathesis polynorbornenes and their hydrogenated derivatives bearing various ester and cyano groups
Yasushi Nishihara, Seisuke Izawa, Yoshiaki Inoue, Yuushou Nakayama, Takeshi Shiono, and Kentaro Takagi
J. Polym. Sci., Part A: Polym. Chem., 46, 3314-3325 (2008). doi

11) チタン錯体触媒による炭化水素系モノマーのリビング重合
蔡正国, 塩野毅
有機合成化学協会誌, 66, 664-672 (2008). doi

2007

1) Preparation of polyaniline coated activated carbon and their electrode performance for supercapacitor
H. Tamai, M. Hakoda, T. Shiono, and H. Yasuda
J. Mater. Sci., 42, 1293-1298 (2007). doi

2) Synthesis of anilinonaphthoquinone based nickel complexes and their application for olen polymerization
M. Okada, Y. Nakayama, and T. Shiono
J. Organomet. Chem., 692, 5183-5189 (2007). doi

3) Synthesis and characterization of norbornene-ethylene-styrene terpolymers with a substituted ansa-fuorenylamidodimethyltitanium-based catalyst
H. T. Ban, K. Nishii, Y. Tsunogae and T. Shiono
J. Polym. Sci., Part A: Polym. Chem., 45, 2765-2773 (2007). doi

4) Homo- and copolymerization of norbornene derivatives with ethene by ansa-fuorenylamidodimethyltitanium activated with methylaluminoxane
T. Hasan, T. Ikeda, and T. Shiono
J. Polym. Sci., Part A: Polym. Chem., 45, 4581-4587 (2007). doi

5) Copolymerization of propylene with 1,3-butadiene using isospecific zirconocene catalysts
T. Ishihara, H. T. Ban, H. Hagihara, and T. Shiono
J. Polym. Sci., Part A: Polym. Chem., 45, 5731-5740 (2007). doi

6) Effect of cocatalysts on the catalytic activities of tantalum- and niobium-based catalysts for ring-opening metathesis polymerization of norbornene
Y. Nakayama, M. Tanimoto, and T. Shiono
Macromol. Rapid Commun., 28, 646-650 (2007). doi

7) Living ring-opening metathesis polymerization of exo-norbornenes bearing both cyano and ester functionalities by a well dened ruthenium catalyst
Y. Nishihara, Y. Inoue, A. T. Saito, Y. Nakayama, T. Shiono, and K. Takagi
Polym. J., 39, 318-329 (2007). doi

8) Synthesis of multiblock poly(L-lactide)-co-poly(epsiron-caprolactone) from hydroxy-telechelic prepolymers prepared by using neodymium tetrahydroborate
Y. Nakayama, S. Okuda, H. Yasuda, and T. Shiono
React. Funct. Polym., 67, 798-806 (2007). doi

9) チーグラー・ナッタ触媒
塩野毅
高分子, 56, 16-17 (2007).

10) 炭化水素系モノマーの立体特異的リビング重合
蔡正国, 塩野毅
高分子論文集, 64, 77-89 (2007).

11) 金属化合物添加による多孔質炭素の細孔制御
玉井久司
炭素, 227, 122-128 (2007).

2006

1) A new approach to styrenic thermoplastic elastomers: synthesis and characterization of crystalline styrene-butadiene-styrene triblock copolymers
H. T. Ban, T. Kase, M. Kawabe, A. Miyazawa, T. Ishihara, H. Hagishara, Y. Tsunogae, M. Murata, and T. Shiono
Macromolecules, 39, 171-176 (2006). doi

2) Stereospecific polymerization of propylene with group 4 ansa-fluorenylamidodimethyl complexes
K. Nishii, H. Hagihara, T. Ikeda, M. Akita, and T. Shiono
J. Organomet. Chem., 691, 193-201 (2006). doi

3) Preparation of poly(3,3'-dialkynyl-2,2'-bithiophene-5,5'-diyl) with high coplanarity and effective-conjugation system
T. Sato Z. Cai, T. Shiono, and T. Yamamoto
Polymer, 47, 37-41 (2006). doi

4) Living random copolymerization of propylene and norbornene with ansa-fluorenylamidodimethyltitanium complex: synthesis of novel syndiotactic polypropylene-b-poly(propylene-ran-norbornene)
Z. Cai, Y. Nakayama, and T. Shiono
Macromolecules, 39, 2031-2033 (2006). doi

5) Synthesis of crystallizable sydiotactic-atactic stereoblock polypropylene using a living polymerization system
Z. Cai, Y. Nakayama, and T. Shiono
Kinet. Catal., 47, 274-277 (2006). doi

6) Characteristics of LLDPE/ZrO2 nanocomposite synthesized by in-situ polymerization using a zirconocene/MAO catalyst
P. Praserthdam, B. Jongsomjit, J. Panpranot, M. Okada, and T. Shiono
Iran. Polym. J., 15, 433-439 (2006). link

7) Synthesis of uniquely branched polyethylene by anilinonaphthoquinoneligated nickel complex activated with tris(penta uorophenyl)borane
M. Okada, Y. Nakayama, T. Ikeda, and T. Shiono
Macromol. Rapid Commun., 27, 1418-1423 (2006). doi

8) Catalytic synthesis of monodisperse polypropylene using a living polymerization system with ansa-fluorenylamidodimethyltitanium-based catalyst
Z. Cai, M. Shigemasa, Y. Nakayama, and T. Shiono
Macromolecules, 39, 6321-6323 (2006). doi

9) Alternating copolymer of bithiophene and dialkylbithiazole and its tendency to align on the surfaces
T. Yamamoto, S. Otsuka, K. Namekawa, H. Fukumoto, I. Yamaguchi, T. Fukuda, N. Asakawa, T. Yamanobe, T. Shiono, and Z. Cai
Polymer, 47, 6038-6041 (2006). doi

10) Comparative reactivity of exo- and endo-isomers in the Ru-initiated ring-opening metathesis polymerization of doubly functionalized
norbornenes with both cyano and ester groups
Y. Nishihara, Y. Inoue, Y. Nakayama, T. Shiono, and K. Takagi
Macromolecules, 39, 7458-7460 (2006). doi

11) Effects of solvents in living polymerization of propene with [t-BuNSiMe2(3,6-t-Bu2Flu)]TiMe2-MMAO catalyst
T. Shiono, Z. Cai, and Y. Nakayama
Stud. Surf. Sci. Catal., 161, 47-52 (2006). doi

12) Synthesis of bis(imino)pyridine complexes of group 5 metals and their catalysis for polymerization of ethylene and norbornene
Y. Nakayama, N. Maeda, and T. Shiono
Stud. Surf. Sci. Catal., 161, 165-170 (2006). doi

13)Ethylene polymerization with an anilinonaphthoquinone-ligated nickel complex
M. Okada, Y. Nakayama, and T. Shiono
Stud. Surf. Sci. Catal., 161, 171-174 (2006). doi

14) Effects of temperature in syndiospecific living polymerization of propylene with [t-BuNSiMe2(3,6-t-Bu2Flu)]TiMe2-MMAO catalyst
Z. Cai, Y. Nakayama, and T. Shiono
Stud. Surf. Sci. Catal., 161, 189-192 (2006). doi

15) Additive effects of dialkylaluminum hydrides on propylene-1,3-butadiene copolymerization using an isospecific zirconocene catalyst
T. Ishihara, H. T. Ban, H. Hagihara, and T. Shiono
Stud. Surf. Sci. Catal., 161,197-200 (2006). doi

16) Propene polymerization by ansa-fluorenylamidodimethyltitanium activated with SiO2-supported modi ed methylalminoxane
T. Shiono, T. Matsumae, K. Nishii, and T. Ikeda
Stud. Surf. Sci. Catal., 161, 241-244 (2006). doi

17) Effect of alpha-olefins on copolymerization of ethylene and alpha-olefin with [t-BuNSiMe2Flu]TiMe2 catalyst
N. Intaragamjon, T. Shiono, B. Jongsomjit, and P. Praserthdam
Stud. Surf. Sci. Catal., 161, 271-274 (2006). doi

18) Elucidation of solvent effects on the catalytic behaviors for [t-BuNSiMe2Flu]TiMe2 complex during ethylene/1-hexene copolymerization
N. Intaragamjon, T. Shiono, B. Jongsomjit, and P. Praserthdam
Catal. Commun., 7, 721-727 (2006). doi

19) A comparative study ethylene/1-hexene copolymerization with [t-BuNSiMe2Flu]TiMe2 catalyst via various activators
N. Intaragamjon, T. Shiono, and P. Praserthdam
Stud. Surf. Sci. Catal., 159, 841-844 (2006). doi

20) Kinetic features of the cobalt dihalide/methylaluminoxane catalytic system in 1,3-butadiene polymerization
D. C. D. Nath, C. M. Fellows, and T. Shiono
Macromol. Res., 14, 338-342 (2006). doi

21) Surface functionalization of mesoporous and microporous activated carbons by immobilization of diamine
H. Tamai, K. Shiraki, T. Shiono, and H. Yasuda
J. Colloid Interface Sci., 295, 299-302 (2006). doi

22) Adsorption of methyl mercaptan on surface modi ed activated carbon
H. Tamai, H. Nagoya, and T. Shiono
J. Colloid Interface Sci., 300, 814-817 (2006). doi

23) Syntheses of group 4 transition metal complexes bearing 2-pyridinethiolate ligands and their catalytic activities for ethylene polymerization
Y. Takashima, Y. Nakayama, M. Hashiguchi, T. Hosoda, H. Yasuda, T. Hirao, and A. Harada
Polymer, 47, 5762-5774 (2006). doi

24) 金属触媒による環状エステルの開環重合
中山祐正, 塩野毅
高分子加工, 55, 17-26 (2006).

25) 希土類触媒によるアクリル酸エステル類のリビング重合
中山祐正, 塩野毅
触媒, 48, 182-188 (2006).

2005

1) Random copolymerization of propene and norbornene with ansa-fluorenylamidodimethyltitanium-based catalysts
T. Hasan, T. Ikeda, and T. Shiono
Macromolecules, 38, 1071-1074 (2005).doi

2) Polymerization of propylene with [t-BuNSiMe2Ind]TiMe2-MAO catalyst systems
K. Nishii, T. Ikeda, M. Akita, and T. Shiono
J. Mol. Catal. A, 231, 241-246 (2005). doi

3) Hydrogenated 1,4-insertion of butadiene in the copolymerization with propylene using an isospecific zirconocene catalyst
T. Ishihara, and T. Shiono
J. Am. Chem. Soc., 127, 5774-5775 (2005). doi

4) Substituent efects of tert-butyl groups on fluorenyl ligand in syndiospecific living polymerization of propylene with ansa-fluorenylamidodimethyltitanium complex
Z. Cai, T. Ikeda, M. Akita, and T. Shiono
Macromolecules, 38, 8135-8139 (2005). doi

5) Stereospecific sequential block copolymerizations of styrene and 1,3-butadiene with a C5Me5TiMe3/B(C6F5)3/Al(oct)3 catalyst
H. T. Ban, Y. Tsunogae, and T. Shiono
J. Polym. Sci., Part A, Polym. Chem., 43, 1188-1195 (2005). doi

6) Impact of diene addition on properties for ethylene-propylene copolymerization with rac-Et[Ind]2ZrCl2/MAO catalyst
B. Jongsomjit, S. Phoowakeereewiwat, S. Thongyai, T. Shiono, and P. Praserthdam
Mater. Lett., 59, 3771-3774 (2005). doi

7) Highly birefringent liquid-crystalline polymers for photonic applications: synthesis of liquid-crystalline polymers with sidechain azo-tolane mesogens and their holographic properties
K. Okano, A. Shishido, O. Tsutsumi, T. Shiono, and T. Ikeda
J. Mater. Chem., 15, 3395-3401 (2005). doi

8) Effect of ester moieties in dye structures on photoinduced reorientation of dyedoped liquid crystals
M. Yaegashi, A. Shishido, T. Shiono, and T. Ikeda
Chem. Mater., 17, 4304-4309 (2005). doi

9) Photoinduced change in birefringence and optical switching at near-infrared region based on photochemical phase transition of azobenzene liquid crystals
H. Kurihara, A. Shishido, O. Tsutsumi, T. Shiono, and T. Ikeda
Mol. Cryst. Liq. Cryst., 441, 173-184 (2005). doi

10) Novel liquid-crystalline phenylene-thienylene co-oligomers for photoinduced reorientation of liquid crystals
M. Yaegashi, A. Shishido, T. Shiono, and T. Ikeda
Mol. Cryst. Liq. Cryst., 441, 201-210 (2005). doi

11) Synthesis and properties of highly birefringent azo-tolane liquid-crystalline polymers: effect of the position of the tolane moiety in the side chain
K. Okano, A. Shishido, T. Ikeda, and T. Shiono
Mol. Cryst. Liq. Cryst., 441, 275-285 (2005). doi

12) Preparation and characterization of azobenzene liquid-crystalline elastomer films with homeotropic alignment
M. Kondo, T. Maeda, A. Shishido, T. Ikeda, Y. Yu, M. Nakano, T. Shiono
Mol. Cryst. Liq. Cryst., 441, 297-305 (2005). doi

13) Synthesis and electroluminescent properties of liquid-crystalline polymers containing oxazole and carbazole moieties in the same side chain
Y. M. Nam, M. Kawamoto, M. Kinoshita, T. Shiono, and T. Ikeda
Mol. Cryst. Liq. Cryst., 443, 95-104 (2005). doi

14) Photoinduced alignment behavior of poly(alkyl methacrylates) containing azobenzene moiety in the side chain
H.-B. Cha, A. Shishido, T. Shiono, and T. Ikeda
Mol. Cryst. Liq. Cryst., 443, 201-209 (2005). doi

15) Effect of intensity of actinic light and temperature on photochemical phase transition of azobenzene liquid crystals probed by a nearinfrared laser beam
H. Kurihara, A. Shishido, O. Tsutsumi, T. Shiono, and T. Ikeda
Mol. Cryst. Liq. Cryst., 443, 229-238 (2005). doi

16) Unique catalytic behavior of chromium complexes having halogenated bis(imino)pyridine ligands for ethylene polymerization
Y. Nakayama, K. Sogo, H. Yasuda, and T. Shiono
J. Polym. Sci.: Part A: Polym. Chem., 43, 3368-3375 (2005). doi

17) Mesoporous activated carbon as electrode for electric double layer capacitor
H. Tamai, M. Kunihiro, M. Morita, H. Yasuda
J. Mater. Sci., 40, 3703-3707 (2005). doi

18) Synthesis of pentavalent imidovanadium complexes and their catalyses for the polymerization of ethylene and propylene
Y. Sato, Y. Nakayama, H. Yasuda
J. Appl. Polym. Sci., 97, 1008-1015 (2005). doi

19) Characteristics of the biodegradability and physical properties of stereocomplexes between poly(L-lactide) and poly(D-lactide) copolymers
H. Shirahama, A. Ichimaru, C. Tsutsumi, Y. Nakayama, and H. Yasuda
J. Polym. Sci.: Part A: Polym. Chem., 43, 438-454 (2005). doi

20) Comparison of Sm complexes with Sn compounds for syntheses of copolymers composed of lactide and cyclic carbonates and their biodegradabilities
Y. Nakayama, H. Yasuda, K. Yamamoto, C. Tsutsumi, R. Jerome, and P. Lecomte
React. Funct. Polym., 63, 95-105 (2005). doi

21) Developments of chiral metallocenes as polymerization catalysts
Y. Nakayama, and T. Shiono
Molecules, 10, 620-633 (2005). doi

22) シンプルプロセスによるポリオレフィンの高性能化・高機能化は可能か?
塩野毅, 石原毅
化学工業, 56, 801-805 (2005).

23) シングルサイト触媒によるオレフィンのリビング重合
蔡正国, 塩野毅
化学, 60, 74-75 (2005).

24) 遷移金属錯体触媒によるシクロオレフィンのビニル重合
中山祐正, 塩野毅
日本ゴム協会誌, 78, 453-460 (2005).

25) 金属触媒作用による炭素細孔体のナノ構造制御
玉井久司
炭素, 216, 47-52 (2005).

Books, Reports (2005-2013)

1) 田中亮, 中山祐正, 塩野毅, "プロピレン, ノルボルネン, メタクリル酸メチルからなるブロック共重合体の合成とその性質" in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.7, p.49-52, 三恵社 (2013).

2) 塩野毅, "触媒調製ハンドブック", 岩本正和監修, エヌ・ティー・エス (2011).

3) 塩野毅, "チーグラー触媒とともに30 " in 「成型加工」, 23, 517 (2011).

4) 塩野毅, 中山祐正, 蔡正国, "配位重合" in 「高分子の合成(下)開環重合・重縮合・配位重合」,遠藤剛編,講談社 (2010).

5) Takeshi Shiono, Tomiki Ikeda, Lee-Soon Park, "Foreword" in Mol. Cryst. Liq. Cryst., 529, vii (2010).

6) 中山祐正, "アルバータ大学への留学とその後" in 「財団ニュース(財団法人山田科学振興財団) 12 (2010).

7) Takeshi Shiono, Tomiki Ikeda, Lee-Soon Park, "Advanced Display Materials and Devices, (ADMD2009), Part I. (Proceedings of the 13th International Symposium held at Hiroshima University, Japan 23-24 July 2009). [In: Mol. Cryst. Liq. Cryst., 2010; 529]", Taylor and Francis, Inc. (2010).

8) Takeshi Shiono, Tomiki Ikeda, Lee-Soon Park, "Advanced Display Materials and Devices, (ADMD2009), Part II. (Proceedings of the 13th International Symposium held at Hiroshima University, Japan 23-24 July 2009). [In: Mol. Cryst. Liq. Cryst., 2010; 530]", Taylor and Francis, Inc. (2010).

9) Takeshi Shiono, Tomiki Ikeda, Lee-Soon Park, "Advanced Display Materials and Devices, (ADMD2009), Part III. (Proceedings of the 13th International Symposium held at Hiroshima University, Japan 23-24 July 2009). [In: Mol. Cryst. Liq. Cryst., 2010; 531]", Taylor and Francis, Inc. (2010).

10) Takeshi Shiono, Tomiki Ikeda, Lee-Soon Park, "Advanced Display Materials and Devices, (ADMD2009), Part IV. (Proceedings of the 13th International Symposium held at Hiroshima University, Japan 23-24 July 2009). [In: Mol. Cryst. Liq. Cryst., 2010; 532]", Taylor and Francis, Inc. (2010).

11) 中山祐正, "ハフニウム〜イリジウム" in 「元素111 の新知識 2 版」,桜井弘編,p.299-315, 講談社 (2009).

12) 蔡正国, 塩野毅, "ジメチルシリレン架橋フルオレニルアミドジメチルチタン錯体によるプロピレンのシンジオ特異的リビング重合" in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.1, p.106-113, 三恵社 (2008).

13) 萩原英昭, 飯塚豊, 石原毅, 尾崎裕之, 塩野毅, "プロピレンと極性基含有モノマーの共重合による機能化PP の合成とその性質" in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.2, p.80-85, 三恵社 (2008).

14) H. T. Ban, 萩原英昭, 角替康男, 野島伸司, 塩野毅, "高耐熱低複屈折環状オレフィン共重合体の開発" in 「次世代ポリオレフィン総合研究」,次世代ポリオレフィン総合研究会編,Vol.2, p.86-94, 三恵社 (2008).

15) 塩野毅, "配位重合による配列制御" in「精密高分子の基礎と実用化技術」,中濱清一監修,p.16-24 シーエムシー出版 (2008).

16) 塩野毅, "触媒便覧" 触媒学会編, 講談社 (2008).

17) Yuushou Nakayama, Yosuke Ikemoto, Ryo Yamaguchi, Hajime Yasuda, and Takeshi Shiono, "Comparison of polymerization catalysts for syntheses of hydroxytelechelic polylactides", in Reactive and Functional Polymers Research Advances, M. I. Barroso eds., p. 113-129, NOVA Science Publisher, New York, (2008).

18) 塩野毅, "炭素材料の新展開", 日本学術振興会炭素材料第117 委員会 (2007).

19) 塩野毅, "5 版実験化学講座25 触媒化学・電気化学", 丸善, (2006).

20) 塩野毅, "基礎高分子科学", 東京化学同人, (2006).

21) 塩野毅, "エコマテリアルハンドブック", 丸善, (2006).

22) T. Shiono, K. Nomura, and M. Terano, "Process in ole n polymerization catalysts and polyole n materials, studies in surface science and catalysis 161", Elsevier, (2006).

23) 塩野毅, "高分子辞典第3版", 朝倉書店, (2005).

24) 塩野毅, 中山祐正, "5 版実験化学講座26 高分子化学", 丸善, (2005).

25) H. Yasuda, Y. Nakayama, and H. Shirahama, "Handbook of biodegradable polymeric materials and their applications", American Scientific Publishers, (2005).

26) 玉井久司, "多孔質吸着材ハンドブック", フジテクノシステム, (2005).

 

 

 

2004

1) "Supporting effects of methylaluminoxane on living polymerization of propylene with a chelating (diamide)dimethyltitanium complex"

H. Hagimoto, T. Shiono, and T. Ikeda, Macromol. Chem. Phys. vol. 205, no. 1, 19-16 (2004).

2) "Copolymerization of ethylene or propylene with a-olefins containing hydroxy groups with zirconocene/methylaluminoxane catalyst"

H. Hagihara, K. Tsuchihara, K. Takeuchi, M. Murata, H. Ozaki, and T. Shiono, J. Polym. Sci., PART A, Polym. Chem. vol. 42, no. 1, 52-58 (2004).

3) "Effect of solvents of living polymerization of propylene with [t-BuNSiMe2Flu]TiMe2-MMAO"

K. Nishii, T. Matsumae, E. O. Dare, T. Shiono, and T. Ikeda, Macromol. Chem. Phys. vol. 205, no. 3, 363-369 (2004).

4) "Copolymerization of propylene and polar allyl monomer with zirconocene/methylaluminoxane catalyst: Catalytic synthesis of amino-terminated isotactic polyproppylene"

H. Hagihara, K. Tsuchihara, J. Sugiyama, K. Takeuchi, and T. Shiono, Macromolecules, vol. 37, no. 14, 5145-5148 (2004).

5) "Synthesis and characterization of cis-polybutadiene-block-syn-polystyrenecopolymers with a cyclopentadienyltitanium trichloride/modified methylaluminoxane catalyst"

H. T. Ban, Y. Tsunogae, and T. Shiono, J. Polym. Sci., PART A, Polym. Chem. vol. 42, no. 11, 2698-2704 (2004).

6) "Highly efficient Ti-based Cctalyst systems for vinyl addition polymerization of norbornene"

T. Hasan, T. Ikeda, and T. Shiono, Macromolecules, vol. 37, no. 20, 7432-7436 (2004).

7) "Ethene-norbornene copolymer with high norbornene content produced by ansa-fluorenylamidodimethyltitanium complex using a suitable activator"

T. Hasan, T. Ikeda, and T. Shiono, Macromolecules, vol. 37, no. 23, 8503-8509 (2004).

8) "A novel synthetic procedure for steteoblock poly(propylene) with a living polymerization system"

K. Nishii, T. Shiono, and T. Ikeda, Macromol. Rapid Commun. vol. 25, no. 10, 1029-1032 (2004).

9) "Copolymerization of 3-butene-1-ol and propylene with an isospecific zirconocene/methylaluminoxane catallyst"

H. Hagihara, K. Tsuchihara, J. Sugiyama, K. Takeuchi, and T. Shiono, J. Polym. Sci., PART A, Polym. Chem. vol. 42, no. 22, 5600-5607 (2004).

10) "Effect of cross-linking density on phoroinduced bending behavior of oriented liquid-crystalline network films containing azobenzene"

Y. Yu, M. Nakano, A. Shishido, T. Shiono, T. Ikeda, Chem. Mater. vol. 16, no. 9, 1637-1643 (2004).

11) "Photoinduced reorientation of liquid crystals doped with thiophene having ester moieties"

M. Yaegashi, A. Shishido, T. Shiono, and T. Ikeda, Trans. Mater. Res. Soc. Jpn. vol. 29, 955-958 (2004).

12) "Supporting effects of silica-supported MAO with zirconocene catalyst on ethylene//1-olefin copolymerization behaviors for LLDPE production"

B. Jongsomijit, P. Kaewkrajang, T. Shiono, and P. Praserthdam, Ind. & Eng. Chem. Res. vol. 43, no. 24, 7959-7963 (2004).

13) "Effect of aluminoxanes on kinetic feature of 1-hexene polymerization with ansa-(fluorenylamido)dimethyltitanium"

T. Shiono, T. Matsumae, K. Nishii, and T. Ikeda, Proceedings of the 3rd International Workshop on "Heterogeneous Ziegler-Natta Polymerization", 65-70 (2004).

14) "Living random copolymerization of ethene and norbornene using ansa-fluorenylamidodimethyltitanium complex"

T. Hasan, T. Shiono, and T.Ikeda, Macromol. Symp. vol. 213, no. 1, 123-130 (2004).

15) "極性基含有機能化ポリオレフィンの開発"

塩野毅, 萩原英昭, 月刊コンバーテック, vol. 377, 65-70 (2004).

16) "アルキルチタン錯体と担持型活性化剤によるプロピレンのリビング重合"

塩野毅, 触媒, vol. 46, no. 8, 644-649 (2004).

17) "重合技術によるポリオレフィンへの極性付与の試み"

石原毅, 塩野毅, 日本接着学会誌, vol. 40, no. 12, 615-622 (2004).

18) "Random and block copolymerizations of norbornene with other monomers catalyzed by novel Ni compounds involving N- or O-donated ligands"

H. Suzuki, S. Matsumura, Y. Satoh, K. Sogoh, and H. Yasuda, React. Funct. Polym. vol. 58, no. 2, 77-91 (2004).

19) "Random and block copolymerizations of norbornene with conjugated 1,3-dienes catalyzed by novel Ni compounds involving N- or O-donated ligands"

H. Suzuki, S. Matsumura, Y. Satoh, K. Sogoh, and H. Yasuda, React. Funct. Polym. vol. 59, no. 3, 253-266 (2004).

20) "Synthesis of random and block copolymers of lactides with 1,5-dioxepan-2-one and their biodegradability"

Y. Watanabe, H. Shirahama, and H. Yasuda, React. Funct. Polym. vol. 59, no. 3, 211-224 (2004).

21) "Comparison of Sm complexes with Sn compounds for syntheses of copolymers composed of lactides and e-caprolactone and their biodegradabilities"

H. Yasuda, K. Yamamoto, Y. Nakayama, C. Tsutsumi, P. Lecomte, R. Jerome, S. McCarthy, and D. Kaplan, React. Funct. Polym. vol. 61, no. 2, 277-292 (2004).

22) "Developments of rare earth metal catalysts for olefin polymerization"

Y. Nakayama and H. Yasuda, J. Organomet. Chem. vol. 689, no. 24, 4489-4498 (2004).

23) "Adsorption of tetraalkylammonium ions on microporous and mesoporous activated carbons prepared from vinylidene chloride copolymer"

H. Tamai, M. Kunihiro and H. Yasuda, J. Colloid, Interface Sci. vol. 275, no. 1, 44-47 (2004).

24) "Bis(amido)titanium complexes having chelating diaryloxo ligands bridged by sulfur or methylene and their catalytic behaviors for ring-opening polymerization of cyclic esters"

Y. Takashima, Y. Nakayama, T. Hirao, H. Yasuda and A. Harada, J. Organomet. Chem. vol. 689, no. 3, 612-619 (2004).

25) "Activity of samarocene catalysts adsorbed on mesoporous silicates for the polymerization of methyl methacrylate"

H. Yasuda, Y. Nakayama, Y. Satoh, Z. Shen, X. Ni, M. Inoue and S. Namba, Polym. Int. vol. 53, no. 11, 1682-1685 (2004).

26) "Block copolymerizations of higher 1-olefins with traditional polar monomers using metallocene-type single component lanthanide initiators"

H. Yasuda and Guillaume Desurmont, Polym. Int. vol. 53, no. 8, 1017-1024 (2004).

27) "Controlled vinyl-sddition-type polymerization of norbornene initiated by several cobalt complexes having substituted terpyridine ligands"

Y. Sato, Y. Nakayama and H. Yasuda, J. Organomet. Chem. vol. 689, no. 4, 744-750 (2004).

28) "有機金属化合物を用いた新しい高分子材料の開発"

安田 源, Organometallic News, no. 3, 88-91 (2004).

2003

1) "Preparation of Pt Dispersed Carbon Particles from Polyimide Particles"

H. Tamai, S. Nakatsuchi, and H. Yasuda, J. Mater. Sci. vol. 38, no. 9, 1859-1868 (2003).

2) "New Pt and Pt/Ru Supported Cabon Particles for Polymer Electrolyte Fuel Cell"

H. Tamai, S. Nakatsuchi, Y. Kera, and H. Yasuda, J. Mater. Sci. Lett. vol. 22, no. 2, 145-148 (2003).

3) "Simple Preparation and Catalytic Activity of Pd Particles Dispersed Mesoporous Carbons from Poly(VDC/MA) Containing Pt and Y Complexes"

H. Tamai, J. Ogawa, and H. Yasuda, J. Colloid Interface Sci. vol. 260, no. 2, 312-316 (2003).

4) "Preparation of Highly Mesoporous and High Surface Area Activated Carbons from Vinylidene Chloride Copolymer"

H. Tamai, M. Kouzu, and H. Yasuda, Carbon, vol. 41, no. 8, 1678-1681 (2003).

5) "Highly Mesoporous Carbon Electrodes for Electric Double-Layer Capacitor"

H. Tamai, M. Kouzu, M. Morita, and H. Yasuda, Electrochem. Solid State Lett. vol. 6, no. 10, A214-A217 (2003).

6) "Syntheses of Bis- and Tetra(trimethylsilyl) Substituted Lanthanocene Methyl Complexes and Their Catalyses for Polymerization of MMA, CL, and lactide"

Y. Satoh, N. Ikitake, Y. Nakayama, S. Okuno, and H. Yasuda, J. Organomet. Chem. vol. 667, no. 1-2, 42-52 (2003).

7) "Synthesis, Structure, and Olefin Polymerization Calysis of a Novel Vanadum (III) 1,1-Bi-2-naphthoolate Complex"

Y. Sato, Y. Nakayama and H. Yasuda, J. Appl. Polym. Sci. vol. 89, no. 6, 1659-1662 (2003).

8) "Ring-opening Metathesis Polymerization of Norbornene with Catecholato Complexes of Tungsten (VI) as Effective Catalyst Precursors"

Y. Nakayama, K. Katsuda, and H. Yasuda, Polym. J. vol. 35, no. 11, 896-900 (2003).

9) "Stereospecific Ring-Opening Metathesis Polymerization of Cycloolefins Using Novel Molybdenum and Tungsten Complexes Having Biphenolate Ligands. Development of Crystalline Hydrogenated Poly(endo-dicyclopentadiene) and Poly(norbornene)"

S. Hayano, H. Kurakata, Y. Tsunogae, Y. Nakayama, Y. Sato, and H. Yasuda, Macromolecules, vol. 36, no. 20, 7422-7431 (2003).

10) "Facile Syntheses of Bis[1-(arylimino)ethyl]pyridine-MoCl3/MMAO Catalytic System and Their Dual Functions for ROMP of Norbornene and Linear Polymerization of Ethylene"

K. Hiya, Y. Nakayama, and H. Yasuda, Macromolecules, vol. 36, no. 21, 7916-7922 (2003).

11) "Stereospecific Polymerizations of Conjugated Dienes by Single Site Iron Complexes Having Chelating N,N,N-Donor Ligands"

Y. Nakayama, Y. Baba, H. Yasuda, K. Kawakita, and N. Ueyama, Macromolecules, vol. 36, no. 21, 7953-7958 (2003).

12) "Biodegradations of Block Copolymers Composed of L- or D,L-Lactide and Six- membered Cyclic Carbonates Prepred with Organolanthanoide Initiators"

C. Tsursumi, K. Yamamoto, A. Ichimaru, M. Nodono, K. Nakagawa, and H. Yasuda, J. Polym. Sci. Polym. Chem. 41, 3572 (2003).

13) "Isospecific polymerization of alkyl methacrylates with a bis(alkyl) complex and formation of stereocomplexes with syndiotactic poly(alkyl methacrylate)s"

G. Qi, Y. Nitto, A. Saiki, T. Tomohiro, Y. Nakayama, H. Yasuda, Tetrahedrom, 59, 10409-10418 (2003).

14) "生分解樹脂の性能評価と分解速度の制御技術"

安田源, Material Stage, no. 3, 82 (2003).

15) "極性モノマ−と非極性モノマ−の共重合"

安田源, 化学, vol. 58, no. 1, 62-63 (2003).

16) "有機金属化合物を用いた新規材料の開発"

安田源, 玉井久司, 炭素, no. 8, 145-146 (2003).

17) "夢の錯体合成−−新しい挑戦"

安田源, 未来科学, no. 11, 71-73 (2003)

2002

1) "Preparation and High Bacteriostatic Action of the Activated Carbons Possessing Ultrafine Silver Particles"

S. Miyanaga, A. Hiwara, and H. Yasuda, Sci. Tec. Adv. Mater. vol. 3, no. 2, pp. 103-109 (2002).

2) "Preparation of Noble Metal Particles Dispersed Mesoporous Carbons and Their Functions"

H. Tamai, J. Ogawa, and H. Yasuda, Mol. Cryst. Liq. Cryst. vol. 388, pp. 465-469 (2002).

3) "Preparation of Mesoporous Carbons from Polymer Materials Using Organometallics"

H. Tamai, M. Kouzu, and H. Yasuda, Mol. Cryst. Liq. Cryst. vol. 388, pp. 447-451 (2002).

4) "Simple Praparation of TiO$_{2}$ Particles Dispersed Activated Carbons and Their Photo-sterilization"

H. Tamai , N. Katsu, K. Ono, and H. Yasuda, J. Mater. Sci. vol. 37, pp. 3175-3180 (2002).

5) "炭化フェノール樹脂のナノ細孔生成とその吸着特性"

玉井 久司, 長永 昭宏, 村上 一幸, 野中 俊晴, 佐々木 雅彦, 安田 , 炭素 no. 205, pp. 226-230 (2002).

6) "Organo-rare-earth Initiated Living Polymerization of Polar and Nonpolar Monomers"

H. Yasuda, J. Organomet. Chem. vol. 647, no. 1-2, pp. 128-138 (2002).

7) "Maximizationof the Molecular Weight of Poly[alkyl(meth)acrylate] Using SmMe(C5Me5)2(THF) as an Initiator"

M. Tanabe, T. Sugimura, and H. Yasuda, React. Func. Polym. vol. 52, no. 3, pp. 135-141 (2002).

8) "Synthesis and Structure of a Chromium(III) Complex Coordinated by 1,1'-Bi-2-naphtholate Ligands and Its Catalytic Acyivity for Ethylene Polymerization"

H. Ikeda, T. Monoi, Y. Nakayama, and H. Yasuda, J. Organomet. Chem. vol. 648, no. 1-2, pp. 226-230 (2002).

9) "Chromium Complexes Coordinated with Chelating Disiloxane-1,3-diamido Ligands as Catalyst Precursors for Ethylene Polymerization"

H. Ikeda, T. Monoi, Y. Nakayama, and H. Yasuda, J. Organomet. Chem. vol. 642, no. 1-2, pp. 156-162 (2002).

10) "キレート配位子を有する5,6および8族遷移金属錯体を用いたオレフィン重合"

中山 祐正, 緒方 敬治, 佐藤 嘉記, 馬場 勇志, 肥谷 幸司, 安田 , 高分子論文集 vol. 59, no. 4, pp. 235-242 (2002).

11) "Homopolymerization and Randam Copolymerization of Olefins with Amino-substituted Cyclopentadienylchromium Complexes"

K. Ogata, Y. Nakayama, and H. Yasuda, J. Polym. Sci. Polym.Chem. vol. 40, pp. 2759-2771 (2002).

12) "Synthesis of cis-Dichloride Complexes of Group 6 Transition Metals Bearing Alkyne and Chalcogen-bridged Chelating Bis(aryloxo) Ligands as Catalyst Precursors for Ring-opening Metathesis Polymerization"

Y. Takashima, Y. Nakayama, H. Yasuda, A. Nakamura, and A. Harada, J. Organomet. Chem. vol. 654, no. 1-2, pp. 74-82 (2002).

13) "Synthesis of Novel Oxo Complexes of Tungsten and Molybdenum with Various Charcogen-bridged Chelating Bis(aryloxo) Ligands and Their Catalytic Behavior for Ring-opening Metathesis Polymerization"

Y. Takashima, Y. Nakayama, H. Yasuda, and A. Harada, J. Organomet. Chem. vol. 651, no. 1-2, pp. 114-123 (2002).

14) "O,S,O−およびO,N,O−キレート三座配位子を有するタングステン錯体の開環メタセシス重合触媒挙動"

高島 義徳, 中山 祐正, 安田 , 中村 , 原田 , 高分子論文集 vol. 59, no. 6, pp. 298-308 (2002).

15) "Polymerization of Cyclic Esters Catalyzed by Titanium Complexes Having Chalcogen-bridged Chelating Daryloxo Ligands"

Y. Takashima, Y. Nakayama, K. Watanabe, T. Itono, N. Ueyama, A. Nakamura, H. Yasuda, A. Harada, and J. Okuda, Macromolecules, vol. 35, no. 20, pp. 7538-7544 (2002).

16) "Steric Isomerization of Alkyne-dialkyltungsten Complexes with a Chelating Diarloxo Ligand: Crystal Structures of Cs- and C1-W(h2-RCCR)[2,2'-S(4-Me-6-R'C6H2O)2](CH2SiMe3)2"

Y. Takashima, Y. Nakayama, H. Yasuda, A. Nakamura, and A. Harada, J. Organomet. Chem. vol. 664, no. 1-2, pp. 234-244 (2002).

17) "Highly Biodegradable Copolymers Composed of Chiral Depsipeptide and L-Lactide Units with Favorable Physical Properties"

H. Shirahama, A. Tanaka, and H. Yasuda, J. Polym. Sci. Polym. Chem. vol. 40, no. 3, pp. 302-316 (2002).

18) "Enzymatic Degradations of Copolymers of L-Lactide with Cyclic Carbonates"

C. Tsutsumi, K. Nakagawa, H. Shirahama, and H.Yasuda, Macromol. Biosci. vol. 2, no. 5, pp. 223-232 (2002).

19) "希土類錯体を用いたアクリルポリマーの重合と粘着剤への応用"

鷹麿, 川口 佳秀, 安田 , 接着 vol. 46, no. 12, pp. 548-553 (2002).

2001

1) "Utilization of Activated Carbon Fiber with Mesopore Structure for Electric Double Layer Capacitors"

M. Morita, S. Watanabe, M. Ishikawa, H, Tani, H. Yasuda, Electrochemistry, 69, 462-466 (2001).

2) "New Carbon Materials from Pitch Containing Organotin Compounds for Anode of Lithium Ion Batteries"

H. Tamai, S. Matsuoka, M. Ishihara, H. Yasuda, Carbon, 39, 1515-1523 (2001).

3) "Antibacterial Activated Carbon Prepared from Pitch Containing Organometallics"

H. Tamai, N. Katsu, K. Ono, H. Yasuda, Carbon, 39, 1963-1969 (2001).

4) "トリアルキルゲルミルメタクリレート共重合ポリマーの合成およびその船底防汚機能"

玉井久司, 河合弘幸, 松田隆臣, 中村直哉, 坪井 誠, 安田 源, 高分子論文集, 58, 611-616 (2001).

5) "Synthesis of Monodisperse Poly(butyl acrylate) Initiated by SmMe(C5Me5)2(THF) and Its Adhesive Properties After Crosslinking by the Electron Beam Irradiation"

Y. Kawaguchi, H. Yasuda, J. Appl. Polym. Sci., 80, 432-437 (2001).

6) "Unique Dual Functions of La(C5Me5)[CH(SiMe3)2]2(THF) for Non-polar and Polar Monomers"

K. Tanaka, M. Furo, E. Ihara, H. Yasuda, J. Polym. Sci., Polym. Chem. Ed., 39, 1382-1390 (2001).

7) "Synthesis of End Functionalized Low Molecular Weight Poly(butyl acylate) and Its Elongation Using a Diisocyanate"

Y. Kawaguchi, H. Yasuda, React. Fucnt. Polym., 46, 185 (2001).

8) "Synthesis and Olefin Polymerization Catalysis of New Trivalent Samarium and Yttrium Complexes with Bridging Bis(cyclopentadienyl) Ligands"

E. Ihara, S. Yoshioka, M. Furo, K. Katsura, H. Yasuda, S. Mohri, N. Kanehisa, Y. Kai, Organometallics, 20, 1752-1761 (2001).

9) "Rare Earth Metal Initiated Polymerizations of (Meth)acrylates and Block Copolymerizations of Olefins with Polar Monomers"

H. Yasuda, J. Polym. Sci. Polym. Chem., 39, 1955-1959 (2001).

10) "Supercritical CO2-Induced Stereocomplex Formation of High Stereoregular Isotactic Poly(methyl methacrylate) and Syndiotactic Poly(methyl methacrylate) Blends: Effect of Molecular Weight on Crystalline Structure"

T. Mizumoto, N. Sugimura, M. Moritani, H. Yasuda, Y. Sato, H. Masuoka, Macromolecules, 34, 5200-5204 (2001).

11) "Polymerization of styrene with a simple rare earth metal initiator"

T. Hayakawa, Y. Nakayama, H. Yasuda, Polym. Int., 50, 1260-1264 (2001).

12) "Polymerization of methyl methacylate initiated by silica supported (C5Me5)2SmMe(THF)"

Y. F. Zhang, X. F. Ni, Z. Q. Shen, H. Yasuda, Chem. J. Chinese Univ., 22, 1778 (2001).

13) "Polymerization of methyl methacrylate with samarocene complex supported on mesoporous silica"

X. F. Ni, Z. Q. Shen, H. Yasuda, Chinese Chem. Lett., 12, 821 (2001).

14) "Polymerization of Methyl Methacrylate with Homogeneous Organopalladium/MMAO Systems"

E. Ihara, Y. Maeno, H. Yasuda, Macromol. Chem. Phys, 202, 1518-1523 (2001).

15) "Ethylene Polymerizations with Alkyl-, Disilylamino- and Cyclopentadinenyl Chromium/MAO Initiators"

H. Ikeda, T. Monoi, K. Ogata, H, Yasuda, Macromol. Chem. Phys, 202, 1806-1811 (2001).

16) "Synthesis of Poly(lactide-ran-MOHEL) and Its Biodegradation with Proteinase K"

H. Shirahama, K. Mizuma, K. Umemoto, H. Yasuda, J. Polym. Sci., Polym. Chem. Ed., 39, 1374-1381 (2001).

17) "Synthesis and Enzymatic Degradation of High Molecular Weight Aliphatic Polyesters"

H. Shirahama, Y. Kawaguchi, M. S. Aldin, H. Yasuda, J. Appl. Polym. Sci., 80, 340-347 (2001).

18) "Synthesis and Biodegradability of Monoalkylated Caprolactone Copolymers"

H. Shirahama, N. Kanamori, H. Yasuda, J. Oleo. Sci., 50, 49 (2001).

19) "Biodegradation of Copolymers Composed of Optically Active L-Lactide and (R)- or (S)-1-Methyltrimethylene Carbonate"

C. Tsutsumi, H. Yasuda, J. Polym. Sci., Polym. Chem., 39, 3916-3927 (2001).

20) "光学活性L-ラクチド/1-トリメチレンカーボネート共重合体の合成と酵素分解性"

堤主計, 中川克彦, 白浜博幸, 安田 源, 高分子論文集, 58, 245 (2001).

21) "Synthesis of supine-prone bis(diene)tungsten complexes bearing catecholate and diphenylacetylene ligands"

Y, Nakayama, H. Saito, N. Ueyama, A. Nakamura J. Organomet. Chem., 627, 221-225 (2001).

22) "Synthesis of a Novel Oxotungsten(VI) Complex Having a Chelating Bis(aryloxo) Ligand and Its Catalytic Behavior for Ring-Opening Metathesis Polymerization"

Y. Takashima, Y. Nakayama, A. Harada, Chem. Lett., 6, 488-489 (2001).

2000

1) "Characteristics and Catalytic Activity of Carbons Obtained from Pitch Containing Noble Metal Complexes"

H. Tamai, Y. Kataoka, F. Nishiyama, H. Yasuda, Carbon, 38, 899-906 (2000).

2) "NO Decomposition by Ultrafine Noble Metals Dispersed on the Rare Earth Phosphate Hollow Particles"

H. Tamai, T. Ikeya, F. Nishiyama, H. Yasuda, K. Iida, S. Nojima, J. Mater. Sci., 35, 4945-4953 (2000).

3) "Preparation of Carbons from Pitch Containing Polysilane and their Anode Properties for Lithium-ion Batteries"

H. Tamai, H. Sugahara, H. Yasuda, J. Mater. Sci. Lett., 19, 53-56 (2000).

4) "Coordination of Allenyl/propargyl Group to Samarium(III): the First Crystal Structures of h3-Allenyl and h1-Propargyl Lanthanide Complexes"

M. Tanaka, H. Yasuda, N. Kanehisa, T. Maruo, Y. Kai, J. Organomet. Chem., 613, 26-32 (2000).

5) "New Approach to Block Copolymerization of Ethylene with Polar Monomers by the Unique Catalytic Function of Organolanthanide Complexes"

G. Desurmont, M. Tanaka, Y. Li, H. Yasuda, T. Tokimitsu, S. Tone, A. Yanagase, J. Polym. Sci., Part A: Polym. Chem., 38, 4095-4109 (2000).

6) "High Polymerization of Methyl Methacrylate with Organonickel/MMAO Systems"

E. Ihara, T. Fujimura, H. Yasuda, T. Maruo, N. Kanehisa, Y. Kai, J. Polym. Sci., Part A: Polym. Chem., 38, 4764-4775 (2000).

7) "First Controlled Block Copolymerizations of Higher 1-Olefins with Polar Monomers Using Metallocene Type Single Component Lanthanide Initiators"

G. Desurmont, T. Tokimitsu, H. Yasuda, Macromolecules, 33, 7679-7681 (2000).

8) "Reaction Pathway for the Formation of Binuclear Samarocene Hydride from Monomeric Alkyl Samarocene Derivative and the Effective Catalysis of Samarocene Hydride for the Block Copolymerization of Ethylene with Polar Monomers"

G. Desurmont, Y. Li, H. Yasuda, T. Maruo, N. Kanehisa, Y. Kai, Organometallics, 19, 1811-1813 (2000).

9) "Alternative h5- and h6-Bonding Modes for Bis(fluorenyl)lanthanide Complexes by Reactions with AlR3 and Succesive Addition of THF"

H. Nakamura, Y. Nakayama, H. Yasuda, T. Maruo, N. Kanehisa, Y. Kai, Organometallics, 19, 5392-5399 (2000).

10) "Synthesis and Biodegradability of Copolymers of Ethylene Carbonate with Lactones"

H. Shirahama, A. Kanetani, H. Yasuda, Polym. J., 32, 280-286 (2000).

11) "Organo Transition Metal Initiated Living Polymerizations"

H. Yasuda, Prog. Polym. Sci., 25, 573-626 (2000).

12) "Synthesis and Adhesion Properties of Novel Syndiotactic Block Copolymers of Alkyl (Meth)acrylate with Methacrylic Acid and its Analogues"

T. Kakehi, M. Yamashita, H. Yasuda, React. Funct. Polym., 46, 81-94 (2000).

13) "Synthesis of end-functionalized low molecular weight poly(butyl acrylate) and its elongation using a diisocyanate"

Y. Kawaguchi, H. Yasuda, React. Funct. Polym., 46, 185-192 (2000).

14) "New Approaches in Polymerizations Using Transition Metal Complexes"

H. Yasuda, E. Ihara, T. Fujimura, Y. Maeno, K. Ogata, Y. Sato, G. Desurmont, 有機合成化学協会誌, 58, 1084-1094 (2000).

15) "Activation of a trans-Dialkyl(oxo)tungsten Complex Bearing a 2,6-Pyridinediethanolate Ligand with Aluminum Cocatalysts to Catalyze the ROMP of Norbornene"

Y. Nakayama, N. Ikushima, N. Ueyama, A. Nakamura, A. Harada, Chem. Lett., 434-435 (2000).

16) "Titanium Complexes Having Chelating Diaryloxo Ligands Bridged by Tellurium and Their Catalytic Behaviors for Polymerization of Ethylene"

Y. Nakayama, K. Watanabe, N. Ueyama, A. Nakamura, A. Harada, J. Okuda, Organometallics, 19, 2498-2503 (2000).

Books, Reports (2000-2004)

1) 塩野 "触媒活用大辞典", 工業調査会 (2004).

2) 安田源, "脱石油素材化に向けた生分解性プラスチックの高機能化とその応用", エヌ・ティー・エス (2003).

3) 安田 源, "化学ってそういうこと!夢広がる分子の世界", 日本化学会 (2003).

4) H. Yasuda, "Novel h5-h6 Rearrangement of Bis(fluorenyl)lanthanide Complexes by the Addition of AlR3", in Perspectives in Organometallic Chemistry, C. G. Screttas and B. R. Steele eds., Royal Society of Chemistry pp.152 (2003).

5) H. Tamai, and H. Yasuda, "Encyclopedia of Surface and Colloid Science "

Marcel Dekker, Inc. (2002).

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